SCHEDULE 1
PART IAUTHORISED MONOMERS
SECTION AMonomers authorised without time limit
1 | 2 | 3 | 4 | |
---|---|---|---|---|
Item | PM/REF No. | CASNo. | Name | Restrictions |
1. | 10030 | 000514-10-3 | Abietic acid | |
2. | 10060 | 000075-07-0 | Acetaldehyde | |
3. | 10090 | 000064-19-7 | Acetic acid | |
4. | 10120 | 000108-05-4 | Acetic acid, vinyl ester | The specific migration of this substance shall not exceed 12 md/kg. |
5. | 10150 | 000108-24-7 | Acetic anhydride | |
6. | 10210 | 000074-86-2 | Acetylene | |
7. | 10630 | 000079-06-1 | Acrylamide | The specific migration of this substance shall be not detectable (when measured by a method with a limit of detection 0.01 mg/kg. |
8. | 10690 | 000079-10-7 | Acrylic acid | |
9. | 10780 | 000141-32-2 | Acrylic acid, n-butyl ester | |
10. | 10810 | 002998-08-5 | Acrylic acid, sec. butyl | |
11. | 10840 | 001663-39-4 | Acrylic acid, tert. butyl | |
12. | 11470 | 000140-88-5 | Acrylic acid, ethyl ester | |
13. | As item 17 | 000818-61-1 | Acrylic acid, hydroxyethyl exter | |
14. | 11590 | 000106-63-8 | Acrylic acid, isobutyl ester | |
15. | 11680 | 000689-12-3 | Acrylic acid, isopropyl ester | |
16. | 11710 | 000096-33-3 | Acrylic acid, methyl ester | |
17. | 11830 | 000818-61-1 | Acrylic acid, monoester with ethylene glycol | |
18. | 11980 | 000925-60-0 | Acrylic acid, propyl ester | |
19. | 12100 | 000107-13-1 | Acrylonitrile | The specific migration of this substance shall be not detectable (when measured by a method with a limit of detection of 0.02 mg/kg, analytical tolerance included) |
20. | 12130 | 000124-04-9 | Adipic acid | |
21. | 12280 | 002035-75-8 | Adipic anhydride | |
22. | 12310 | Albumin | ||
23. | 12340 | Albumin, coagulated by formaldehyde | ||
24. | 12375 | Alcohols, aliphatic, monohydric, saturated, linear, prinmary (C4-C22) | ||
25. | 12670 | 002855-13-2 | 1-Amino-3-aminomethyl-3,5,5-trimethylcyclohexane | The specific migration of this substance shall not exceed 6 mg/kg. |
26. | 12788 | 002432-99-7 | 11-aminoundecanoic acid | The specific migration of this substance shall be not detectable (when measured by a method with a limit of detection of 0.01 mg/kg. |
27. | 12820 | 000123-99-9 | Azalaid acid | |
28. | 12970 | 004196-95-6 | Azelaic anhydride | |
29. | 13000 | 001477-55-0 | 1,3-Benzenedimethanamine | The specific migration pof this substance shall not exceed 0.05 mg/kg. |
30. | 13090 | 000065-85-0 | Benzolic acid | |
31. | 13150 | 000100-51-6 | Benzyl alcohol | |
32. | As item 72 | 000111-46-6 | Bis(2-hydroxyethyl) ether | As item 72. |
33. | As item 192 | 000077-99-6 | 2,2-Bis(hydroxymethyl)-butan-1-ol | As item 192. |
34. | 13390 | 000105-08-8 | 1,4-Bis(hydroxymethyl)-cyclohexane | |
35. | 13480 | 000080-05-7 | 2,2-Bis(4-hydroxyphenyl)-propane | The specific migration of this substance shall not exceed 3 mg/kg. |
36. | 13510 | 001675-54-3 | 2,2-Bis(4-hydroxyphenyl)-propane bis(2,3-epoxypropyl) ether | The quantity of this substance in the finished plastic material or article shall not exceed 1 mg/kg or the specific migration of this substance shall be not detectable (when measured by a method with a limit of detection of 0.02 mg/kg. analytical tolerance included). |
37. | As item 84 | 000110-98-5 | Bis(hydroxypropyl) ether | |
38. | As item 71 | 005124-30-1 | Bis(4-isocyanatocyclohexyl)methane | As item 71. |
39. | 13530 | 038103-06-9 | 2,2-Bis(4-hydroxyphenyl)-propane bis(phthalic anhydride) | The specific migration of this substance shall not exceed 0.05 mg/kg. |
40. | 13600 | 047465-97-4 | 3,3-Bis(3-methyl-4-hydroxyphenyl)indolin-2-one | The specific migration of this substance shall not exceed 1.8 mg/kg. |
41. | As item 35 | 000080-05-7 | Bisphenol A | As item 35. |
42. | As item 36 | 001675-54-3 | Bisphenol A bis(2,3-epoxypropyl) ether | As item 36. |
43. | 13614 | 038103-06-9 | Bisphenol A bis(phthalic anhydride) | As item 39. |
44. | 13630 | 000106-99-0 | Butadiene | The quantity of this substance in the finished plastic material or article shall not exceed 1 mg/kg or the specific migration of this substance shall be not detectable (when measured by a method with a limit of detection of 0.02 mg/kg. analytical tolerance included). |
45. | 13690 | 000107-88-0 | Butan-1,3-diol | |
46. | 13840 | 000071-36-3 | Butan-1-ol | |
47. | 13870 | 000106-98-9 | But-1-ene | |
48. | 13900 | 000107-01-7 | But-2-ene | |
49. | 14110 | 000123-72-8 | Butyraldehyde | |
50. | 14140 | 000107-92-6 | Butyric acid | |
51. | 14170 | 000106-31-0 | Butyric anhydride | |
52. | 14200 | 000105-60-2 | Caprolactam | The specific migration of this substance alone or together with item 53 shall not exceed a total of 15 mg/kg. |
53. | 14230 | 002123-24-2 | Caprolactam, sodium salt | The specific migration of this substance alone or together with item 52 shall not exceed a total of 15 mg/kg (expressed as caprolactam). |
54. | 14320 | 000124-07-2 | Caprylic acid | |
55. | 14350 | 000630-08-0 | Carbon monoxide | |
56. | 14380 | 000075-44-5 | Carbonyl chloride | The quantity of this substance in the finished plastic material or article shall not exceed 1 mg/kg. |
57. | 14410 | 008001-79-4 | Castor oil (food grade quality) | |
58. | 14500 | 009004-34-6 | Cellulose | |
59. | 14530 | 007782-50-5 | Chlorine | |
60. | As item 85 | 000106-89-8 | 1-Chloro-2,3-epoxypropane | As item 85. |
61. | 14680 | 000077-92-9 | Citric acid | |
62. | 14710 | 000108-39-4 | m-Cresol | |
63. | 14740 | 000095-48-7 | o-Cresol | |
64. | 14770 | 000106-44-5 | p-Crresol | |
65. | As item 34 | 000105-08-8 | 1,4-Cyclohexanedimethanol | |
66. | 14950 | 003175-53-3 | Cyclohexyl isocyanate | The quantity in the finished plastic material or article of any substance within, or any combination of substances within, items 66, 71, 79, 81, 82, 83, 106, 132, 135, 186, 187 and 188 shall not exceed 1 mg/kg (expressed as isocyanate moiety). |
67. | 15100 | 000112-30-1 | Decan-1-ol | |
68. | As item 88 | 000107-15-3 | 1,2-Diaminoethane | As item 88. |
69. | As item 105 | 000124-09-4 | 1,6-Diaminohexane | As item 105. |
70. | 15250 | 000110-60-1 | 1,4-Diaminobutane | |
71. | 15700 | 005124-30-1 | Dicyclohexylmethane-4,4'-diisocyanate | As item 66. |
72. | 15760 | 000111-46-6 | Diethylene glycol | The specific migration of this substance alone or together with item 89 shall not exceed a total of 30 mg/kg. |
73. | 15880 | 000120-80-9 | 1,2-Dihydroxybenzene | The specific migration of this substance shall not exceed 6 mg/kg. |
74. | 15910 | 000108-46-3 | 1,3-Dihydroxybenzene | The specific migration of this substance shall not exceed 2.4 mg/kg. |
75. | 15940 | 000123-31-9 | 1,4-Dihydroxybenzene | The specific migration of this substance shall not exceed 0.6 mg/kg. |
76. | 15970 | 000611-99-4 | 4,4'-Dihydroxybenzophenone | The specific migration of this substance shall not exceed 6 mg/kg. |
77. | 16000 | 000092-88-6 | 4,4'-Dihydroxybiphenyl | The specific migration of this substance shall not exceed 6 mg/kg. |
78. | 16150 | 000108-01-0 | Dimethylaminoethanol | The specific migration of this substance shall not exceed 18 mg/kg. |
79. | 16240 | 000091-97-4 | 3,3'-Dimethyl-4,4'-diisocyanatobiphenyl | As item 66. |
80. | 16480 | 000126-58-9 | Dipentaerythritol | |
81. | 16570 | 004128-73-8 | Diphenylether-4,4'-diisocyanaate | As item 66. |
82. | 16600 | 005873-54-1 | Diphenylmethane-2,4'-diisocyanate | As item 66. |
83. | 16630 | 000101-68-8 | Diphenylmethane-4-4'-diisocyanate | As item 66. |
84. | 16660 | 000110-98-3 | Dipropylene glycol | |
85. | 16750 | 000106-89-8 | Epichlorohydrin | The quantity of this substance in the finished plastic material or article shall not exceed 1 mg/kg. |
86. | 16780 | 000064-17-5 | Ethanol | |
87. | 16950 | 000074-85-1 | Ethylene | |
88. | 16960 | 000107-15-3 | Ethylenediamine | The specific migration of this substance shall not exceed 12 mg/kg. |
89. | 16990 | 000107-21-1 | Ethylene glycol | The specifi c migration opf this substance alone or together with item 72 shall not exceed a total of 30 mg/kg. |
90. | 17005 | 000151-56-4 | Ethyleneimine | The specific migration of this substance shall be not detectable (when measured by a method with a limit of detection of 0.01 mg/kg). |
91. | 17020 | 000075-21-8 | Ethylene oxide | The quantity of this substance in the finished plastic material or article shall not exceed 1 mg/kg. |
