Directive 2013/39/EU of the European Parliament and of the CouncilShow full title

ANNEX II

“‘ANNEX I ENVIRONMENTAL QUALITY STANDARDS FOR PRIORITY SUBSTANCES AND CERTAIN OTHER POLLUTANTS

PART A: ENVIRONMENTAL QUALITY STANDARDS (EQS)

AA

:

annual average.

MAC

:

maximum allowable concentration.

Unit

:

[μg/l] for columns (4) to (7)

[μg/kg wet weight] for column (8)

a CAS: Chemical Abstracts Service.
b This parameter is the EQS expressed as an annual average value (AA-EQS). Unless otherwise specified, it applies to the total concentration of all isomers.
c Inland surface waters encompass rivers and lakes and related artificial or heavily modified water bodies.
d This parameter is the EQS expressed as a maximum allowable concentration (MAC-EQS). Where the MAC-EQS are marked as “not applicable”, the AA-EQS values are considered protective against short-term pollution peaks in continuous discharges since they are significantly lower than the values derived on the basis of acute toxicity.
e For the group of priority substances covered by brominated diphenylethers (No 5), the EQS refers to the sum of the concentrations of congener numbers 28, 47, 99, 100, 153 and 154.
f For Cadmium and its compounds (No 6) the EQS values vary depending on the hardness of the water as specified in five class categories (Class 1: < 40 mg CaCO3/l, Class 2: 40 to < 50 mg CaCO3/l, Class 3: 50 to < 100 mg CaCO3/l, Class 4: 100 to < 200 mg CaCO3/l and Class 5: ≥ 200 mg CaCO3/l).
g This substance is not a priority substance but one of the other pollutants for which the EQS are identical to those laid down in the legislation that applied prior to 13 January 2009.
h No indicative parameter is provided for this group of substances. The indicative parameter(s) must be defined through the analytical method.
i DDT total comprises the sum of the isomers 1,1,1-trichloro-2,2 bis (p-chlorophenyl) ethane (CAS number 50-29-3; EU number 200-024-3); 1,1,1-trichloro-2 (o-chlorophenyl)-2-(p-chlorophenyl) ethane (CAS number 789-02-6; EU Number 212-332-5); 1,1-dichloro-2,2 bis (p-chlorophenyl) ethylene (CAS number 72-55-9; EU Number 200-784-6); and 1,1-dichloro-2,2 bis (p-chlorophenyl) ethane (CAS number 72-54-8; EU Number 200-783-0).
j There is insufficient information available to set a MAC-EQS for these substances.
l For the group of priority substances of polyaromatic hydrocarbons (PAH) (No 28), the biota EQS and corresponding AA-EQS in water refer to the concentration of benzo(a)pyrene, on the toxicity of which they are based. Benzo(a)pyrene can be considered as a marker for the other PAHs, hence only benzo(a)pyrene needs to be monitored for comparison with the biota EQS or the corresponding AA-EQS in water.
k Unless otherwise indicated, the biota EQS relate to fish. An alternative biota taxon, or another matrix, may be monitored instead, as long as the EQS applied provides an equivalent level of protection. For substances numbered 15 (Fluoranthene) and 28 (PAHs), the biota EQS refers to crustaceans and molluscs. For the purpose of assessing chemical status, monitoring of Fluoranthene and PAHs in fish is not appropriate. For substance number 37 (Dioxins and dioxin-like compounds), the biota EQS relates to fish, crustaceans and molluscs, in line with section 5.3 of the Annex to Commission Regulation (EU) No 1259/2011 of 2 December 2011 amending Regulation (EC) No 1881/2006 as regards maximum levels for dioxins, dioxin-like PCBs and non-dioxin-like PCBs in foodstuffs (OJ L 320, 3.12.2011, p. 18).
m These EQS refer to bioavailable concentrations of the substances.
n PCDD: polychlorinated dibenzo-p-dioxins; PCDF: polychlorinated dibenzofurans; PCB-DL: dioxin-like polychlorinated biphenyls; TEQ: toxic equivalents according to the World Health Organisation 2005 Toxic Equivalence Factors.’”
(1)	(2)	(3)	(4)	(5)	(6)	(7)	(8)
No	Name of substance	CAS numbera	AA-EQSbInland surface watersc	AA-EQSbOther surface waters	MAC-EQSdInland surface watersc	MAC-EQSdOther surface waters	EQSBiotak
(1)	Alachlor	15972-60-8	0,3	0,3	0,7	0,7
