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The Control of Major Accident Hazards Regulations 2015

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PART 2 E+W+SNamed Dangerous Substances

Column 1CAS number (see note 22)Column 2Column 3
Qualifying quantity in tonnes of dangerous substances for the application of:
Dangerous substances
Lower tier requirementsUpper tier requirements
1. Ammonium nitrate (see note 13)-5,00010,000
2. Ammonium nitrate (see note 14)-1,2505,000
3. Ammonium nitrate (see note 15)-3502,500
4. Ammonium nitrate (see note 16)-1050
5. Potassium nitrate (see note 17)-5,00010,000
6. Potassium nitrate (see note 18)-1,2505,000
7. Arsenic pentoxide, arsenic (V) acid and/or salts1303-28-212
8. Arsenic trioxide, arsenious (III) acid and/or salts1327-53-30.1
9. Bromine7726-95-620100
10. Chlorine7782-50-51025
11. Nickel compounds in inhalable powder form: nickel monoxide, nickel dioxide, nickel sulphide, trinickel disulphide, dinickel trioxide-1
12. Ethyleneimine151-56-41020
13. Fluorine7782-41-41020
14. Formaldehyde (concentration ≥ 90 %)50-00-0550
15. Hydrogen1333-74-0550
16. Hydrogen chloride (liquefied gas)7647-01-025250
17. Lead alkyls-550
18. Liquefied flammable gases, Category 1 or 2 (including LPG) and natural gas (see note 19)-50200
19. Acetylene74-86-2550
20. Ethylene oxide75-21-8550
21. Propylene oxide75-56-9550
22. Methanol67-56-15005,000
23. 4, 4′-Methylene bis (2-chloraniline) and/or salts, in powder form101-14-40.01
24. Methylisocyanate624-83-90.15
25. Oxygen7782-44-72002,000

26. 2,4 -Toluene diisocyanate

2,6 -Toluene diisocyanate

584-84-9

91-08-7

10100
27. Carbonyl dichloride (phosgene)75-44-50.30.75
28. Arsine (arsenic trihydride)7784-42-10.21
29. Phosphine (phosphorus trihydride)7803-51-20.21
30. Sulphur dichloride10545-99-01
31. Sulphur trioxide7446-11-91575
32. Polychlorodibenzofurans and polychlorodibenzodioxins (including TCDD), calculated in TCDD equivalent (see note 20)-0.001
33. The following CARCINOGENS or the mixtures containing the following carcinogens at concentrations above 5% by weight: 4-Aminobiphenyl and/or its salts, Benzotrichloride, Benzidine and/or salts, Bis (chloromethyl) ether, Chloromethyl methyl ether, 1,2-Dibromoethane, Diethyl sulphate, Dimethyl sulphate, Dimethylcarbamoyl chloride, 1,2-Dibromo-3-chloropropane, 1,2-Dimethylhydrazine, Dimethylnitrosamine, Hexamethylphosphoric triamide, Hydrazine, 2- Naphthylamine and/or salts, 4-Nitrodiphenyl, and 1,3 Propanesultone-0.52

34. Petroleum products and alternative fuels

(a) gasolines and naphthas,

(b) kerosenes (including jet fuels),

(c) gas oils (including diesel fuels, home heating oils and gas oil blending streams),

(d) heavy fuel oils,

(e) alternative fuels serving the same purposes and with similar properties as regards flammability and environmental hazards as the products referred to in points (a) to (d)

-2,50025,000
35. Anhydrous ammonia7664-41-750200
36. Boron trifluoride7637-07-2520
37. Hydrogen sulphide7783-06-4520
38. Piperidine110-89-450200
39. Bis(2-dimethylaminoethyl) (methyl)amine3030-47-550200
40. 3-(2-Ethylhexyloxy)propylamine5397-31-950200
41. Mixtures of sodium hypochlorite classified as Aquatic Acute Category 1 [H400] containing less than 5% active chlorine and not classified under any of the other hazard categories in Part 1 of this Schedule, provided that the mixture in the absence of sodium hypochlorite would not be classified as Aquatic Acute Category 1 [H400].-200500
42. Propylamine (see note 21)107-10-85002,000
43. Tert-butyl acrylate (see note 21)1663-39-4200500
44. 2-Methyl-3-butenenitrile (see note 21)16529-56-95002,000
45. Tetrahydro-3,5-dimethyl-1,3,5-thiadiazine-2-thione (Dazomet) (see note 21)533-74-4100200
46. Methyl acrylate (see note 21)96-33-35002,000
47. 3-Methylpyridine (see note 21)108-99-65002,000
48. 1-Bromo-3-chloropropane (see note 21)109-70-65002,000

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