92. | 17170 | 061788-47-4 | Fatty acids, coco | |
93. | 17200 | 068308-53-2 | Fatty acids, soya | |
94. | 17230 | 061790-12-3 | Fatty acids, tall oil | |
95. | 17260 | 000050-00-0 | formaldehyde | The specific migration of this substance shall not exceed 15 mg/kg. |
96. | 17290 | 000110-17-8 | Fumaric acid | |
97. | 17530 | 000050-99-7 | Glucose | |
98. | 18010 | 000110-94-1 | Glutaric acid | |
99. | 18070 | 000108-55-4 | Glutaric anhydride | |
100. | 18100 | 000056-81-5 | Glycerol | |
101. | 18250 | 000115-28-6 | Hexachloroendomethylenetetrahydrophthalic acid | The specific migration of this substance shall be not detectable (when measured by a method with a limit of detection of 0.01 mg/kg). |
102. | 18280 | 000115-27-5 | Hexachloroendomethylenetetrahydrophthalic anhydride | The specific migration of this substance shallb be not detectable (when measured by a method with a limit of detection of 0.01 mg/kg). |
103. | 18310 | 036653-82-4 | Hexadecan-1-ol | |
104. | 18430 | 000116-15-4 | Hexafluoropropylene | The specific migration of this substance shall be not detectable (when measured by a method with a limit of detection of 0.01 mg/kg). |
105. | 18460 | 000124-09-4 | Hexamethylenediamine | The specific migration pof this substance shall not exceed 2.4 mg/kg. |
106. | 18640 | 000822-06-0 | Hexamethylene diisocyanate | As item 66. |
107. | 18670 | 000100-97-0 | Hexamethylenetetramine | The specific migration of this substance shall not exceed 1.5 mg/kg (expressed as formaldahyde). |
108. | As item 75 | 000123-31-9 | Hydroquinone | As item 75. |
109. | 18880 | 000099-96-7 | p-Hydroxybenzoic acid | |
110. | 19000 | 000115-11-7 | Isobutene | |
111. | 19470 | 000143-07-7 | Lauric acid | |
112. | 19510 | 011132-73-3 | Lignocellulose | |
113. | 19540 | 000110-16-7 | maleic acid | The specific migration of this substance alone or together with item 114 shall not exceed a total of 30 mg/kg. |
114. | 19960 | 000108-31-6 | Maleic anhydride | The specific migration of this substance alone or together with item 113 shall not exceed a total of 30 mg/kg (expressed as maleic acid). |
115. | As item 190 | 000108-78-1 | Melamine | As item 190. |
116. | 20020 | 000079-41-4 | Methacrylic acid | |
117. | 20110 | 000097-88-1 | Methacrylic acid, butyl ester | |
118. | 20140 | 002998-18-7 | Methacrylic acid, sec. butyl | |
119. | 20170 | 000585-07-9 | Methacryhlic acid, tert. butyl ester | |
120. | 20890 | 000097-63-2 | Methacrylic acid, ethyl ester | |
121. | 21010 | 000097-86-9 | Methacrylic acid, isobutyl ester | |
122. | 21100 | 004655-34-9 | Methacrylic acid, isopropyl ester | |
123. | 21130 | 000080-62-6 | Methacrylic acid, methyl ester | |
124. | 21190 | 000868-77-9 | Methacrylic acid, monoester with ethyleneglycol | |
125. | 21340 | 002210-28-8 | Methacrylic acid, propyl ester | |
126. | 21460 | 000760-93-0 | Methacrylic anhydride | |
127. | 21490 | 000126-98-7 | Methacrylonitrile | The specific migration of this substance shall be not detectable (when measured by a method with a limit of detection of 0.02 mg/kg, analytical tolerance included). |
128. | 21550 | 000067-56-1 | Methanol | |
129. | 21940 | 000924-42-5 | N-Methylolacrylamide | The specific migration of this substance shall be not detectable (when measured by a method with a limit of detection of 0.01 mg/kg). |
130. | 22150 | 000691-37-2 | 4-Methylpent-1-ene | The specific migration of this substance shall not exceed 0.02 mg/kg. |
131. | 22350 | 000544-63-8 | Myristic acid | |
132. | 22420 | 003173-72-6 | 1,5-Naphthalene diisocyanate | As item 66. |
133. | 22450 | 009004-70-0 | Nitrocellulose | |
134. | 22480 | 000143-08-8 | Nonan-1-ol | |
135. | 22570 | 000112-96-9 | Octadecyl isocyanate | As item 66. |
136. | 22600 | 000111-87-5 | Octan-1-ol | |
137. | 22660 | 000111-66-0 | Oct-1-ene | The specific migration of this substance shall not exceed 15 mg/kg. |
138. | 22763 | 000112-80-1 | Oleic acid | |
139. | 22780 | 000057-10-3 | Palmitic acid | |
140. | 22840 | 000115-77-5 | Pentaerythritol | |
141. | 22870 | 000071-41-0 | Pentan-1-ol | |
142. | 22960 | 000108-95-2 | Phenol | |
143. | 23050 | 000108-45-2 | 1,3-Phenylenediamine | The quantity of this substance in the finished plastic material or article shall not exceed 1 mg/kg. |
144. | As item 56 | 000075-44-5 | Phosgene | As item 56. |
145. | 23170 | 007644-38-2 | Phosphoric acid | |
146. | As item 181 | Phthalic acid | As item 181. | |
147. | 232500 | 000088-99-3 | o-Phthalic Acid | |
148. | 23230 | 000131-17-9 | Phthalic acid diallyl ester | The specific migration of this sustance shall be not detectable (when measured by a method with a limit of detection of 0.01 mg/kg). |
149. | 23380 | 000085-44-9 | Phthalic anhydride | |
150. | 23470 | 000080-56-8 | alpha-Pinene | |
151. | 23500 | 000127-91-3 | beta-Pinene | |
152. | 23590 | 025322-68-3 | Polyethylene glycol | |
153. | 23650 | 025322-69-4 | Polypropylene glycol (molecular weight greater than 400) | |
154. | 23740 | 000057-55-6 | Propan-1,2-diol | |
155. | 23800 | 000071-23-8 | Propan-1-ol | |
156. | 23830 | 000067-63-0 | Propan-2-ol | |
157. | 23860 | 000123-38-6 | Propionaldehyde | |
158. | 23890 | 000079-09-4 | Propionic acid | |
159. | 23950 | 000123-62-6 | Propionic anhydride | |
160. | 23980 | 000115-07-1 | Propylene | |
161. | 24010 | 000075-56-9 | Propylene oxide | The quantity of this substance in the finished plastic material or article shall not exceed 1 mg/kg. |
162. | As item 73 | 000120-80-9 | Pyrocatechol | As item 73. |
163. | 24070 | 073138-82-6 | Resin acids and rosin acids | |
164. | As item 74 | 000108-46-3 | Resorcinol | As item 74. |
165. | 24100 | 008050-09-7 | Rosin | |
166. | 24130 | 008050-09-7 | Rosin gum | |
167. | 24160 | 008052-10-6 | Rosin tall oil | |
168. | 24190 | 009014-63-5 | Rosin wood | |
169. | 24250 | 009006-04-6 | Rubber, natural | |
170. | 24270 | 000069-72-7 | Salicyclic acid | |
171. | 24280 | 000111-20-6 | Sebacic acid | |
172. | 24430 | 002561-88-8 | Sebacic anhydride | |
173. | 24490 | 000050-70-4 | Sorbitol | |
174. | 24520 | 008001-22-7 | Soybean oil | |
175. | 24550 | 000057-11-4 | Stearic acid | |
176. | 24610 | 000100-42-5 | Styrene | |
177. | 24820 | 000110-15-6 | Succinic acid | |
178. | 24850 | 000108-30-5 | Succinic anhydride | |
179. | 24880 | 000057-50-1 | Sucrose | |
180. | 24887 | 006326-79-4 | 5-Sulphoisophthalic acid, monosodium sale | The specific migration of this substance shall not exceed 0.05 mg/kg. |
181. | 24910 | 000100-21-0 | Terephthalic acid | The specific migration of this substance shall not exceed 7.5 mg/kg. |
182. | 24970 | 000120-61-6 | Terephthalic acid, dimethyl ester | |
183. | 25090 | 000112-60-7 | Tetraethylene glycol | |
184. | 25150 | 000109-99-9 | Tetrahydrofuran | The specific migration of this substance shall not exceed 0.6 mg/kg. |
185. | 25180 | 000102-60-3 | N,N,N',N'-Tetrakis(2-hydroxypropyl)ethylenediamine | |
186. | 25210 | 000584-84-9 | 2,4-Toluene diisocyanate | As item 66. |
187. | 25240 | 000091-08-7 | 2,6-Toluene diisocyanate | As item 66. |
188. | 25270 | 026747-90-0 | 2,4-Toluene diisocyanate dimer | As item 66. |
189. | 25360 | Trialdyl(C5-C15)acitic acid, 2,3-epoxypropyl ester | The specific migration of this substance shall not exceed 0.6 mg/kg. | |
190. | 25420 | 000108-78-1 | 2,4,6-Triamino-1,3,5-triazine | The specific migration of this substance shall not exceed 30 mg/kg. |
191. | 25510 | 000112-27-6 | Triethylene glycol | |
192. | 25600 | 000077-99-6 | 1,1,1-Trimethylolpropane | The specific migration of this substance shall not exceed 6 mg/kg. |
193. | 25910 | 024800-44-0 | Tripropylene glycol | |
194. | 25960 | 000057-13-6 | Urea | |
195. | 26050 | 000075-01-4 | Vinyl chloride | The restrictions are those in regulation 5(1)(a) and (b) of the 1987 Regulations when analysed by the method referred to in regulation 14 of those regulations. |
196. | 26110 | 000075-35-4 | Vinylidene chloride | The quantity of this substance in the finishedplastic material or article shall not exceed 5 mg/kg or the specific migration pof this substance shall be not detectable (when measured by a method with a limit of detection of 0.05 mg/kg). |
SECTION BMonomers authorised up to the end of 1996
