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The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009

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6.1  For substances which produce such effects and for which specific concentration limits do not yet appear in Table 3.2 of part 3 of Annex VI of the CLP Regulation, concentration limits laid down in Table VI shall determine, where appropriate, the classification of the preparation.

  • The following symbol and risk phrases are assigned:

  • Carcinogenic categories 1 and 2:T; R45 or R49
    Carcinogenic category 3:Xn; R40
    Mutagenic categories 1 and 2:T; R46
    Mutagenic category 3:Xn R68
    Toxic for reproduction fertility categories 1 and 2:T; R60
    Toxic for reproduction development categories 1 and 2:T; R61
    Toxic for reproduction fertility category 3:Xn; R62
    Toxic for reproduction development category 3:Xn; R63
  • Table VI
    Classification of the substanceClassification of the preparation
    Categories 1 and 2Category 3
    Carcinogenic substancesof category 1 or 2 with R45 or R49

    concentration ≥ 0.1%carcinogenic

    R45, R49 obligatory as appropriate

    Carcinogenic substancesof category 3 with R40

    concentration ≥ 1%carcinogenic

    R40 obligatory (unless already assigned R45(*))

    Mutagenic substances of category 1 or 2 with R46

    concentration ≥ 0.1% mutagenic

    R46 obligatory

    Mutagenic substances of category 3 with R68(**)

    concentration ≥ 1%mutagenic

    R68(**) obligatory (unless already assigned R46)

    Substances “toxic for reproduction” of category 1 or 2 with R60 (fertility)

    concentration ≥ 0.5%toxic for reproduction(fertility)

    R60 obligatory

    Substances “toxic for reproduction” of category 3 with R62 (fertility)

    concentration ≥ 5%toxic for reproduction(fertility)

    R62 obligatory (unless already assigned R60)

    Substances “toxic for reproduction” of category1 or 2 with R61 (development)

    concentration ≥ 0.5%toxic for reproduction (development)

    R61 obligatory

    Substances “toxic for reproduction” of category 3 with R63 (development)

    concentration ≥ 5%toxic for reproduction (development)

    R63 obligatory (unless already assigned R61)

  • (*) In cases where the preparation is assigned R49 and R40, both R phrases shall be kept, because R40 does not distinguish between the exposure routes, whereas R49 is only assigned for the inhalation route.

  • (**) R68 here refers to substances classified as mutagenic. Concentration limits for substances required to be labelled R68 but classified as harmful are given in Table II.

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