- Latest available (Revised)
- Point in Time (12/01/2009)
- Original (As adopted by EU)
Council Directive 1999/13/EC of 11 March 1999 on the limitation of emissions of volatile organic compounds due to the use of organic solvents in certain activities and installations (repealed)
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Version Superseded: 01/12/2010
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This Annex contains the categories of activity referred to in Article 1. When operated above the thresholds listed in Annex IIA, the activities mentioned in this Annex fall within the scope of the Directive. In each case the activity includes the cleaning of the equipment but not the cleaning of products unless specified otherwise.
Any activity in which an adhesive is applied to a surface, with the exception of adhesive coating and laminating associated with printing activities.
Any activity in which a single or multiple application of a continuous film of a coating is applied to:
vehicles as listed below:
new cars, defined as vehicles of category M1 in Directive 70/156/EEC(1), and of category N1 in so far as they are coated at the same installation as M1 vehicles,
truck cabins, defined as the housing for the driver, and all integrated housing for the technical equipment, of vehicles of categories N2 and N3 in Directive 70/156/EEC,
vans and trucks, defined as vehicles of categories N1, N2 and N3 in Directive 70/156/EEC, but not including truck cabins,
buses, defined as vehicles of categories M2 and M3 in Directive 70/156/EEC,
trailers, defined in categories O1, O2, O3 and O4 in Directive 70/156/EEC,
metallic and plastic surfaces including surfaces of airplanes, ships, trains, etc.,
wooden surfaces,
textile, fabric, film and paper surfaces,
leather.
It does not include the coating of substrate with metals by electrophoretic and chemical spraying techniques. If the coating activity includes a step in which the same article is printed by whatever technique used, that printing step is considered part of the coating activity. However, printing activities operated as a separate activity are not included, but may be covered by the Directive if the printing activity falls within the scope thereof.
Any activity where coiled steel, stainless steel, coated steel, copper alloys or aluminium strip is coated with either a film forming or laminate coating in a continuous process.
Any industrial or commercial activity using VOCs in an installation to clean garments, furnishing and similar consumer goods with the exception of the manual removal of stains and spots in the textile and clothing industry.
Any activity of producing complete footwear or parts thereof.
The manufacture of the above final products, and of intermediates where carried out at the same site, by mixing of pigments, resins and adhesive materials with organic solvent or other carrier, including dispersion and predispersion activities, viscosity and tint adjustments and operations for filling the final product into its container.
Textual Amendments
F1 Substituted by Directive 2008/112/EC of the European Parliament and of the Council of 16 December 2008 amending Council Directives 76/768/EEC, 88/378/EEC, 1999/13/EC and Directives 2000/53/EC, 2002/96/EC and 2004/42/EC of the European Parliament and of the Council in order to adapt them to Regulation (EC) No 1272/2008 on classification, labelling and packaging of substances and mixtures (Text with EEA relevance).
The chemical synthesis, fermentation, extraction, formulation and finishing of pharmaceutical products and where carried out at the same site, the manufacture of intermediate products.
Any reproduction activity of text and/or images in which, with the use of an image carrier, ink is transferred onto whatever type of surface. It includes associated varnishing, coating and laminating techniques. However, only the following sub-processes are subject to the Directive:
—
a printing activity using an image carrier of rubber or elastic photopolymers on which the printing areas are above the non-printing areas, using liquid inks which dry through evaporation,
—
a web-fed printing activity using an image carrier in which the printing and non-printing area are in the same plane, where web-fed means that the material to be printed is fed to the machine from a reel as distinct from separate sheets. The non-printing area is treated to attract water and thus reject ink. The printing area is treated to receive and transmit ink to the surface to be printed. Evaporation takes place in an oven where hot air is used to heat the printed material,
—
the adhering together of two or more flexible materials to produce laminates,
—
a rotogravure printing activity used for printing paper for magazines, brochures, catalogues or similar products, using toluene-based inks,
—
a printing activity using a cylindrical image carrier in which the printing area is below the non-printing area, using liquid inks which dry through evaporation. The recesses are filled with ink and the surplus is cleaned off the non-printing area before the surface to be printed contacts the cylinder and lifts the ink from the recesses,
—
a web-fed printing activity in which the ink is passed onto the surface to be printed by forcing it through a porous image carrier, in which the printing area is open and the non-printing area is sealed off, using liquid inks which dry only through evaporation. Web-fed means that the material to be printed is fed to the machine from a reel as distinct from separate sheets,
—
an activity by which a varnish or an adhesive coating for the purpose of later sealing the packaging material is applied to a flexible material.