1 | 2 | 3 | 4 | |
---|---|---|---|---|
Item | PM/REF No. | CASNo. | Name | Restrictions |
1. | As item 92 | 00542-02-9 | Acetoguanamine | |
2. | 10160 | 002206-94-2 | alpha-Acetoxystyrene | |
3. | 10162 | 010521-96-7 | beta-Acetoxystyrene | |
4. | 10480 | Acids, aliphatic, monocarboxylic, saturated (C2-C24) | ||
5. | 10510 | Acids, aliphatic, monocarboxylic, unsaturated (C3-C24) | ||
6. | 10599/70 | Acids, fatty, unsaturated (C18) | ||
7. | 10599/70 | 061788-89-4 | Acids, fatty, unsaturated (C18), dimers | |
8. | 10599/92 | 068783-41-5 | Acids, fatty, unsaturated (C18), dimers, hydrogenated | |
9. | 10600 | Acids, linear, with an even number of carbon atoms (C8-C22), and the dimers and trimers of the unsaturated acids | ||
10. | 10660 | 015214-89-8 | Acrylamidomethylpropanesulphonic acid | |
11. | 10720 | 000999-55-3 | Acrylic acid, allyl ester | |
12. | 10750 | 002495-35-4 | Acrylic acid, benzyl ester | |
13. | 10775 | 084100-23-2 | Acrylic acid, 4-tert.-butylcyclohexyl ester | |
14. | 10930 | 003066-71-5 | Acrylic acid, cyclohyxyl ester | |
15. | 10990 | 002156-96-9 | Acrylic acid, decyl ester | |
16. | 11000 | 050967-02-8 | Acrylic acid, dicyclopentadienyl ester | |
17. | 11005 | 012542-30-2 | Acrylic acid, dicyclopentenyl ester | |
18. | 11010 | 024447-78-7 | Acrylic acid, diester with 2,2-bis(4-hydroxyphenyl)-propane bis(2-hydroxyethyl) ether | |
19. | 11020 | 019485-03-1 | Acrylic acid, diester with butan-1,3-diol | |
20. | 11050 | 001070-70-8 | Acrylic acid, diester with butan-1,4-diol | |
21. | 11080 | 004074-88-8 | Acrylic acid, diester with diethyleneglycol | |
22. | 11110 | 002274-11-5 | Acrylic acid, diester with ethyleneglycol | |
23. | 11140 | 013048-33-4 | Acrylic acid, diester with hexan-1,6-diol | |
24. | 11170 | 026570-48-9 | Acrylic acid, diester with polyethyleneglycol | |
25. | 11180 | 017831-71-9 | acrylic acid, diester with tetraethyleneglycol | |
26. | 11195 | 068901-05-3 | Acrylic acid, diester with tripropyleneglycol | |
27. | 11200 | 002426-54-2 | Acrylic acid, 2-(diethylamino)ethyl ester | |
28. | 11230 | 002439-35-2 | Acrylic acid, 2-(dimethylamino)ethyl ester | |
29. | 11245 | 002156-97-0 | Acryhlic acid, dodecyl ester | |
30. | 11260 | 000106-90-1 | Acrylic acid, 2,3-epoxypropyl ester | The quantity in the finished plastic material or articleof any substance within, or any combination of substances within, items 30, 56, 70 and 181 shall not exceed 5 mg/kg (expressed as epoxy). |
31. | 11500 | 000103-11-7 | Acrylic acid, 2-ethylhexyl ester | |
32. | 11520 | 002918-23-2 | Acrylic acid, 2-hydroxyisopropyl ester(=acrylic acid, 2-hydroxy-1-methylethyl ester) | |
33. | 11530 | 000999-61-1 | Acrylic acid, 2-hydroxypropyl ester | |
34. | 11532 | 002761-08-2 | Acrylic acid, 3-hydroxypropyl ester | |
35. | 11560 | 005888-33-5 | Acrylic acid, isobornyl ester | |
36. | 11620 | 001330-61-6 | Acrylic acid, isodecyl ester | |
37. | 11695 | 003121-61-7 | Acrylic acid, 2-methoxyethyl ester | |
38. | 11650 | 029590-42-9 | Acrylic acid, isooctyl ester | |
39. | 11740 | 010095-13-3 | Acrylic acid, monoester with butan-1,3-diol | |
40. | 11770 | 002478-10-6 | Acrylic acid, monoester with butan-1,4-diol | |
41. | 11800 | 013533-05-6 | Acrylic acid, monoester with diethyleneglycol | |
42. | 11860 | Acrylic acid, monoester with propyleneglycol | ||
43. | 11875 | 004813-57-4 | Acrylic acid, octadecyl ester | |
44. | 11890 | 002499-59-4 | Acrylic acid, octadecyl ester | Acrylic acid, n-octyl ester |
45. | 12010 | 040074-09-7 | Acrylic acid, 2-sulphoethyl ester | |
46. | 12040 | 039121-78-3 | Acrylic acid, sulphopropyl ester | |
47. | 12055 | 094160-26-6 | Acrylic acid, triester with glycerol tris(2-hydroxypropyl) ether | |
48. | 12062 | 075577-70-7 | Acrylic acid, triester with 1,1,1-trimethylolpropane tris(2-hydroxyethyl) ether | |
49. | 12160 | 002998-04-1 | Adipic acid, diallyl ester | |
50. | 12190 | 000105-97-5 | Adipic acid, didecyl ester | |
51. | 12220 | 027178-16-1 | Adipic acid, diisodecyl ester | |
52. | 12250 | 000123-79-5 | Adipic acid, dioctyl ester | |
53. | 12265 | 004074-90-2 | Adipic acid, divinyl ester | |
54. | 12370 | Alcohols, aliphatic, monohydric, saturated, linear, secondary or tertiary (C4-C22) | ||
55. | 12610 | 000107-18-6 | Allyl alcohol | |
56. | 12640 | 000106-92-3 | Allyl 2,3-epoxypropyl ether | As item 30. |
57. | 12700 | 000150-13-0 | p-Aminobenzoic acid | |
58. | 12790 | 000080-46-6 | p-tert.-Amylphenol | |
59. | 12850 | 029602-44-6 | Azelaic acid, bis(2-hydroxyethyl) ester | |
60. | 12910 | 001732-10-1 | Azelaic acid, dimethyl ester | |
61. | As item 255 | 000528-44-9 | 1,2,4-Benzenetricarboxylic acid | As item 255. |
62. | 13060 | 004422-95-1 | 1,3,5-Benzenetricarboxylic acid trichloride | |
63. | As item 94 | 000091-76-9 | Benzoguanamine | |
64. | 13210 | 001761-71-3 | Bis(4-aminocyclohexyl)-methane | |
65. | 13328 | 000104-38-1 | Bis(2-hydroxyethyl) ether of hydroquinone | |
66. | As item 103 | 000080-09-1 | Bisphenol S | |
67. | 13660 | 000584-03-2 | Butan-1,2-diol | |
68. | 13720 | 000110-63-4 | Butan-1,4-diol | |
69. | 13750 | 000513-85-9 | Butan-2,3-diol | |
70. | 13780 | 002425-79-8 | Butan-1,4-diol bis(2,3-epoxypropyl) ether | As item 30. |
71. | 13810 | 000505-65-7 | Butan-1,4-diol formal | |
72. | 13932 | 000598-32-3 | Butan-3-en-2-ol | |
73. | 13960 | 001852-16-0 | N-(Butoxymethyl)-acrylamide | |
74. | 14008 | 000098-52-2 | 4-tert.-Butylcyclohexanol | |
75. | 14020 | 000098-54-4 | 4-tert.-Butylphenol | |
76. | 14035 | 001746-23-2 | 4-tert.-Butylstyrene | |
77. | 14260 | 000502-44-3 | Caprolactone | |
78. | As item 101, Section A | 000115-28-6 | Chlorendic acid | As item 101, Section A. |
79. | 14560 | 000126-99-8 | 2-Chlorobutan-1,3-diene | |
80. | 14650 | 000079-38-9 | Chlorotrifluoroethylene | The quantity of this substance in the finished platic material or article shall not exceed 5 mg/kg. |
81. | 14800 | 003724-65-0 | Crotonic acid | |
82. | 14833 | 000623-43-8 | Crotonic acid, methyl ester | |
83. | 14980 | 001631-25-0 | N-Cyclohexylmaleimide | The quantity of this substance in the finished plastic material or article shall not exceed 5 mg/kg. |
84. | 15020 | 002182-05-0 | Cyclohexyl vinyl ether | |
85. | 15030 | 000931-88-4 | Cyclooctene | |
86. | 15060 | 000142-29-0 | Cyclopentene | |
87. | 15070 | 001647-16-1 | Dec-1,9-diene | |
88. | 15095 | 000334-48-5 | Decanoic acid | |
89. | 15120 | 000872-05-9 | Dec-1-ene | |
90. | 15260 | 000646-25-3 | 1,10-Diaminodecane | |
91. | 15270 | 002783-17-7 | 1,12-Diaminododecane | |
92. | 15280 | 000542-02-9 | 2,4-Diamino-6-methyl-1,3,5-triazine | |
93. | 15295 | 000373-44-4 | 1,8-Diaminooctane | |
94. | 15310 | 000091-76-9 | 2,4-Diamino-6-phenyl-1,3,5,-triazine | |
95. | 15340 | 000109-76-2 | 1,3-Diaminopropane | |
96. | 15370 | 003236-53-1 | 1,6-Diamino-2,2,4-trimethylhexane | |
97. | 15400 | 003236-54-2 | 1,6-Diamino-2,4,4-trimethylhexane | |
98. | 15490 | 002215-89-6 | 4,4'-Dicarboxydiphenyl ether | |
99. | 15580 | 001653-19-6 | 2,3-Dichlorobuta-1,3-diene | |
100. | 15610 | 000080-07-9 | 4,4'-Dichlorodiphenyl sulphone | |
101. | 15730 | 000077-73-6 | Dicyclopentadiene | |
102. | 15790 | 000111-40-0 | Diethylenetriamine | |
103. | 16090 | 000080-09-1 | 4,4'-Dihydroxydiphenyl sulpone | |
104. | 16120 | 000110-97-4 | Diisopropanolamine | |
105. | 16180 | 005205-93-6 | N-(Dimethylaminopropyl)methacrylamide | |
106. | 16210 | 006864-37-5 | 3,3'-Dimethyl-4,4'-diaminodicyclohexylmethane | |
107. | 16252 | 000110-03-2 | 2,5-Dimethylhexane-2,5-diol | |
108. | 16270 | 000526-75-0 | 2,3-Dimethylphenol | |
109. | 16300 | 000105-67-9 | 2,4-Dimethylphenol | |
110. | 16330 | 000095-87-4 | 2,5-Dimethylphenol | |
111. | 16360 | 000576-26-1 | 2,6-Dimethylphenol | |
112. | 16390 | 000126-30-7 | 2,2-Dimethylpropan-1,3-diol | |
113. | 16450 | 000646-06-0 | 1,3-Dioxolane | |
114. | 16510 | 000138-86-3 | Dipentene | |
115. | 16540 | 000102-09-0 | Diphenyl carbonate | |
116. | 16690 | 001321-74-0 | Divinylbenzene | |
117. | 16697 | 000693-23-2 | Dodecanedioic acid | |
118. | 16719 | 003813-52-3 | Endomethylenetetrahydrophthalic acid | |
119. | 16900 | 013036-41-4 | N-(Ethoxymethyl)-acryhlamide | |
120. | 17040 | 000149-57-5 | 2-Ethylhexanoic acid | |
121. | 17050 | 000104-76-7 | 2-Ethylhexan-1-ol | |
