An engine cooling system with sufficient capacity to maintain the engine at normal operating temperatures prescribed by the manufacturer.
Specifications of the lubricating oil used for the test shall be recorded and presented with the results of the test.
The cetane number and the sulphur content of the reference fuel used for test shall be recorded at sections 1.1.1 and 1.1.2 respectively of [Annex VII], Appendix 1.
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
At least one hour before the test, each filter (pair) shall be placed in a closed, but unsealed, petri dish and placed in a weighing chamber for stabilization. At the end of the stabilization period, each filter (pair) shall be weighed and the tare weight shall be recorded. The filter (pair) shall then be stored in a closed petri dish or filter holder until needed for testing. If the filter (pair) is not used within eight hours of its removal from the weighing chamber, it must be reweighed before use.
The instrumentation and sample probes shall be installed as required. When using a full flow dilution system for exhaust gas dilution, the tailpipe shall be connected to the system.
The dilution system and the engine shall be started and warmed up until all temperatures and pressures have stabilized at full load and rated speed (section 3.6.2).
Warming up of the engine and the system shall be at maximum speed and torque in order to stabilize the engine parameters according to the recommendations of the manufacturer.
The output of the analysers shall be recorded on a strip chart recorder or measured with an equivalent data acquisition system with the exhaust gas flowing through the analysers at least during the last three minutes of each mode. If bag sampling is applied for the diluted CO and CO2 measurement (see Appendix 1, section 1.4.4), a sample shall be bagged during the last three minutes of each mode, and the bag sample analysed and recorded.
The particulate sampling can be done either with the single filter method or with the multiple filter method (Appendix 1, section 1.5). Since the results of the methods may differ slightly, the method used must be declared with the results.
For the single filter method the modal weighting factors specified in the test cycle procedure shall be taken into account during sampling by adjusting sample flow rate and/or sampling time, accordingly.
Sampling must be conducted as late as possible within each mode. The sampling time per mode must be at least 20 seconds for the single filter method and at least 60 seconds for the multi-filter method. For systems without bypass capability, the sampling time per mode must be a least 60 seconds for single and multiple filter methods.
The engine speed and load, intake air temperatur, fuel flow and air or exhaust gas flow shall be measured for each mode once the engine has been stabilized.
If the measurement of the exhaust gas flow or the measurement of combustion air and fuel consumption is not possible, it can be calculated using the carbon and oxygen balance method (see Appendix 1, section 1.2.3).
Any additional data required for calculation shall be recorded (see Appendix 3, sections 1.1 and 1.2).
After the emission test a zero gas and the same span gas will be used for re-checking. The test will be considered acceptable if the difference between the two measuring results is less than 2 %.
[Appendix 1
MEASUREMENT AND SAMPLING PROCEDURES
1. MEASUREMENT AND SAMPLING PROCEDURES (NRSC TEST) U.K.
Gaseous and particulate components emitted by the engine submitted for testing shall be measured by the methods described in Annex VI. The methods of Annex VI describe the recommended analytical systems for the gaseous emissions (Section 1.1) and the recommended particulate dilution and sampling systems (Section 1.2).
1.1. Dynamometer specification U.K.
An engine dynamometer with adequate characteristics to perform the test cycle described in Annex III, Section 3.7.1 shall be used. The instrumentation for torque and speed measurement shall allow the measurement of the power within the given limits. Additional calculations may be necessary. The accuracy of the measuring equipment must be such that the maximum tolerances of the figures given in point 1.3 are not exceeded.
1.2. Exhaust gas flow U.K.
The exhaust gas flow shall be determined by one of the methods mentioned in sections 1.2.1 to 1.2.4.
1.2.1. Direct measurement method U.K.
Direct measurement of the exhaust flow by flow nozzle or equivalent metering system (for detail see ISO 5167:2000).
Note: Direct gaseous flow measurement is a difficult task. Precautions must be taken to avoid measurement errors that will impact emission value errors. U.K.
1.2.2. Air and fuel measurement method U.K.
Measurement of the airflow and the fuel flow.
Air flow-meters and fuel flow-meters with the accuracy defined in Section 1.3 shall be used.