Any activity of mixing, milling, blending, calendering, extrusion and vulcanisation of natural or synthetic rubber and any ancillary operations for converting natural or synthetic rubber into a finished product.
Any activity except dry cleaning using organic solvents to remove contamination from the surface of material including degreasing. A cleaning activity consisting of more than one step before or after any other activity shall be considered as one surface cleaning activity. This activity does not refer to the cleaning of the equipment but to the cleaning of the surface of products.
Any activity to extract vegetable oil from seeds and other vegetable matter, the processing of dry residues to produce animal feed, the purification of fats and vegetable oils derived from seeds, vegetable matter and/or animal matter.
Any industrial or commercial coating activity and associated degreasing activities performing:
[F2. . . . .]
the original coating of road vehicles as defined in Directive 70/156/EEC or part of them with refinishing-type materials, where this is carried out away from the original manufacturing line, or
the coating of trailers (including semi-trailers) (category O).
Textual Amendments
Any coating activity of metallic conductors used for winding the coils in transformers and motors, etc.
Any activity giving a loading of preservative in timber.
Any activity to adhere together wood and/or plastic to produce laminated products.
Activity(solvent consumption threshold in tonnes/year) | Threshold(solvent consumption threshold in tonnes/year) | Emission limit values in waste gases (mg C/Nm3) | Fugitive emission values (percentage of solvent input) | Total emission limit values | Special provisions | |||
---|---|---|---|---|---|---|---|---|
New | Existing | New | Existing | |||||
1 | Heatset web offset printing (> 15) | 15—25 | 100 | 30 (1) | (1)Solvent residue in finished product is not to be considered as part of fugitive emissions. | |||
> 25 | 20 | 30 (1) | ||||||
2 | Publication rotogravure (> 25) | 75 | 10 | 15 | ||||
3 | Other rotogravure, flexography, rotary screen printing, laminating or varnishing units (> 15) rotary screen printing on textile/cardboard (> 30) | 15—25 | 100 | 25 | (1)Threshold for rotary screen printing on textile and on cardboard. | |||
> 25 | 100 | 20 | ||||||
> 30 (1) | 100 | 20 | ||||||
4 | Surface cleaning (1) (> 1) | 1—5 | 20 (2) | 15 | (1)Using compounds specified in Article 5(6) and (8).(2)Limit refers to mass of compounds in mg/Nm3, and not to total carbon. | |||
> 5 | 20 (2) | 10 | ||||||
5 | Other surface cleaning (> 2) | 2—10 | 75 (1) | 20 (1) | (1)Installations which demonstrate to the competent authority that the average organic solvent content of all cleaning material used does not exceed 30 % by weight are exempt from application of these values. | |||
> 10 | 75 (1) | 15 (1) | ||||||
6 | Vehicle coating (< 15) and vehicle refinishing | > 0,5 | 50 (1) | 25 | (1)Compliance in accordance with Article 9(3) should be demonstrated based on 15 minute average measurements. | |||
7 | Coil coating (> 25) | 50 (1) | 5 | 10 | (1)For installations which use techniques which allow reuse of recovered solvents, the emission limit shall be 150. | |||
8 | Other coating, including metal, plastic, textile (5), fabric, film and paper coating (> 5) | 5—15 | 100 (1) (4) | [X125 ( 4 )] | (1)Emission limit value applies to coating application and drying processes operated under contained conditions.(2)The first emission limit value applies to drying processes, the second to coating application processes.(3)For textile coating installations which use techniques which allow reuse of recovered solvents, the emission limit applied to coating application and drying processes taken together shall be 150.(4)Coating activities which cannot be applied under contained conditions (such as shipbuilding, aircraft painting) may be exempted from these values, in accordance with Article 5(3)(b).(5)Rotary screen printing on textile is covered by activity No 3. | |||