122. | 17110 | 016219-75-3 | 5-Ethylidenebicyclo-[2.2.1]hept-2-ene | |
123. | 17116 | 005877-42-9 | 4-Ethyloct-1-yn-3-ol | |
124. | 17150 | 000078-27-3 | 1-Ethynylcyclohexanol | |
125. | 17305 | 000141-02-6 | Fumeric acid, bis(2-ethylhexyl ester) | |
126. | 17320 | 002807-54-7 | Fumaric acid, diallyl ester | |
127. | 17350 | 000105-75-9 | Fumaric acid, dibutyl ester | |
128. | 17380 | 000623-91-6 | Fumaric acid, diethyl ester | |
129. | 17398 | 007283-68-3 | Fumaric acid, dioctadecyl ester | |
130. | 17800 | Glucosides obtained from glucose and pentaerythritol | ||
131. | 17830 | Glucosides obtained from glucose and polyethyleneglycol (molecular weight greater than 200) | ||
132. | 17860 | Glucosides obtained from glucose and polypropyleneglycol (molecular weight greater than 400) | ||
133. | 18220 | 068564-88-5 | N-Heptylaminoundecanoid acid | |
134. | 18370 | 000592-45-0 | Hexa-1,4-diene | |
135. | 18400 | 000592-42-7 | Hexa-1,5-diene | |
136. | 18436 | 001687-30-5 | Hexadydrophthalic acid | |
137. | 18441 | 000085-42-7 | Hexahydrophthalic anhydride | |
138. | 18490 | 015511-81-6 | Hexamethylenediamine adipate | |
139. | 18610 | 006422-99-7 | Hexamethylenediamine sebacate | |
140. | 18700 | 000629-11-8 | Hexan-1,6-diol | |
141. | 18820 | 000592-41-6 | Hex-1-ene | |
142. | 18850 | 000107-41-5 | Hexyleneglycol | |
143. | 18865 | 003031-66-1 | Hex-3-yn-2,5-diol | |
144. | 18905 | 002628-17-3 | 4-Hydroxystyrene | |
145. | 18970 | 000078-83-1 | Isobutanol | |
146. | 19030 | 016669-59-3 | N-(Isobutoxymethyl)-acrylamide | |
147. | 19060 | 000109-53-5 | Isobutyl vinyl ether | |
148. | 19090 | 000079-84-2 | Isobutyraldehyde | |
149. | 19120 | 025339-17-7 | Isodecanol | |
150. | 19130 | 026896-18-4 | Isononanoic acid | |
151. | 19140 | 026952-21-6 | Isooctanol | |
152. | 19150 | 000121-91-5 | Isophthalic acid | |
153. | 19180 | 000099-63-8 | Isophthalic acid dichloride | |
154. | 19210 | 001459-93-4 | Isophthalic acid, dimethyl ester | |
155. | As item 200 | 000078-79-5 | Isoprene | |
156. | 19270 | 000097-65-4 | Itaconic acid | |
157. | 19480 | 002146-71-6 | Lauric acid, vinyl ester | |
158. | 19490 | 000947-04-6 | Laurolactam | |
159. | 19570 | 000999-21-3 | Maleic acid, diallyl ester | |
160. | 19600 | 000105-76-0 | Maleic acid, dibutyl ester | |
161. | 19660 | 000141-05-9 | Maleic acid, diethyl ester | |
162. | 19690 | 014234-82-3 | Maleic acid, diisobutyl ester | |
163. | 19720 | 001330-76-3 | Maleic acid, diisooctyl ester | |
164. | 19750 | 000624-48-6 | Maleic acid, dimethyl ester | |
165. | 19915 | 000925-21-3 | Maleic acid, monobutyl ester | |
166. | 19936 | 007423-42-9 | Maleic acid, mono(2-ethylhexyl) ester | |
167. | 19990 | 000079-39-0 | Methacrylamide | |
168. | 20050 | 000096-05-9 | Methacrylic acid, allyl ester | |
169. | 20080 | 002495-37-6 | Methacrylic acid, benzyl ester | |
170. | 20095 | 046729-07-1 | Methacrylic acid, 4-tert.-butylcyclohexyl ester | |
171. | 20200 | 001888-94-4 | Methacrylic acid, 2-chloroethyl ester | |
172. | 20260 | 000101-43-9 | Methacrylic acid, cyclohexyl ester | |
173. | 20320 | 003179-47-3 | Methacrylic acid, decyl ester | |
174. | 20380 | 001189-08-8 | Methacrylic acid, diester with butan-1,3-diol | |
175. | 20410 | 002028-81-7 | Methacrylic acid, diester with butan-1,4-diol | |
176. | 20440 | 000097-90 | Methacryl5ic acid, diester with ethyleneglycol | |
177. | 20455 | 006606-59-3 | Methacrylic acid, diester with hexan-1,6-diol | |
178. | 20470 | 025852-47-5 | Methacrylic acid, diester with polyethyleneglycol | |
179. | 20530 | 002867-47-2 | Methacrylic acid, 2-(dimethylamino)-ethyl ester | |
180. | 20560 | 000142-90-5 | Methacrylic acid, dodecyl ester | |
181. | 20590 | 000106-91-2 | Methacrylic acid, 2,3-epoxypropyl ester | As item 30. |
182. | 20740 | 039670-09-2 | Methacrylic acid, ester with ethoxytriethyleneglycol | |
183. | 20830 | Methacrylic acid, esters with propan-1,2-diol | ||
184. | 20920 | 000688-84-6 | Methacrylic acid, 2-ethylhexyl ester | |
185. | 20945 | 004664-49-7 | Methacrylic acid, 2-hydroxyisopropyl ester (=methacrylic acid, 2-hydroxy-1-methylethyl ester) | |
186. | 20950 | 000923-26-2 | Methacrylic acid, 2-hydroxypropyl ester | |
187. | 20965 | 002761-09-3 | Methacrylic acid, 3-hydroxypropyl ester | |
188. | 20980 | 007534-94-3 | Methacrylic acid, isobornyl ester | |
189. | 21040 | 029964-84-9 | Methacrylic acid, isodecyl ester | |
190. | 21070 | 028675-80-1 | Methacrylic acid, isooctyl ester | |
191. | 21115 | 000816-74-0 | Methacrylic acid, methallyl ester | |
192. | 21170 | 000997-46-6 | Methacrylic acid, monoester with butan-1,4-diol | |
193. | 21220 | 032360-05-7 | Methacrylic acid, octadecyl ester | |
194. | 21250 | 002157-01-9 | Methacrylic acid, n-octyl ester | |
195. | 21280 | 002177-70-0 | Methacrylic acid, phenyl ester | |
196. | 21370 | 010595-80-9 | Methacrylic acid, 2-sulphoethyl ester | |
197. | 21400 | 054276-35-6 | Methacrylic acid, sulphopropyl ester | |
198. | 21430 | 004245-37-8 | Methacrylic acid, vinyl ester | |
199. | 21520 | 001561-92-8 | Methallylsulphonic acid, sodium salt | The quantity of this substance in the finished plastic material or article shall not exceed 5 mg/kg. |
200. | 21640 | 000078-79-5 | 2-Methylbut-1,3-diene | |
201. | 21670 | 000563-46-2 | 2-Methylbut-1-ene | |
202. | 21730 | 000563-45-1 | 3-Methylbut-1-ene | |
203. | 21733 | 000115-19-5 | 2-Methylbut-3-yn-2-ol | |
204. | 21736 | 002549-61-3 | alpha-Methyl-epsilon-caprolactone | |
205. | 21739 | 002549-60-2 | beta-Methyl-epsilon-caprolactone | |
206. | 21742 | 002549-58-8 | delta-Methyl-epsilon-caprolactone | |
207. | 21745 | 002549-59-9 | epsilon-Methyl-epsilon-caprolactone | |
208. | 21748 | 002549-42-0 | gamma-Methyl-epsilon-caprolactone | |
209. | 21760 | 000694-91-7 | 5-Methylenebicyclo-[2.2.2]hept-2-ene | |
210. | As item 71 | 000506-65-7 | 1,4-(Methylenedioxy)butane | |
211. | 21867 | 001116-90-1 | 4-methylhex-1,4-diene | The specific migration pof this substance shall be not detectable (when measured by a method with a limit of detection of 0.05 mg/kg). |
212. | 21850 | 000095-71-6 | Methylhydroquinone | |
213. | 21880 | 000717-27-1 | Methylhydroquinone diacetate | |
214. | 21970 | 000923-02-4 | N-Methylolmethacrylamide | |
215. | 22210 | 000098-86-9 | alpha-Methylstyrene | |
216. | 22240 | 000622-97-9 | p-Methylstyrene | |
217. | 22270 | 000107-25-5 | Methyl vinyl ether | |
218. | 22360 | 001141-38-4 | 2,6-Naphthalenedicarboxylic acid | |
219. | As item 112 | 000126-30-7 | Neopentylglycol | |
220. | 22428 | 051000-52-3 | Neodecanoic acid, vinyl ester | |
221. | 22465 | 000112-05-0 | Nonanoic acid | |
222. | 22540 | 000104-40-5 | 4-Nonylphenol | |
223. | 13180 (also used for bicyclo[2.2.2]hept-2-ene) | 000498-66-8 | Norbornene | As item 39 on Part I Section C. |
224. | 22585 | 003710-30-3 | Octa-1,7-diene | |
225. | 22690 | 001806-26-4 | 4-Octylphenol | |
226. | 22720 | 000140-66-9 | 4-tert.-Octylphenol | |
227. | 22811 | 000591-93-5 | Pent-1,4-diene | |
228. | 22842 | 002590-16-1 | Pentaerythritol diallyl ether | |
229. | 22858 | 005343-92-0 | Pentan-1,2-diol | |
230. | 22861 | 000111-29-5 | Pentan-1,5-diol | |
231. | 22900 | 000109-67-1 | Pent-1-ene | |
232. | 22901 | 000109-68-2 | Pent-2-ene | |
233. | 22932 | 001187-93-5 | Perfluoromethyl perfluorovinyl ether | |
234. | 22935 | 003823-94-7 | Perfluoromethyl vinyl ether | |
235. | 22937 | 001623-05-8 | Perfluoropropyl perfluorovinyl ether | |
236. | 22940 | 006996-01-06 | Perfluoropropyl vinyl ether | |
237. | 23140 | 000092-69-3 | 4-Phenylphenol | |
239. | 23530 | 025190-06-1 | Poly(1,4-butyleneglycol) (molecular weight greater than 1000) | |
240. | 23770 | 000504-63-2 | Propan-1,3-diol | |
241. | 23920 | 000105-38-4 | Propionic acid, vinyl ester | |
242. | 24370 | 000106-79-6 | Sebacic acid, dimethyl ester | |
243. | 24560 | 000111-63-7 | Stearic acid, vinyl ester | |
244. | 24760 | 026914-43-2 | Styrenesulphonic acid | |
245. | 24940 | 000100-20-9 | Terephthalic acid dichloride | |
246. | 25030 | 016646-44-9 | Tetra(allyloxy)ethane | |
247. | 25120 | 000116-14-3 | Tetrafluoroethylene | |
248. | 25158 | 000088-98-2 | 1,2,3,6-Tetrahydrophthalic acid | |
249. | 25161 | 000085-43-8 | 1,2,3,6-Tetrahydrophthalic anhydride | |
250. | 25300 | 000088-19-7 | o-Toluenesulphonamide | |