The calculation of the exhaust gas flow is as follows:
G EXHW = G AIRW + G FUEL (for wet exhaust mass)
1.2.3. Carbon balance method U.K.
Exhaust mass calculation from fuel consumption and exhaust gas concentrations using the carbon balance method (Annex III, Appendix 3).
1.2.4. Tracer measurement method U.K.
This method involves measurement of the concentration of a tracer gas in the exhaust. A known amount of an inert gas (e.g. pure helium) shall be injected into the exhaust gas flow as a tracer. The gas is mixed and diluted by the exhaust gas, but must not react in the exhaust pipe. The concentration of the gas shall then be measured in the exhaust gas sample.
In order to ensure complete mixing of the tracer gas, the exhaust gas sampling probe shall be located at least 1 m or 30 times the diameter of the exhaust pipe, whichever is larger, downstream of the tracer gas injection point. The sampling probe may be located closer to the injection point if complete mixing is verified by comparing the tracer gas concentration with the reference concentration when the tracer gas is injected upstream of the engine.
The tracer gas flow rate shall be set so that the tracer gas concentration at engine idle speed after mixing becomes lower than the full scale of the trace gas analyser.
The calculation of the exhaust gas flow is as follows:
where
G EXHW
=
instantaneous exhaust mass flow (kg/s)
G T
=
tracer gas flow (cm 3 /min)
conc mix
=
instantaneous concentration of the tracer gas after mixing, (ppm)
ρ EXH
=
density of the exhaust gas (kg/m 3 )
conc a
=
background concentration of the tracer gas in the intake air (ppm)
The background concentration of the tracer gas ( conc a ) may be determined by averaging the background concentration measured immediately before and after the test run.
When the background concentration is less than 1 % of the concentration of the tracer gas after mixing ( conc mix. ) at maximum exhaust flow, the background concentration may be neglected.
The total system shall meet the accuracy specifications for the exhaust gas flow and shall be calibrated according to Appendix 2, Section 1.11.2.
1.2.5. Air flow and air to fuel ratio measurement method U.K.
This method involves exhaust mass calculation from the air flow and the air to fuel ratio. The calculation of the instantaneous exhaust gas mass flow is as follows:
where
A/Fst
=
stoichiometric air/fuel ratio (kg/kg)
λ
=
relative air/fuel ratio
conc CO2
=
dry CO 2 concentration ( %)
conc CO
=
dry CO concentration (ppm)
conc HC
=
HC concentration (ppm)
Note: The calculation refers to a diesel fuel with a H/C ratio equal to 1,8. U.K.
The air flowmeter shall meet the accuracy specifications in Table 3, the CO 2 analyser used shall meet the specifications of clause 1.4.1, and the total system shall meet the accuracy specifications for the exhaust gas flow.
Optionally, air to fuel ratio measurement equipment, such as a zirconia type sensor, may be used for the measurement of the relative air to fuel ratio in accordance with the specifications of clause 1.4.4.
1.2.6. Total dilute exhaust gas flow U.K.
When using a full flow dilution system, the total flow of the dilute exhaust (G TOTW ) shall be measured with a PDP or CFV or SSV (Annex VI, Section 1.2.1.2) The accuracy shall conform to the provisions of Annex III, Appendix 2, Section 2.2.
1.3. Accuracy U.K.
The calibration of all measurement instruments shall be traceable to national or international standards and comply with the requirements listed in Table 3.
Table 3 — Accuracy of measuring instruments U.K.
No | Measuring instrument | Accuracy |
---|
1 | Engine speed | ± 2 % of reading or ± 1 % of engine's max. value whichever is larger |
2 | Torque | ± 2 % of reading or ± 1 % of engine's max. value whichever is larger |
3 | Fuel consumption | ± 2 % of engine's max. value |
4 | Air consumption | ± 2 % of reading or ± 1 % of engine's max. value whichever is larger |
5 | Exhaust gas flow | ± 2,5 % of reading or ± 1,5 % of engine's max. value whichever is larger |
6 | Temperatures ≤ 600 K | ± 2 K absolute |
7 | Temperatures > 600 K | ± 1 % of reading |
8 | Exhaust gas pressure | ± 0,2 kPa absolute |
9 | Intake air depression | ± 0,05 kPa absolute |
10 | Atmospheric pressure | ± 0,1 kPa absolute |
11 | Other pressures | ± 0,1 kPa absolute |
12 | Absolute humidity | ± 5 % of reading |
13 | Dilution air flow | ± 2 % of reading |
14 | Diluted exhaust gas flow | ± 2 % of reading |
1.4. Determination of the gaseous components U.K.
1.4.1. General analyser specifications U.K.
The analysers shall have a measuring range appropriate for the accuracy required to measure the concentrations of the exhaust gas components (section1.4.1.1). It is recommended that the analysers be operated in such a way that the measured concentration falls between 15 % and 100 % of full scale.