> 15 | 50/75 (2) (3) (4) | 20 (4) | ||||||
9 | Winding wire coating (> 5) | 10 g/kg (1) | (1)Applies for installations where average diameter of wire ≤ 0,1 mm.(2)Applies for all other installations. | |||||
5 g/kg (2) | ||||||||
10 | Coating of wooden surfaces (> 15) | 15—25 | 100 (1) | 25 | (1)Emission limit applies to coating application and drying processes operated under contained conditions.(2)The first value applies to drying processes, the second to coating application processes. | |||
> 25 | 50/75 (2) | 20 | ||||||
11 | Dry cleaning | 20 g/kg (1) (2) (3) | (1)Expressed in mass of solvent emitted per kilogram of product cleaned and dried.(2)The emission limit in Article 5(8) does not apply for this sector.(3)The following exemption refers only to Greece: the total emission limit value does not apply, for a period of 12 years after the date on which this Directive is brought into effect, to existing installations located in remote areas and/or islands, with a population of no more than 2 000 permanent inhabitants where the use of advanced technology equipment is not economically feasible. | |||||
12 | Wood impregnation (> 25) | 100 (1) | 45 | 11 kg/m3 | (1)Does not apply for impregnation with creosote. | |||
13 | Coating of leather (> 10) | 10—25 | 85 g/m2 | Emission limits are expressed in grams of solvent emitted per m2 of product produced. | ||||
> 25 | 75 g/m2 | |||||||
> 10 (1) | 150 g/m2 | (1)For leather coating activities in furnishing and particular leather goods used as small consumer goods like bags, belts, wallets, etc. | ||||||
14 | Footwear manufacture (> 5) | 25 g per pair | Total emission limit values are expressed in grams of solvent emitted per pair of complete footwear produced. | |||||
15 | Wood and plastic lamination (> 5) | 30 g/m2 | ||||||
16 | Adhesive coating (> 5) | 5—15 | 50 (1) | 25 | (1)If techniques are used which allow reuse of recovered solvent, the emission limit value in waste gases shall be 150. | |||
> 15 | 50 (1) | 20 | ||||||
17 | Manufacture of coating [F1mixtures, varnishes, inks and adhesives (> 100) | 100—1 000 | 150 | 5 | 5 % of solvent input | The fugitive emission value does not include solvent sold as part of a coatings [F1mixture] in a sealed container. | ||
> 1 000 | 150 | 3 | 3 % of solvent input | |||||
18 | Rubber conversion (> 15) | 20 (1) | 25 (2) | 25 % of solvent input | (1)If techniques are used which allow reuse of recovered solvent, the emission limit value in waste gases shall be 150.(2)The fugitive emission value does not include solvent sold as part of products or mixtures in a sealed container. | |||
19 | Vegetable oil and animal fat extraction and vegetable oil refining activities (> 10) | Animal fat : 1,5 kg/tonne Castor : 3 kg/tonne Rape seed : 1 kg/tonne Sunflower seed : 1 kg/tonne Soya beans (normal crush) : 0,8 kg/tonne Soya beans (white flakes) : 1,2 kg/tonne Other seeds and other vegetable matter:
| (1)Total emission limit values for installations processing individual batches of seeds and other vegetable matter should be set by the competent authority on a case-by-case basis, applying the best available techniques.(2)Applies to all fractionation processes excluding de-gumming (the removal of gums from the oil).(3)Applies to de-gumming. | |||||
20 | Manufacturing of pharmaceutical products (> 50) | 20 (1) | 5 (2) | 15 (2) | 5 % of solvent input | 15 % of solvent input | (1)If techniques are used which allow reuse of recovered solvent, the emission limit value in waste gases shall be 150.(2)The fugitive emission limit value does not include solvent sold as part of products or mixtures] in a sealed container. |
Editorial Information
The total emission limit values are expressed in terms of grams of solvent emitted in relation to the surface area of product in square metres and in kilograms of solvent emitted in relation to the car body.