251. | 25380 | Trialkyl(C5-C15) acetic acid vinyl ester (=vinyl versatate) | ||
252. | 25390 | 000101-37-1 | Triallyl cyanurate | |
253. | 25450 | 026896-48-0 | Tricyclodecadedimethanol | |
254. | 25480 | 000102-71-6 | Triethanolamine | |
255. | 25540 | 000528-44-9 | Trimellitic acid | The quantity of this substance alone or together with item 256 in the finished plastic material or article shall not exceed 5 mg/kg. |
256. | 25550 | 000552-30-7 | Trimellitic anhydride | The quantity of this substance alone or together with item 255 in the finished plastic material or article shall not exceed 5 mg/kg (expressed as trimellitic acid). |
257. | 25630 | 037275-47-1 | 1,1,1-Trimethylolpropane diacrylate | |
258. | 25645 | 000682-09-7 | 1,1,1-Trimethylolpropane diallyl ether | |
259. | 25780 | 025723-16-4 | 1,1,1-Trimethylolpropane propoxylated | |
260. | 25810 | 015625-89-5 | 1,1,1-Trimethyololpropane triacrylate | |
261. | 25840 | 003290-92-4 | 1,1,1-Trimethylolpropane trimethacrylate | |
262. | 25900 | 000110-88-3 | Trioxane | |
263. | As item 254 | 000102-71-6 | Tris(2-hydroxyethyl)amine | |
264. | 25930 | 001067-53-4 | Tris(2-methoxyethoxy)-vinylsilane | The quantity of this substance in the finished plastic material or article shall not exceed 5 mg/kg. |
265. | 26140 | 000075-38-7 | Vinylidene fluoride | The specific migration of this substance shall be not detectable (when measured by a method with a limit of detection of 0.05 mg/kg). |
266. | 26170 | 003195-78-6 | N-Vinyl-N-methylacetamide | The quantity of this substance in the finished plastic material or article shall not exceed 5 mg/kg. |
267. | 26200 | 002867-48-3 | N-Vinyl-N-methylformamide | |
268. | 26230 | 000088-12-0 | Vinylpyrrolidone | |
269. | 26260 | 001184-84-5 | Vinylsulphonic acid | |
270. | 26290 | 025013-15-4 | Vinyhltoluene | |
271. | As item 216 | 000622-97-9 | p-Vinyltoluene | |
272. | 26320 | 002768-02-7 | Vinyltrimethoxysilane | The quantity of this substance in the finished plastic material or article shall not exceed 5 mg/kg. |
273. | As item 109 | 000105-67-9 | m-Xylenol | |
274. | As item 108 | 000526-75-0 | o-Xylenol | |
275. | As item 110 | 000095-87-4 | p-Xylenol |
SECTION CMonomers authorised until 1st April 1995
1 | 2 | 3 | 4 | |
---|---|---|---|---|
Item | PM/REF No. | CASNo. | Name | Restrictions |
1. | 10180 | 000556-08-1 | p-(Acetylamino)benzoic acid | |
2. | 10240 | Acids, aliphatic, dicarboxylic, esters with alcohols, aliphatic, monohydric | ||
3. | 10270 | Acids, aliphatic, dicarboxylic (C3-C12), esters with alcohols, unsaturated (C3-C18) | ||
4. | 10300 | Acids, aliphatic, dicarboxylic, saturated (C4-C18) | ||
5. | 10330 | Acids, aliphatic, dicarboxylic, unsaturated (C4-C12) | ||
6. | 10360 | Acids, aliphatic, dicarboxylic, unsaturated, esters with polyethyleneglycol | ||
7. | 10390 | Acids, aliphatic, dicarboxylic, unsaturated, esters with polypropyleneglycol | ||
8. | 10420 | Acids, aliphatic, mono- and dicarboxylic (C2-C20), vinyl esters | ||
9. | 10450 | Acids, aliphatic, monocarboxylic (C3-C12), esters with alcohols, unsaturated (C3-C18) | ||
10. | 10540 | Acids, aliphatic, monocarboxylic, unsaturated (C3-C8), esters with alcohols, aliphatic, monohydric, saturated (C2-C12) | ||
11. | 10570 | Acids, aliphatic, monocarboxylic, unsaturated, esters with polypropyleneglycol | ||
12. | 10630 | 000079-06-1 | Acrylamide | |
13. | 10870 | 002206-89-5 | Acrylic acid, 2-chloroethyl ester | |
14. | 10900 | Acrylic acid, cyclohexylaminoethyl ester | ||
15. | 10960 | 016868-13-6 | Acrylic acid, cyclopentyl ester | |
16. | 11290 | Acrylic acid, esters with alcohols, aliphatic, monohydric, saturated (C1-C21) | ||
17. | 11320 | Acrylic acid, esters with alcohols, aliphatic, monohydric, unsaturated (C4-C18) | ||
18. | 11350 | Acrylic acid, esters with alcohols, aliphatic, polyhydric (C2-C21) | ||
19. | 11380 | Acrylic acid, esters with etheralcohols | ||
20. | 11410 | Acrylic acid, esters with glycolethers obtained from mono- and/or diglycols with alcohols, aliphatic, monohydric (C1-C18) | ||
21. | 11440 | 044992-01-0 | Acrylic acid, ester with trimethylethanolammonium chloride | |
22. | 11920 | 005048-82-8 | Acrylic acid, phenylaminoethyl ester | |
23. | 11950 | 000937-41-7 | Acrylic acid, phenyl ester | |
24. | 12070 | 002177-18-6 | Acrylic acid, vinyl ester | |
25. | 12400 | Alcohols, aliphatic, monohydric, unsaturated (up to C18) | ||
26. | 12430 | Alcohols, aliphatic, polyhydric (up to C18) | ||
27. | 12460 | Alcohols, cycloaliphatic, mono- and/or polyhydric, substituted (up to C18) | ||
28. | 12490 | Aldehydes (C4) | ||
29. | 12520 | Alkadienes | ||
30. | 12550 | n-Alkenes (up to C16) | ||
31. | 12580 | p-Alkyl (C4-C9) phenols | ||
32. | 12670 | 002855-13-2 | 1-Amino-3-aminomethyl-3,5,5-trimethylcyclohexane | |
33. | 12730 | 000060-32-2 | 6-Aminocaproic acid | |
34. | 12670 | omega-Aminocarboxylic acids, aliphatic, linear (C6-C12) | ||
35. | 12880 | 000123-98-8 | Azelaic acid dichloride | |
36. | 12940 | 004080-88-0 | Azelaic acid, diphenyl ester | |
37. | 13030 | 000539-48-0 | 1,4-Benzenedimethanamine | |
38. | 13120 | 000769-78-8 | Benzoic acid, vinyl ester | |
39. | 13180 | 000498-66-8 | Bicyclo[2.2.1]hept-2-ene | |
40. | 13240 | 003377-24-0 | 2,2-Bis(4-aminocyclohexyl)propane | |
41. | 13300 | 038050-97-4 | 1,4-Bis(4',4'-dihydroxytriphenylmethyl)benzene | |
42. | 13330 | Bis(2-hydroxyethyl) ether of hydroquinone and its condensation products with propylene oxide | ||
43. | 13360 | 001620-68-4 | 2,6-Bis(2-hydrowy-5-methylbenzyl)-4-methylphenol | |
44. | 13420 | 000843-55-0 | 1,1-Bis(4-hydroxyphenyl)cyclohexane | |
45. | 13450 | 000125-13-3 | 3,3-Bis(4-hydroxyphenyl)-2-indolinone | |
46. | 13570 | 000141-07-1 | 1,3-Bis(methoxymethyl)urea | |
47. | 13930 | 006117-91-5 | But-2-en-1-ol | |
48. | 13990 | 005153-77-5 | N-(Butoxymethyl)methacrylamide | |
49. | 14050 | 000111-34-2 | Butyl vinyl ether | |
50. | 14080 | 000926-02-3 | tert.-Butyl vinyl ether | |
51. | 14290 | Caprolactone, substituted | ||
52. | 14440 | 064147-40-6 | Castor oil, dehydrated | |
53. | 14470 | 008001-78-3 | Castor oil, hydrogenated | |
54. | 14590 | 000615-67-8 | Chlorohydroquinone | |
55. | 14620 | 057981-99-4 | Chlorohydroquinone diacetate | |
56. | 14830 | Crotonic acid, esters with alcohols, mono- and polyhydric | ||
57. | 14860 | Cycloalkenes | ||
58. | 14920 | 002842-38-8 | 2-(Cyclohexylamino)ethanol | |
59. | 15010 | 001131-60-8 | p-Cyclohexylphenol | |
60. | 15040 | 000542-92-7 | Cyclopenta-1,3-diene | |
61. | 15160 | 000765-05-9 | Decyl vinyl ether | |
62. | 15190 | Diamines, aliphatic, linear (C2-C12) | ||
63. | 15430 | 003749-77-7 | 4,4'-Dicarboxydiphenoxybutane | |
64. | 15460 | 003753-05-7 | 4,4'-Dicarboxydiphenoxyethane | |
65. | 15520 | 004919-48-6 | 4,4'-Dicarboxydiphenyl sulphide | |
66. | 15550 | 002449-35-6 | 4,4'-Dicarboxydiphenyl sulphone | |
67. | 15640 | 000156-59-2 | cis-1,2-Dichloroethylene | |
68. | 15670 | 000156-60-5 | trans-1,2-Dichloroethylene | |
69. | 16030 | 001965-09-9 | 4,4'-Dihydroxydiphenyl ether | |
70. | 16060 | 002664-63-3 | 4,4'-Dihydroxydiphenyl sulphide | |
71. | 16420 | 000123-91-1 | Dioxane | |
72. | 16720 | 000826-62-0 | Endomethylenetetrahydrophthalic anhydride | |
73. | 16810 | Ether alcohols | ||
74. | 16840 | Ethers of N-methylolacrylamide | ||
75. | 16870 | Ethers of N-methylolmethacrylamide | ||
76. | 16930 | 000075-00-3 | Ethyl chloride | |
77. | 17080 | 000103-44-6 | 2-Ethylhexyl vinyl ether | |
78. | 17140 | 000109-92-2 | Ethyl vinyl ether | |
79. | 17410 | Fumaric acid, esters with alcohols, aliphatic, monohydric, saturated (C1-C18) | ||
80. | 17440 | Fumaric acid, esters with alcohols, aliphatic, monohydric, unsaturated (C1-C18) | ||
81. | 17470 | Fumaric acid, esters with alcohols, polyhydric | ||
82. | 17500 | 000098-01-0 | Furfural | |
83. | 17560 | Glucosides obtained from glucose and butan-1,3-diol | ||
84. | 17590 | Glucosides obtained from glucose and butan-1,4-diol | ||
85. | 17620 | Glucosides obtained from glucose and diethyleneglycol | ||
86. | 17650 | Glucosides obtained from glucose and 2,2-dimethylpropan-1,3-diol | ||
87. | 17680 | Glucosides obtained from glucose and ethyleneglycol | ||
88. | 17710 | Glucosides obtained from glucose and glycerol | ||