If the full scale value is 155 ppm (or ppm C) or less or if read-out systems (computers, data loggers) that provide sufficient accuracy and resolution below 15 % of full scale are used, concentrations below 15 % of full scale are also acceptable. In this case, additional calibrations are to be made to ensure the accuracy of the calibration curves – Annex III, Appendix 2, section 1.5.5.2.
The electromagnetic compatibility (EMC) of the equipment shall be on a level as to minimise additional errors.
1.4.1.1. Measurement error U.K.
The analyser shall not deviate from the nominal calibration point by more than ± 2 % of the reading or ± 0,3 % of full scale, whichever is larger.
NOTE: For the purpose of this standard, accuracy is defined as the deviation of the analyser reading from the nominal calibration values using a calibration gas (≡ true value) U.K.
1.4.1.2. Repeatability U.K.
The repeatability, defined as 2,5 times the standard deviation of 10 repetitive responses to a given calibration or span gas, must be no greater than ± 1 % of full scale concentration for each range used above 155 ppm (or ppm C) or ± 2 % of each range used below 155 ppm (or ppm C).
1.4.1.3. Noise U.K.
The analyser peak-to-peak response to zero and calibration or span gases over any 10-second period shall not exceed 2 % of full scale on all ranges used.
1.4.1.4. Zero drift U.K.
The zero drift during a one-hour period shall be less than 2 % of full scale on the lowest range used. The zero response is defined as the mean response, including noise, to a zero gas during a 30-second time interval.
1.4.1.5. Span drift U.K.
The span drift during a one-hour period shall be less than 2 % of full scale on the lowest range used. Span is defined as the difference between the span response and the zero response. The span response is defined as the mean response, including noise, to a span gas during a 30-second time interval.
1.4.2. Gas drying U.K.
The optional gas drying device must have a minimal effect on the concentration of the measured gases. Chemical dryers are not an acceptable method of removing water from the sample.
1.4.3. Analysers U.K.
Sections 1.4.3.1 to 1.4.3.5 of this Appendix describe the measurement principles to be used. A detailed description of the measurement systems is given in Annex VI.
The gases to be measured shall be analysed with the following instruments. For non-linear analysers, the use of linearising circuits is permitted.
1.4.3.1. Carbon monoxide (CO) analysis U.K.
The carbon monoxide analyser shall be of the non-dispersive infra-red (NDIR) absorption type.
1.4.3.2. Carbon dioxide (CO 2 ) analysis U.K.
The carbon dioxide analyser shall be of the non-dispersive infra-red (NDIR) absorption type.
1.4.3.3. Hydrocarbon (HC) analysis U.K.
The hydrocarbon analyser shall be of the heated flame ionization detector (HFID) type with detector, valves, pipework, etc, heated so as to maintain a gas temperature of 463 K (190 °C) ± 10 K.
1.4.3.4. Oxides of nitrogen (NO x ) analysis U.K.
The oxides of nitrogen analyser shall be of the chemiluminescent detector (CLD) or heated chemiluminescent detector (HCLD) type with a NO 2 /NO converter, if measured on a dry basis. If measured on a wet basis, a HCLD with converter maintained above 328 K (55 °C) shall be used, provided the water quench check (Annex III, Appendix 2, section 1.9.2.2) is satisfied.
For both CLD and HCLD, the sampling path shall be maintained at a wall temperature of 328 K to 473 K (55 to 200 °C) up to the converter for dry measurement, and up to the analyser for wet measurement.
1.4.4. Air to fuel measurement U.K.
The air to fuel measurement equipment used to determine the exhaust gas flow as specified in section 1.2.5 shall be a wide range air to fuel ratio sensor or lambda sensor of Zirconia type.
The sensor shall be mounted directly on the exhaust pipe where the exhaust gas temperature is high enough to eliminate water condensation.