The surface area of any product dealt with in the table below is defined as follows:
the surface area calculated from the total electrophoretic coating area, and the surface area of any parts that might be added in successive phases of the coating process which are coated with the same coatings as those used for the product in question, or the total surface area of the product coated in the installation.
The surface of the electrophoretic coating area is calculated using the formula:
This method shall also be applied for other coated parts made out of sheets.
Computer aided design or other equivalent methods shall be used to calculate the surface area of the other parts added, or the total surface area coated in the installation.
The total emission limit value in the table below refers to all process stages carried out at the same installation from electrophoretic coating, or any other kind of coating process, through to the final wax and polish of topcoating inclusive, as well as solvent used in cleaning of process equipment, including spray booths and other fixed equipment, both during and outside of production time. The total emission limit value is expressed as the mass sum of organic compounds per m2 of the total surface area of coated product and as the mass sum of organic compounds per car body.
Activity(solvent consumption threshold in tonnes/year) | Production threshold(refers to annual production of coated item) | Total emission limit value | |
---|---|---|---|
New | Existing | ||
Coating of new cars (> 15) | > 5 000 | 45 g/m2 or 1,3 kg/body + 33 g/m2 | 60 g/m2 or 1,9 kg/body + 41 g/m2 |
≤ 5 000 monocoque or > 3 500 chassis-built | 90 g/m2 or 1,5 kg/body + 70 g/m2 | 90 g/m2 or 1,5 kg/body + 70 g/m2 | |
Total emission limit (g/m2) | |||
Coating of new truck cabins (> 15) | ≤ 5 000 | 65 | 85 |
> 5 000 | 55 | 75 | |
Coating of new vans and trucks (> 15) | ≤ 2 500 | 90 | 120 |
> 2 500 | 70 | 90 | |
Coating of new buses (> 15) | ≤ 2 000 | 210 | 290 |
> 2 000 | 150 | 225 |
Vehicle coating installations below the solvent consumption thresholds in the table above shall meet the requirements for the vehicle refinishing sector in Annex IIA.
The purpose of the reduction scheme is to allow the operator the possibility to achieve by other means emission reductions, equivalent to those achieved if the emission limit values were to be applied. To that end the operator may use any reduction scheme, specially designed for his installation, provided that in the end an equivalent emission reduction is achieved. Member States shall report according to Article 11 of the Directive to the Commission about the progress in achieving the same emission reduction, including the experience from the application of the reduction scheme.
In the case of applying coatings, varnishes, adhesives or inks, the following scheme can be used. Where the following method is inappropriate the competent authority may allow an operator to apply any alternative exemption scheme which it is satisfied fulfils the principles outlined here. The design of the scheme takes into account the following facts:
where substitutes containing little or no solvent are still under development, a time extension must be given to the operator to implement his emission reduction plans;
the reference point for emission reductions should correspond as closely as possible to the emissions which would have resulted had no reduction action been taken.
The following scheme shall operate for installations for which a constant solid content of product can be assumed and used to define the reference point for emission reductions:
the operator shall forward an emission reduction plan which includes in particular decreases in the average solvent content of the total input and/or increased efficiency in the use of solids to achieve a reduction of the total emissions from the installation to a given percentage of the annual reference emissions, termed the target emission. This must be done on the following time frame: | ||
Time period | Maximum allowed total annual emissions | |
---|---|---|
New installations | Existing installations | |
By 31.10.2001 | By 31.10.2005 | Target emission × 1,5 |
By 31.10.2004 | By 31.10.2007 | Target emission |
The annual reference emission is calculated as follows:
The total mass of solids in the quantity of coating and/or ink, varnish or adhesive consumed in a year is determined. Solids are all materials in coatings, inks, varnishes and adhesives that become solid once the water or the volatile organic compounds are evaporated.