89. | 17740 | Glucosides obtained from glucose and hexan-1,6-diol | ||
90. | 17770 | Glucosides obtained from glucose and hexan-1,2,6-triol | ||
91. | 17890 | Glucosides obtained from glucose and propanediol | ||
92. | 17920 | Glucosides obtained from glucose and sorbitol | ||
93. | 17950 | Glucosides obtained from glucose and sucrose | ||
94. | 17980 | Glucosides obtained from glucose and 1,1,1-trimethylolpropane | ||
95. | 18040 | 029733-18-4 | Glutaric acid, diisodecyl ester | |
96. | 18130 | 004371-64-6 | 1,1-Heptadecanedicarboxylic acid | |
97. | 18160 | 025339-56-4 | Heptene | |
98. | 18190 | 000592-76-7 | Hept-1-ene | |
99. | 18250 | 000115-28-6 | Hexachloroendomethylenetetrahydrophthalic acid | The quantity of this substance in the finished plastic material or article shall not exceed 5 mg/kg. |
100. | 18280 | 000115-27-5 | Hexachloroendomethylenetetrahydrophthalic anhydride | |
101. | 18340 | 000822-28-6 | Hexadecyhl vinyl ether | |
102. | 18430 | 000116-15-4 | Hexafluoropropylene | |
103. | 18520 | 038775-37-0 | Hexamethylenediamine azelate | |
104. | 18550 | Hexamethylenediamine dodecanedicarboxylate | ||
105. | 18580 | Hexamethylenediamine heptadecanedicarboxylate | ||
106. | 18670 | 000100-97-0 | Hexamethylenetetramine | |
107. | 18730 | 002935-44-6 | Hexan-2,5-diol | |
108. | 18760 | 000106-69-4 | Hexan-1,2,6-triol | |
109. | 18790 | 025264-93-1 | Hexene | |
110. | 18910 | 000288-32-4 | Imidazole | |
111. | 18940 | 000095-13-6 | Indene | |
112. | 19240 | 000744-45-6 | Isophthalic acid, diphenyl ester | |
113. | 19300 | 002155-60-4 | Itaconic acid, dibutyl ester | |
114. | 19330 | 007748-43-8 | Itaconic acid, 2,3-eposypropyl diester | The quantity of this substance in the finished plastic material or article shall not exceed 5 mg/kg. |
115. | 19360 | Itaconic acid, 2,3-epoxypropyl monoester | The quantity of this substance in the finished plastic material or article shall not exceed 5 mg/kg. | |
116. | 19390 | Itaconic acid, esters with alcohols, aliphatic, monohydric, saturated (C1-C18) | ||
117. | 19420 | Itaconic acid, esters with alcohols, polyhydric | ||
118. | 19450 | Latcams of omega-aminocarboxylic acids, aliphatic, linear (C7-C12) | ||
119. | 19630 | 071550-61-3 | Maleic acid, diester with propan-1,2-diol | |
120. | 19780 | 002915-53-9 | Maleic acid, dioctyl ester | |
121. | 19810 | Maleic acid, esters with alcohols, aliphatic, saturated (C1-C18) | ||
122. | 19840 | Maleic acid, esters with alcohols, polyhydric | ||
123. | 19870 | Maleic acid, ester with butan-1,3-diol | ||
124. | 19900 | 002424-58-0 | Maleic acid, monoallyl ester | |
125. | 19930 | Maleic acid, monoesters with alcohols, aliphatic, monohydric, unsaturated (C3-C18) | ||
126. | 20230 | Methacrylic acid, cyclohexylaminoethyl ester | ||
127. | 20290 | 016868-14-7 | Methacrylic acid, cyclopentyl ester | |
128. | 20350 | Methacrylic acid, (di-tert.-butylamino)ethyl ester | ||
129. | 20500 | 000105-16-8 | Methacrylic acid, 2-(diethylamino)ethyl ester | |
130. | 20620 | Methacrylic acid, esters with alcohols, aliphatic, monohydric, saturated (C1-C21) | ||
131. | 20650 | Methacrylic acid, esters with alcohols, aliphatic, monohydric, unsaturated (C4-C18) | ||
132. | 20680 | Methacrylic acid, esters with alcohols, polyhydric (C2-C21) | ||
133. | 20710 | Methacrylic acid, esters with etheralcohols | ||
134. | 20770 | Methacrylic acid, esters with glycolethers obtained from mono- and/or diglycols with alcohols, aliphatic, monohydric (C1-C18) | ||
135. | 20800 | 024493-59-2 | Methacrylic acid, ester with methoxytriethyleneglycol | |
136. | 20860 | Methacrylic acid, ester with trimethylethanolammonium chloride | ||
137. | 21160 | Methacrylic acid, monoester with butan-1,3-diol | ||
138. | 21310 | 003683-12-3 | Methacrylic acid, phenylethyl ester | |
139. | 21580 | 003644-11-9 | N-(Methoxymethyl)-acrylamide | |
140. | 21610 | 003644-12-0 | N-(Methoxymethyl)-metharcylamide | |
141. | 21700 | 000513-35-9 | 2-Methylbut-2-ene | |
142. | 21790 | 000110-26-9 | Methylenebisacrylamide | |
143. | 21820 | 013093-19-1 | Methylenebiscaprolactam | |
144. | 21910 | 000814-78-8 | Methyl isopropenyl ketone | |
145. | 21940 | 000924-42-5 | N-Methylolacrylamide | |
146. | 22000 | 001118-58-7 | 2-Methylpent-1,3-diene | |
147. | 22030 | 001115-08-8 | 3-Methylpent-1,4-diene | |
148. | 22060 | 000926-56-7 | 4-Methylpent-1,3-diene | |
149. | 22090 | 000763-29-1 | 2-Methylpent-1-ene | |
150. | 22120 | 000760-20-3 | 3-Methylpent-1-ene | |
151. | 22150 | 000691-37-2 | 4-Methylpent-1-ene | |
152. | 22180 | 004461-48-7 | 4-Methylpent-2-ene | |
153. | 22300 | 000078-94-4 | Methyl vinyl ketone | The quantity of this substance in the finished plastic material or article shall not exceed 5 mg/kg. |
154. | 22330 | 001822-74-8 | Methyl vinyl thioether | |
155. | 22510 | 027215-95-8 | Nonene | |
156. | 22580 | 000930-02-9 | Octadecyl vinyl ether | |
157. | 22630 | 025377-83-7 | Octene (except oct-1-ene) | |
158. | 22750 | 000929-62-4 | Octyl vinyl ether | |
159. | 22810 | 000504-60-9 | Pent-1,3-diene | |
160. | 22930 | Perfluoroalkyl(C1-C3)vinyl ethers | ||
161. | 22990 | Phenols, mono- and dihydric, alkoxylated or hydrogenated | ||
162. | 23020 | 028994-41-4 | alpha-Penyl-o-cresol | |
163. | 23080 | 001079-21-6 | Phenylhydroquinone | |
164. | 23110 | 058244-28-3 | Phenylhydroquinone diacetate | |
165. | 23230 | 000131-17-9 | Phthalic acid, diallyl ester | |
166. | 23260 | 000088-95-9 | o-Phthalic acid dichloride | |
167. | 23290 | Phthalic acids, halogenated derivatives | ||
168. | 23320 | Phthalic acids, hydrogenated | ||
169. | 23350 | Phthalic acids, hydrogenated, substituted, endosubstituted, and their halogenated derivatives | ||
170. | 23410 | Phthalic anhydride, hydrogenated | ||
171. | 23440 | 000111-16-0 | Pimelic acid | |
172. | 23560 | Polyethers based on ethylene oxide, propylene oxide and/or tetrahydrofuran, containing free hydroxyl groups | ||
173. | 23620 | Polyols derived from phenols and bisphenols hydrogenated and/or condensed with epoxyalkanes and/or arylepoxyalkanes possibly halogenated, alkoxylated, aryloxylated | ||
174. | 23680 | 009002-89-5 | Polyvinylalcohols | |
175. | 23710 | 063148-65-2 | Polyvinylbutyrals | |
176. | 24040 | 000764-47-6 | Propyl vinyl ether | |
177. | 24220 | 009006-03-5 | Rubber, chlorinated | |
178. | 24310 | 000111-19-3 | Sebacic acid, dichloride | |
179. | 24340 | 002432-89-5 | Sebacic acid, didecyl ester | |
180. | 24400 | 002918-18-5 | Sebacic acid, diphenyl ester | |
181. | 24640 | Styrene, substituted by alkyl groups (alpha) | ||
182. | 24670 | Styrene, substituted in the benzene ring | ||
183. | 24700 | Styrene, substituted by halogens (alpha or beta) | ||
184. | 24730 | Styrene, substituted in the vinyl group | ||
185. | 24790 | 000505-48-6 | Suberic acid | |
186. | 25000 | 001539-04-4 | Terephthalic acid, diphenyl ester | |
187. | 25060 | 000632-58-6 | Tetrachlorophthalic acid | |
188. | 25330 | 000070-55-3 | p-Toluenesulphonamide | |
189. | 25570 | 000067-48-1 | Trimethylethanolammonium chloride | |
190. | 25660 | 019727-16-3 | 1,1,1-Trimethylolpropane dimethacrylate | |
191. | 25690 | 1,1,1-Trimethylolpropane maleates | ||
192. | 25720 | 007024-08-0 | 1,1,1-Trimethylolpropane monoacrylate | |
193. | 25750 | 007024-09-1 | 1,1,1-Trimethylolpropane monomethacrylate | |
194. | 25870 | 000107-39-1 | 2,4,4-Trimethylpent-1-ene | |
195. | 25990 | 000689-97-4 | Vinylacetylene | The quantity of this substance in the finished plastic material or article shall not exceed 5 mg/kg. |
196. | 26020 | 001484-13-5 | N-Vinylcarbazole | The quantity of this substance in the finished plastic material or article shall not exceed 5 mg/kg. |
197. | 26080 | Vinyl ethers of alcohols, aliphatic, monohydric, saturated (C2-C18) | ||
198. | 26140 | 000075-38-7 | Vinylidene fluoride |
PART IISUPPLEMENTARY
1
In regulation 5 and Part I of this Schedule—
a
the PM/REF No. of any substance is its EEC packaging material reference number,
b
the CASNo. of any substance is its CAS (Chemical Abstracts Service) Registry Number, and
c
the name of any substance is its chemical name,
and to the extent that there is any inconsistency between the CASNo. and the name, the name shall take precedence over the CASNo.