(2)	Anthracene	120-12-7	0,1	0,1	0,1	0,1
(3)	Atrazine	1912-24-9	0,6	0,6	2,0	2,0
(4)	Benzene	71-43-2	10	8	50	50
(5)	Brominated diphenyletherse	32534-81-9			0,14	0,014	0,0085
(6)	Cadmium and its compounds (depending on water hardness classes)f	7440-43-9	≤ 0,08 (Class 1) 0,08 (Class 2) 0,09 (Class 3) 0,15 (Class 4) 0,25 (Class 5)	0,2	≤ 0,45 (Class 1) 0,45 (Class 2) 0,6 (Class 3) 0,9 (Class 4) 1,5 (Class 5)	≤ 0,45 (Class 1) 0,45 (Class 2) 0,6 (Class 3) 0,9 (Class 4) 1,5 (Class 5)
(6a)	Carbon-tetrachlorideg	56-23-5	12	12	not applicable	not applicable
(7)	C10-13 Chloroalkanesh	85535-84-8	0,4	0,4	1,4	1,4
(8)	Chlorfenvinphos	470-90-6	0,1	0,1	0,3	0,3
(9)	Chlorpyrifos (Chlorpyrifos-ethyl)	2921-88-2	0,03	0,03	0,1	0,1
(9a)	Cyclodiene pesticides: Aldring Dieldring Endring Isodring	309-00-2 60-57-1 72-20-8 465-73-6	Σ = 0,01	Σ = 0,005	not applicable	not applicable
(9b)	DDT totalg,i	not applicable	0,025	0,025	not applicable	not applicable
	para-para-DDTg	50-29-3	0,01	0,01	not applicable	not applicable
(10)	1,2-Dichloroethane	107-06-2	10	10	not applicable	not applicable
(11)	Dichloromethane	75-09-2	20	20	not applicable	not applicable
(12)	Di(2-ethylhexyl)-phthalate (DEHP)	117-81-7	1,3	1,3	not applicable	not applicable
(13)	Diuron	330-54-1	0,2	0,2	1,8	1,8
(14)	Endosulfan	115-29-7	0,005	0,0005	0,01	0,004
(15)	Fluoranthene	206-44-0	0,0063	0,0063	0,12	0,12	30
(16)	Hexachloro-benzene	118-74-1			0,05	0,05	10
(17)	Hexachloro-butadiene	87-68-3			0,6	0,6	55
(18)	Hexachloro-cyclohexane	608-73-1	0,02	0,002	0,04	0,02
(19)	Isoproturon	34123-59-6	0,3	0,3	1,0	1,0
(20)	Lead and its compounds	7439-92-1	1,2m	1,3	14	14
(21)	Mercury and its compounds	7439-97-6			0,07	0,07	20
(22)	Naphthalene	91-20-3	2	2	130	130
(23)	Nickel and its compounds	7440-02-0	4m	8,6	34	34
(24)	Nonylphenols (4-Nonylphenol)	84852-15-3	0,3	0,3	2,0	2,0
(25)	Octylphenols ((4-(1,1′,3,3′-tetramethylbutyl)-phenol))	140-66-9	0,1	0,01	not applicable	not applicable
(26)	Pentachloro-benzene	608-93-5	0,007	0,0007	not applicable	not applicable
(27)	Pentachloro-phenol	87-86-5	0,4	0,4	1	1
(28)	Polyaromatic hydrocarbons (PAH)l	not applicable	not applicable	not applicable	not applicable	not applicable
	Benzo(a)pyrene	50-32-8	1,7 × 10–4	1,7 × 10–4	0,27	0,027	5
	Benzo(b)fluor-anthene	205-99-2	see footnote 11	see footnote 11	0,017	0,017	see footnote 11
	Benzo(k)fluor-anthene	207-08-9	see footnote 11	see footnote 11	0,017	0,017	see footnote 11
	Benzo(g,h,i)-perylene	191-24-2	see footnote 11	see footnote 11	8,2 × 10–3	8,2 × 10–4	see footnote 11
	Indeno(1,2,3-cd)-pyrene	193-39-5	see footnote 11	see footnote 11	not applicable	not applicable	see footnote 11
(29)	Simazine	122-34-9	1	1	4	4
(29a)	Tetrachloro-ethyleneg	127-18-4	10	10	not applicable	not applicable
(29b)	Trichloro-ethyleneg	79-01-6	10	10	not applicable	not applicable
(30)	Tributyltin compounds (Tributyltin-cation)	36643-28-4	0,0002	0,0002	0,0015	0,0015
(31)	Trichloro-benzenes	12002-48-1	0,4	0,4	not applicable	not applicable
(32)	Trichloro-methane	67-66-3	2,5	2,5	not applicable	not applicable
(33)	Trifluralin	1582-09-8	0,03	0,03	not applicable	not applicable
(34)	Dicofol	115-32-2	1,3 × 10–3	3,2 × 10–5	not applicablej	not applicablej	33
(35)	Perfluorooctane sulfonic acid and its derivatives (PFOS)	1763-23-1	6,5 × 10–4	1,3 × 10–4	36	7,2	9,1
(36)	Quinoxyfen	124495-18-7	0,15	0,015	2,7	0,54
(37)	Dioxins and dioxin-like compounds	See footnote 10 in Annex X to Directive 2000/60/EC			not applicable	not applicable	Sum of PCDD+PCDF+PCB-DL 0,0065 μg.kg–1 TEQn
(38)	Aclonifen	74070-46-5	0,12	0,012	0,12	0,012
(39)	Bifenox	42576-02-3	0,012	0,0012	0,04	0,004
(40)	Cybutryne	28159-98-0	0,0025	0,0025	0,016	0,016
(41)	Cypermethrin	52315-07-8	8 × 10–5	8 × 10–6	6 × 10–4	6 × 10–5
(42)	Dichlorvos	62-73-7	6 × 10–4	6 × 10–5	7 × 10–4	7 × 10–5
(43)	Hexabromocyclododecane (HBCDD)	See footnote 12 in Annex X to Directive 2000/60/EC	0,0016	0,0008	0,5	0,05	167
(44)	Heptachlor and heptachlor epoxide	76-44-8/1024-57-3	2 × 10–7	1 × 10–8	3 × 10–4	3 × 10–5	6,7 × 10–3
(45)	Terbutryn	886-50-0	0,065	0,0065	0,34	0,034