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The Chemicals (Hazard Information and Packaging) Regulations 1993

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CORROSIVE AND IRRITANT EFFECTS

Solid and liquid preparations

4.—(1) —For substances that produce corrosive effects (R34, R35) or irritant effects (R36, R37, R38, R41), the individual concentration limits specified in Table IV determine, when appropriate, the classification of solid and liquid preparations.

TABLE IV
Classification of the substance and/or relevant standard risk phraseClassification of the preparation and standard risk phrase
at least C with R35at least C with R34at least Xi with R41at least Xi with R36, R37, R38
at least C with R35conc. ≥ 10% R35 obligatory5% ≤ conc. < 10% R34 obligatory1% ≤ conc. < 5% R36, R38 obligatory
at least C with R34conc. ≥ 10% R34 obligatory5% ≤ conc. < 10% R36, R38 obligatory
at least Xi with R41conc. ≥ 10% R41 obligatory5% ≤ conc. < 10% R36 obligatory
at least Xi with R36, R37, R38conc. ≥ 20% R36, R37 and R38 are obligatory in light of the concentration present if they apply to the substances under consideration
Gaseous Preparations

(2) —For gases that produce corrosive effects (R34, R35) or irritant effects (R37, R41), the individual concentration limits specified in Table IVA below, expressed as a volume/volume percentage determine, when appropriate, the classification of gaseous preparations and shall determine which particular risk phrases are to be assigned to them.

TABLE IVA
Classification of the substance (gas) and/or relevant standard risk phraseClassification of the gaseous preparation and standard risk phrase
at least C with R35at least C with R34at least Xi with R41at least Xi with R36, R37 or R38
at least C with R35conc. ≥ 1% R35 obligatory0.2% ≤ conc. < 1% R34 obligatory0.02% ≤ conc. < 0.2% R37 obligatory
at least C with R34conc. ≥ 5% R34 obligatory0.5% ≤ conc. < 5% R37 obligatory
at least Xi with R41conc. ≥ 5% R41 obligatory0.5% ≤ conc. < 5% R36 obligatory
at least Xi with R36, R37, R38conc. ≥ &5percnt; R37, R36, R38 obligatory as appropriate

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