2
If a substance appearing in Part I of this Schedule as an individual compound also falls within a generic term which appears therein, the restriction (if any) applying to that substance shall be that indicated for the individual compound and the entry applying to the generic term shall be treated as varied to such extent (if any) as is necessary therefor.
3
1
The items identified in Part I of this Schedule—
a
shall be taken to include—
i
substances undergoing polymerisation (which shall be taken to include polyconden sation, polyaddition or any other similar process) to manufacture macromolecules,
ii
natural or synthetic macromolecular substances used in the manufacture of modified macromolecules, if the monomers required to synthesise them are not so identified, and
iii
substances used to modify existing natural or synthetic macromolecular substances.
2
a
If a substance identified in Part I of this Schedule is an acid, a phenol or an alcohol and has salts (including double salts) of one or more of the following names (that is to say salts (including double salts) of aluminium, ammonium, calcium, iron, magnesium, potassium, sodium or zinc), then any such salts (including double salts) shall be treated as included in the specification of that substance.
b
If a substance is identified in Part I of this Schedule as an . . . acid, salt and has salts of one or more of the following names (that is to say salts of aluminium, ammonium, calcium, iron, magnesium, potassium, sodium or zinc), then the free acid corresponding to that substance is not treated as included in the specification of that substance.
SCHEDULE 2
PART IPROVISIONS APPLICABLE WHEN CHECKING COMPLIANCE WITH THE MIGRATION LIMITS
A. General provisions
1
When the results of the migration tests specified in this Schedule are analytically determined the specific gravity of any simulants used shall be assumed to be 1, so that milligrams of any substance released per litre of simulant will correspond numerically to milligrams of that substance released per kilogram of that simulant.
2
Where any migration test specified in this Schedule is carried out on any sample taken from any plastic material or article and the quantities of food or simulant placed in contact with the sample differ from those employed in the actual conditions under which the plastic material or article is used or is to be used, the results obtained should be corrected by applying the following formula:
M is the migration in mg/kg;
m is the mass in mg of substance released by the sample as determined by the migration test;
a1 is the surface area in square decimetres of the sample in contact with the food or simulant during the migration test;
a2 is the surface area in square decimetres of the plastic material or article in actual conditions of use;
q is the quantity in grams of food in contact with the plastic material or article in actual conditions of use.
3
1
Subject to sub-paragraph (2) below, any testing of migration from any plastic material or article shall be carried out on that plastic material or article.
2
In any case where determination in accordance with sub-paragraph (1) above is impracti-cable, such testing shall be carried out, using either specimens taken from that plastic material or article or, where appropriate, specimens representative of that plastic material or article.
3
Any sample used for such testing shall be placed in contact with the simulant or food, as the case may be, in a manner representing the contact conditions in actual use, and, for this purpose, the testing shall be carried out in such a way that only those parts of the sample intended to come into contact with food in actual use will be in contact with the simulant or food.
4
Any migration testing of caps, gaskets, stoppers or similar devices for sealing shall be carried out on these articles by applying them to the containers for which they are intended in a manner which corresponds to the conditions of closing in normal or foreseeable use.
4
1
Any sample of a plastic material or article shall be placed in contact with the appropriate simulant or the food for a period and at a temperature which are chosen by reference to the contact conditions in actual use in accordance with the provisions of this Schedule.
2
At the end of the period referred to in sub-paragraph (1) above, analytical determination of the total quantity of substances (overall migration), each specific quantity of a substance (specific migration) or, as the case may be, both that total and that specific quantity released by the sample shall be carried out on the simulant or food, as the case may be.
5
Where a plastic material or article is intended to come into repeated contact with food, any migration test shall (subject to paragraph 7 below) be carried out three times on a single sample in accordance with the conditions laid down in this Schedule using separate samples of the simulant or, as the case may be, food on each occasion, and the level of the migration found in the third test shall be treated as the level relevant to that test.
B. Special provisions relating to overall migration
6
1
Subject to the following sub-paragraphs of this paragraph, any method of analytical determination may be used to prove excess of an overall migration limit in relation to a plastic material or article.
2
In any proceedings for an offence under regulation 3 comprising excess of an overall migration limit, it shall be a defence for the person charged to prove that—
a
if an aqueous simulant specified in this Schedule had been used, and the analytical determination of the total quantity of substances released by a sample of the plastic material or article tested had been carried out by evaporation of the simulant and weighing of the residue, or
b
if rectified olive oil or any of its substitutes had been used as a simulant and—
i
a sample of the plastic material or article had been weighed before and after contact with the simulant,
ii
the simulant absorbed by the sample had been extracted and determined quantitatively,
iii
the quantity of simulant so found had been subtracted from the weight of the sample measured after contact with the simulant, and
iv
the difference between the initial and corrected final weights had been determined to represent the overall migration of the sample examined,
there would have been no such excess so determined.
7
1
Where a plastic material or article is intended to come into repeated contact with food and it is technically impossible to carry out the test described in paragraph 5 above, the test shall be so modified as to enable the level of migration occurring during the third such test to be determined and, subject to sub-paragraph (2) below, such a determination may be used to prove excess of an overall migration limit in relation to a plastic material or article.
2
In any procedures for an offence under regulation 3 comprising excess of an overall migration limit as determined under sub-paragraph (1) above, it shall be a defence for the person charged to prove that, if—
a
three identical samples of the plastic material or article had been procured,
b
one of them had been subjected to the appropriate test according with paragraph 4 above and the overall migration determined (M1),
c
the second and third samples had been subjected to the same conditions of temperature but the period of contact had been two and three times that specified and overall migration had been determined in each case (M2 and M3, respectively), and
d
the plastic material or article had been deemed to comply with the overall migration limit relevant to it provided that either M1 or M3 − M2 did not exceed that overall migration limit,
the plastic material or article would not have been deemed to exceed that limit.
8
1
Any plastic material or article which exceeds its overall migration limit by an amount not exceeding the analytical tolerance specified in sub-paragraph (2) below shall be deemed for the purposes of these Regulations not to exceed its overall migration limit.
2
The following analytical tolerances shall be applied for limits of overall migration—
a
20 mg/kg or, as the case may be, 3 milligrams per square decimetre in migration tests using as a simultant rectified olive oil or substitutes,
b
6 mg/kg or, as the case may be, 1 milligram per square decimetre in migration tests using other simulants referred to in this Schedule.
PART IISIMULANTS TO BE USED IN MIGRATION TESTS
1
Subject to the provisions of this Schedule, the simulants which may be used in migration testing are as follows—
Simulant A: distilled water or water of equivalent quality;
Simulant B 3% acetic acid (w/v) in aqueous solution;
Simulant C 15% ethanol (v/v) in aqueous solution;
Simulant D: Rectified olive oil, save that if for technical reasons connected with the method of analysis it is necessary to use a different simulant, rectified olive oil shall be replaced by a mixture of synthetic triglycerides or by sunflower oil.
2
The particulars of simulant D referred to in paragraph 1 above are as hereinafter described:
a
the characteristics of rectified olive oil shall be as follows—
Iodine value (Wijs) | =80 to 88 |
Refractive index at 25°C | = 1.4665 to 1.4679 |
Acidity (expressed as % of oleic acid) | = 0.5% maximum |
Peroxide number (expressed as oxygen milliequivalents per kg of oil) | = 10 maximum |
b
the composition of the synthetic triglycerides mixture shall be as follows—
i
fatty acid distribution
No of C—atoms in fatty acid
residue… | 6 | 8 | 10 | 12 | 14 | 16 | 18 | others |
GLC area (%)… | ~1 | 6—9 | 8—11 | 45—52 | 12—15 | 8—10 | 8—12 | <=1 |
ii
purity
Content of monoclycerides (enzymatically) | ≤0.2% |
Content of diglyceride(enzymatically) | ≤2.0% |
Unsaponifiable matter | ≤0.2% |
Iodine value (Wijs) | ≤0.1% |
Acid value | ≤0.1% |
Water content (K. Fischer) | ≤0.1% |
Melting point | 28±2°C |
iii
typical absorption spectrum (thickness of layer: d=1 cm; Reference: water at 35°C)
Wavelength (nm) | 290 | 310 | 330 | 350 | 370 | 390 | 430 | 470 | 510 |
Transmittance (%) | ~2 | ~15 | ~37 | ~64 | ~80 | ~88 | ~95 | ~97 | ~98 |
At least 10% light transmittance at 310 nm (cell of 1 cm, reference: water at 35°C)
- a
characteristics of sunflower oil shall be as follows—
Iodinevalue (Wijs)
= 120 to 145
Refractive index at 20°C
= 1.474 to 1.476
aponification number
= 188to 193
Relative density at 20°C
0.918 to 0.925
Unsaponifiablematter
= 0.5% to 1.5%
- a
PART IIISPECIFICATION OF SIMULANTS TO BE USED
1
1
Subject to the provisions of this Part of this Schedule, capability of migration into food shall be treated for the purposes of these Regulations as being determined by carrying out the migration test described in this Schedule—
a
in any case where a simultant is specified in the Table to this Schedule, either on the simulant or on the food; and
b
in any case where the food is not specified in that table, either on the simulant which corresponds most closely in extractive capacity to the food or on the food.