The annual reference emissions are calculated by multiplying the mass determined in (a) by the appropriate factor listed in the table below. Competent authorities may adjust these factors for individual installations to reflect documented increased efficiency in the use of solids. | |
Activity | Multiplication factor for use in item (ii)(b) |
---|---|
Rotogravure printing; flexography printing; laminating as part of a printing activity; varnishing as part of a printing activity; wood coating; coating of textiles, fabric film or paper; adhesive coating | 4 |
Coil coating, vehicle refinishing | 3 |
Food contact coating, aerospace coatings | 2,33 |
Other coatings and rotary screen printing | 1,5 |
The target emission is equal to the annual reference emission multiplied by a percentage equal to:
(the fugitive emission value + 15), for installations falling within item 6 and the lower threshold band of items 8 and 10 of Annex IIA,
(the fugitive emission value + 5) for all other installations.
Compliance is achieved if the actual solvent emission determined from the solvent management plan is less than or equal to the target emission.
This Annex provides guidance on carrying out a solvent management plan. It identifies the principles to be applied (item 2) and provides a framework for the mass balance (item 3) and an indication of the requirements for verification of compliance (item 4).
The solvent management plan serves the following purposes:
verification of compliance as specified in Article 9(1);
identification of future reduction options;
enabling of the provision of information on solvent consumption, solvent emissions and compliance with the Directive to the public.
The following definitions provide a framework for the mass balance exercise.
Inputs of organic solvents (I):
The quantity of organic solvents or their quantity in [F1mixtures purchased which are used as input into the process in the time frame over which the mass balance is being calculated.
The quantity of organic solvents or their quantity in mixtures recovered and reused as solvent input into the process. (The recycled solvent is counted every time it is used to carry out the activity.)
Outputs of organic solvents (O):
Emissions in waste gases.
Organic solvents lost in water, if appropriate taking into account waste water treatment when calculating O5.
The quantity of organic solvents which remains as contamination or residue in products output from the process.
Uncaptured emissions of organic solvents to air. This includes the general ventilation of rooms, where air is released to the outside environment via windows, doors, vents and similar openings.
Organic solvents and/or organic compounds lost due to chemical or physical reactions (including for example those which are destroyed, e.g. by incineration or other waste gas or waste water treatments, or captured, e.g. by adsorption, as long as they are not counted under O6, O7 or O8).
Organic solvents contained in collected waste.
Organic solvents, or organic solvents contained in mixtures, which are sold or are intended to be sold as a commercially valuable product.
Organic solvents contained in mixtures] recovered for reuse but not as input into the process, as long as not counted under O7.
Organic solvents released in other ways.
The use made of the solvent management plan will be determined by the particular requirement which is to be verified, as follows:
Verification of compliance with the reduction option in Annex IIB, with a total emission limit value expressed in solvent emissions per unit product, or otherwise stated in Annex IIA.
For all activities using Annex IIB the solvent management plan should be done annually to determine consumption (C). Consumption can be calculated according to the following equation:
A parallel exercise should also be undertaken to determine solids used in coating in order to derive the annual reference emission and the target emission each year.
For assessing compliance with a total emission limit value expressed in solvent emissions per unit product or otherwise stated in Annex IIA, the solvent management plan should be done annually to determine emissions (E). Emissions can be calculated according to the following equation:
where F is the fugitive emission as defined in section (ii)(a). The emission figure should then be divided by the relevant product parameter.
For assessing compliance with the requirements of Article 5(5)(b)(ii), the solvent management plan should be done annually to determine total emissions from all activities concerned, and that figure should then be compared with the total emissions that would have resulted had the requirements of Annex II been met for each activity separately.
Determination of fugitive emissions for comparison with fugitive emission values in Annex IIA:
Methodology
The fugitive emission can be calculated according to the following equation:
or
This quantity can be determined by direct measurement of the quantities. Alternatively, an equivalent calculation can be made by other means, for instance by using the capture efficiency of the process.
The fugitive emission value is expressed as a proportion of the input, which can be calculated according to the following equation:
Frequency
Determination of fugitive emissions can be done by a short but comprehensive set of measurements. It need not be done again until the equipment is modified.
OJ L 42, 23.2.1970, p. 1. Directive as last amended by Directive 97/27/EC (OJ L 233, 25.8.1997, p. 1).
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