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16. In Schedule 4—
(a)following the title, there shall be inserted the following words—
(b)in paragraph 3(5)—
(i)for head (c) there shall be substituted the following head—
“(c)thermal insulation and single mechanical refrigeration, provided that for self-reactive substances with a flash point lower than the sum of the emergency temperature plus 5°C explosion-proof electrical fittings, Ex IIB T3, are used within the coolant compartment to prevent ignition of flammable vapours from the self-reactive substances;”, and
(ii)for sub-head (iii) of head (e) there shall be substituted the following sub-head—
“(iii)for self-reactive substances with a flash point lower than the sum of the emergency temperature plus 5°C explosion-proof electrical fittings, Ex IIB T3, are used within the coolant compartment to prevent ignition of flammable vapours from the self-reactive substances;”;
(c)after paragraph 7, there shall be inserted the following paragraph—
“7A. Packages containing any of the following goods shall not be carried in a small container—
UN 1510 TETRANITROMETHANE
UN 2015 HYDROGEN PEROXIDE, STABILIZED or HYDROGEN PEROXIDE, AQUEOUS SOLUTION, STABILIZED.”;
(d)in paragraph 8(5)—
(i)for head (c) there shall be substituted the following head—
“(c)thermal insulation and single mechanical refrigeration, provided that for self-reactive substances with a flash point lower than the sum of the emergency temperature plus 5°C explosion-proof electrical fittings, Ex IIB T3, are used within the coolant compartment to prevent ignition of flammable vapours from the organic peroxides;”, and
(ii)for sub-head (iii) of head (e), there shall be substituted the following sub-head—
“(iii)for self-reactive substances with a flash point lower than the sum of the emergency temperature plus 5°C explosion-proof electrical fittings, Ex IIB T3, are used within the coolant compartment to prevent ignition of flammable vapours from the organic peroxides.”;
(e)after paragraph 10 there shall be inserted the following paragraphs—
“11. Packages containing any of the following goods shall not be carried in a small container—
UN 3101 ORGANIC PEROXIDE TYPE B, LIQUID
UN 3102 ORGANIC PEROXIDE TYPE B, SOLID.
12. Refrigerated liquefied gases shall not be carried in a small container.”; and
(f)after paragraph 12 there shall be inserted the following Part—
13. Composite intermediate bulk containers containing any of the following goods, where those goods are in solid form, shall be carried in a closed vehicle or a closed container—
UN 1479 OXIDIZING SOLID, N.O.S. of packing group I
UN 1491 POTASSIUM PEROXIDE
UN 1504 SODIUM PEROXIDE
UN 2466 POTASSIUM SUPEROXIDE
UN 2547 SODIUM SUPEROXIDE.
14. Composite or wooden intermediate bulk containers containing any of the following goods, where those goods are in solid form and of packing group I, shall be carried in a closed vehicle or a closed container—
UN 1544 ALKALOIDS, SOLID, N.O.S., or ALKALOID SALTS, SOLID, N.O.S.
UN 1557 ARSENIC COMPOUND, SOLID, N.O.S.
UN 1570 BRUCINE
UN 1601 DISINFECTANT, SOLID, TOXIC, N.O.S.
UN 1655 NICOTINE COMPOUND, SOLID, N.O.S. or NICOTINE PREPARATION, SOLID, N.O.S.
UN 1692 STRYCHNINE or STRYCHNINE SALTS
UN 1693 TEAR GAS SUBSTANCE, SOLID, N.O.S.
UN 1699 DIPHENYLCHLOROARSINE
UN 2025 MERCURY COMPOUND, SOLID, N.O.S.
UN 2026 PHENYLMERCURIC COMPOUND, N.O.S.
UN 2570 CADMIUM COMPOUND
UN 2630 SELENATES or SELENITES
UN 2811 TOXIC SOLID, ORGANIC, N.O.S.
UN 3143 DYE, SOLID, TOXIC, N.O.S.
UN 3146 ORGANOTIN COMPOUND, SOLID, N.O.S.
UN 3172 TOXINS EXTRACTED FROM LIVING SOURCES, N.O.S.
UN 3276 NITRILES, TOXIC, N.O.S.
UN 3278 ORGANOPHOSPHORUS COMPOUND, TOXIC, N.O.S.
UN 3280 ORGANIC ARSENIC COMPOUND, N.O.S.
UN 3281 METAL CARBONYLS, N.O.S.
UN 3282 ORGANOMETALLIC COMPOUND, TOXIC, N.O.S.
UN 3283 SELENIUM COMPOUND, N.O.S.
UN 3288 TOXIC SOLID, INORGANIC, N.O.S.
Halogenated substances, with a flashpoint above 61°C, with the exception of UN 1694 BROMOBENZYL CYANIDES
Inorganic cyanides
Pesticides, solid, toxic.
15. Composite intermediate bulk containers containing the goods UN 2930 TOXIC SOLID, FLAMMABLE, ORGANIC, N.O.S. of packing group I shall be carried in a closed vehicle or a closed container.
16. Composite or wooden intermediate bulk containers containing any of the following goods, where those goods are in solid form and of packing group I, shall be carried in a closed vehicle or a closed container—
UN 1759 CORROSIVE SOLID, N.O.S.
UN 1905 SELENIC ACID
UN 2430 ALKYLPHENOLS, SOLID, N.O.S.
UN 2923 CORROSIVE SOLID, TOXIC, N.O.S.
UN 3259 AMINES, SOLID, CORROSIVE, N.O.S. or POLYAMINES, SOLID, CORROSIVE, N.O.S.
UN 3260 CORROSIVE SOLID, ACIDIC, INORGANIC, N.O.S.
UN 3261 CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S.
UN 3262 CORROSIVE SOLID, BASIC, INORGANIC, N.O.S.
UN 3263 CORROSIVE SOLID, BASIC, ORGANIC, N.O.S..
17. Composite intermediate bulk containers containing the goods UN 2921 CORROSIVE SOLIDS, FLAMMABLE, N.O.S. of packing group I shall be carried in a closed vehicle or a closed container.”.
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