2
A simulant is specified in relation to a food for the purposes of this paragraph where ‘X’ is placed in the column headed by that simulant opposite the food in the Table to this Part of this Schedule, and the Table shall be read in conjunction with the notes thereto and the following paragraphs of this Part of this Schedule.
3
Where more than one simulant is to be used in relation to a migration test, a new sample of the plastic material or article shall be used for each such test.
2
Where, in the Table to this Part of this Schedule, “X” is followed by an oblique stroke and a figure, the result of any migration test on the simulant shall be divided by the number indicated.
3
Where, in the Table to this Part of this Schedule, the letter “a” is shown in brackets after the “X”, only one of the two simulants specified shall be used in the migration test, that is to say—
a
if the pH value of the food is higher than 4.5, simulant A shall be used,
b
if the pH value of the foodstuff is 4.5 or less, simulant B shall be used.
4
Where a food is listed in the Table to this Part of this Schedule under both a specific and a general heading, the simulant relating to the specific heading is the simulant which falls to be used for the migration test.
Simulants to be used | |||||
---|---|---|---|---|---|
Reference Number | Description of food | A | B | C | D |
01 | Beverages | ||||
01.01 | Non-alcoholic beverages or alcoholic beverages of an alcoholic strength lower than 5% vol.:
| X(a) | X(a) | ||
01.02 | Alcoholic beverages of an alcoholic strength equal to or exceeding 5% vol.:
| X((**)) | X((*)) | ||
01.03 | Miscellaneous undenatured ethyl alcohol | X((**)) | X((*)) | ||
02 | Cereals, cearal products, pastry, biscuits, cakes and other bakers' wares | ||||
02.01 | Starches | ||||
02.02 | Cereals, unprocessed, puffed, in flakes (including popcorn, cornflakes and the like) | ||||
02.03 | Cereal flour and meal | ||||
02.04 | Macaroni, spaghetti and similar products | ||||
02.05 | Pastry, biscuits, cakes and other bakers' wares, dry: | ||||
| X/5 | ||||
| |||||
02.06 | Pastry, cakes and other bakers' wares, fresh: | ||||
| X/5 | ||||
| X | ||||
03 | Chocolate, sugar and products thereof, Confectionery products | ||||
03.01 | Chocolate, chocolate-coated products, substitutes and products coated with substitutes | X/5 | |||
03.02 | Confectionery products:
| ||||
| X/5 | ||||
| |||||
| |||||
| X/3 | ||||
| X | ||||
03.03 | Sugar and sugar products | ||||
| |||||
| X | ||||
| X | ||||
04 | Fruit, vegetables and products thereof | ||||
04.01 | Whole fruit, fresh or chilled | ||||
04.02 | Processed fruit: | ||||
| |||||
| X(a) | X(a) | |||
| |||||
| X(a) | X(a) | |||
| X(a) | X(a) | X | ||
| X((**)) | X | |||
04.03 | Nuts (peanuts, chestnuts, almonds, hazalnuts, walnuts, pine kernels and others) | ||||
| |||||
| X/5((*)) | ||||
| X | X/3((*)) | |||
04.04 | Whole vegetables, fresh or chilled | ||||
04.05 | Processed vegetables: | ||||
| |||||
| X(a) | X(a) | |||
| |||||
| X(a) | X(a) | |||
| X(a) | X(a) | X | ||
| X((**)) | X | |||
05 | Fats and oils | ||||
05.01 | Animal and vegetable fats and oils, whether natural or treated (including cocoa butter, lard, resolidified butter) | X | |||
05.02 | Margarine, butter and other fats and oils made from water emulsions in oil | X/2 | |||
06 | Animal products and eggs | ||||
06.01 | Fish: | ||||
| X | X/3((**)) | |||
| X | X/3((**)) | |||
06.02 | Crustaceans and mulluscs (including oysters,mussels, snails) not naturally protected by their shells | X | |||
06.03 | Meat of all zoological species (including poultry and game): | ||||
| X | X/4 | |||
| X | X/4 | |||
06.04 | Processed meat products (ham, salami, bacon and other) | X | X/4 | ||
06.05 | Preserved and part-preserved meat and fish: | ||||
| X(a) | X(a) | |||
| X(a) | X(a) | X | ||
06.06 | Eggs not in shell: | ||||
| |||||
| X | ||||
06.07 | Egg yolks: | ||||
| X | ||||
| |||||
06.08 | Dried white of egg | ||||
07 | Milk products | ||||
07.01 | Milk: | ||||
| X | ||||
| X | ||||
| X | ||||
| |||||
07.02 | Fermented milk such as yoghurt, buttermilk and such products in association with fruit and fruit products | X | |||
07.03 | Cream and sour cream | X(a) | X(a) | ||
07.04 | Cheeses: | ||||
| |||||
| X(a) | X(a) | |||
| X(a) | X(a) | X/3((**)) | ||
07.05 | Rennet: | ||||
| X(a) | X(a) | |||
| |||||
08 | Miscellaneous products | ||||
08.01 | Vinegar | X | |||
08.02 | Fresh or roasted foods: | ||||
| X/5 | ||||
| X/4 | ||||
08.03 | Preparations for soups, broths in liquid, solid or powder form (extracts, concentrates), homogenized composite food preparations, prepared dishes:
| ||||
| X/5 | ||||
| |||||
| |||||
| Z(a) | X(a) | X/3 | ||
| X(a) | X(a) | |||
08.04 | Yeasts and raising agents: | ||||
| X(a) | X(a) | |||
| |||||
08.05 | Salt | ||||
08.06 | Sauces: | ||||
| X(a) | X(a) | |||
| X(a) | X(a) | X/3 | ||
| X(a) | X(a) | X | ||
08.07 | Mustard (except powdered mustard under heading 08.17) | X(a) | X(a) | X/3((**)) | |
08.08 | Sandwichs, toasted bread and the like containing any kind of foodstuff: | ||||
| X/5 | ||||
| |||||
08.09 | Ice-cream | X | |||
08.10 | Dried foods: | ||||
| X/5 | ||||
| |||||
08.11 | Frozen or deep-frozen foods | ||||
08.12 | Concentrated extracts of an alcoholic strength equal to or exceeding 5% vol. | X((*)) | X | ||
08.13 | Cocoa: | ||||
| X/5((**)) | ||||
| X/3((**)) | ||||
08.14 | Coffee, whether or not roasted, decaffeinated or soluble, coffee substitutes, granulated or powdered | ||||
08.15 | Liquid coffee extracts | X | |||
08.16 | Aromatic herbs and other herbs: Camomile, mallow, mint, tea, lime blossom and others | ||||
08.17 | Spices and seasonings in the natural state: Cinnamons, cloves, powdered mustard, pepper, vanilla, saffron and other | ||||
(**) If it can be demonstrated under regulation 10 or proved by means of an appropriate test that there is to be no fatty contact with the plastic material or article, simulant D shall not be used. | |||||
(*) Simulant B shall not be used where the pH is more than 4.5. |
PART IVTEST CONDITIONS (TIMES AND TEMPERATURES)
1
Subject to paragraph 2 below—
a
the migration tests shall be carried out, selecting from the times and temperatures specified in the Table to this Part of this Schedule those which correspond most closely to the normal or foreseeable conditions of contact for the plastic material or article being studied;
b
if a plastic material or article is intended to be used successively at short intervals in several of the conditions of contact referred to in column 1 of the table, migration will be determined by subjecting that plastic material or article successively to each correspond ing test condition specified in column 2, using the same simulant;
c
where the plastic material or article may in actual use be employed under any conditions of contact time or temperature, the 10-day tests at 40°C and the two-hour tests at 70°C shall be carried out to test migration, except that, where simulant D is used (rectified olive oil or any of its substitutes), only the 10-day test at 40°C shall be carried out.
2
If it is found that carrying out the tests required by paragraph 1 above under the conditions specified in the table causes physical or other changes in the plastic material or article, the migration tests shall be carried out under conditions more appropriate to the specific case.
3
The Table to this Part of this Schedule shall be read with the footnotes to it.
Conditions of contact in actual use | Test conditions | |
---|---|---|
1 | 2 | |
1. | Contact time: t >24 hours | |
1.1 T ≤5°C | 10 days at 5°C | |
1.2 5°C <T ≤40°C(1) | 10 days at 40°C | |
2. | Contact time: two hours ≤ t ≤24 hours | |
2.1 T <5°C | 24 hours at 5°C | |
2.2 5°C <T ≤40°C | 24 hours at 40°C | |
2.3 40°C<T ≤70°C | 24 hours at 70°C | |
2.4 70°C <T ≤100°C | 24 hours at 100°C | |
3. | Contact time: t <two hours | |
3.1 T ≤5°C | Two hours at 5°C | |
3.2 5°C <T ≤40°C | Two hours at 40°C | |
3.3 40°C <T ≤70°C | Two hours at 70°C | |
3.4 70°C <T ≤100°C | One hour at 100°C* | |
3.5 1000°C <T ≤121°C(2) | 30 minutes at 121°C | |
3.6 121°C <T ≤130°C(2) | 30 minutes at 130°C | |
3.7 130°C <T ≤150°C(2) | 30 minutes at 150°C | |
3.8 T >150°C | 30 minutes at 175°C | |
(1) For plastic materials in contact with foodstuffs for which a preservation temperature of less than 20°C is specified on the labelling or by law, the test conditions will be 10 days at 20°C. | ||
(2) Use only simulant D at these temperatures, in addition to simulants A, B and C as appropriate, at 100°C or at reflux temperature. | ||
* or reflux temperature. |