The accuracy of the sensor with incorporated electronics shall be within:
To fulfil the accuracy specified above, the sensor shall be calibrated as specified by the instrument manufacturer.
1.4.5. Sampling for gaseous emissions U.K.
The gaseous emissions sampling probes must be fitted at least 0,5 m or three times the diameter of the exhaust pipe — whichever is the larger — upstream of the exit of the exhaust gas system as far as applicable and sufficiently close to the engine as to ensure an exhaust gas temperature of at least 343 K (70 °C) at the probe.
In the case of a multi-cylinder engine with a branched exhaust manifold, the inlet of the probe shall be located sufficiently far downstream so as to ensure that the sample is representative of the average exhaust emissions from all cylinders. In multi-cylinder engines having distinct groups of manifolds, such as in a ‘ V ’ -engine configuration, it is permissible to acquire a sample from each group individually and calculate an average exhaust emission. Other methods which have been shown to correlate with the above methods may be used. For exhaust emissions calculation the total exhaust mass flow of the engine must be used.
If the composition of the exhaust gas is influenced by any exhaust after-treatment system, the exhaust sample must be taken upstream of this device in the tests of stage I and downstream of this device in the tests of stage II. When a full flow dilution system is used for the determination of the particulates, the gaseous emissions may also be determined in the diluted exhaust gas. The sampling probes shall be close to the particulate sampling probe in the dilution tunnel (Annex VI, section 1.2.1.2, DT and Section 1.2.2, PSP). CO and CO 2 may optionally be determined by sampling into a bag and subsequent measurement of the concentration in the sampling bag.
1.5. Determination of the particulates U.K.
The determination of the particulates requires a dilution system. Dilution may be accomplished by a partial flow dilution system or a full flow dilution system. The flow capacity of the dilution system shall be large enough to completely eliminate water condensation in the dilution and sampling systems, and maintain the temperature of the diluted exhaust gas between 315 K (42 °C) and 325 K (52 °C) immediately upstream of the filter holders. De-humidifying the dilution air before entering the dilution system is permitted, if the air humidity is high. Dilution air pre-heating above the temperature limit of 303 K (30 °C) is recommended, if the ambient temperature is below 293 K (20 °C). However, the diluted air temperature must not exceed 325 K (52 °C) prior to the introduction of the exhaust in the dilution tunnel.
Note: For steady-state procedure, the filter temperature may be kept at or below the maximum temperature of 325 K (52 °C) instead of respecting the temperature range of 42 to 52 °C. U.K.
For a partial flow dilution system, the particulate sampling probe must be fitted close to and upstream of the gaseous probe as defined in Section 4.4 and in accordance with Annex VI, section 1.2.1.1, figure 4-12 EP and SP.
The partial flow dilution system has to be designed to split the exhaust stream into two fractions, the smaller one being diluted with air and subsequently used for particulate measurement. From that it is essential that the dilution ratio be determined very accurately. Different splitting methods can be applied, whereby the type of splitting used dictates to a significant degree the sampling hardware and procedures to be used (Annex VI, section 1.2.1.1).
To determine the mass of the particulates, a particulate sampling system, particulate sampling filters, a microgram balance and a temperature and humidity controlled weighing chamber are required.
For particulate sampling, two methods may be applied:
the single filter method uses one pair of filters (1.5.1.3 of this Appendix) for all modes of the test cycle. Considerable attention must be paid to sampling times and flows during the sampling phase of the test. However, only one pair of filters will be required for the test cycle,
the multiple filter method dictates that one pair of filters (section 1.5.1.3 of this Appendix) is used for each of the individual modes of the test cycle. This method allows more lenient sample procedures but uses more filters.
1.5.1. Particulate sampling filters U.K.
1.5.1.1. Filter specification U.K.
Fluorocarbon coated glass fibre filters or fluorocarbon based membrane filters are required for certification tests. For special applications different filter materials may be used. All filter types shall have a 0,3 μm DOP (di-octylphthalate) collection efficiency of at least 99 % at a gas face velocity between 35 and 100 cm/s. When performing correlation tests between laboratories or between a manufacturer and an approval authority, filters of identical quality must be used.
1.5.1.2. Filter size U.K.
Particulate filters must have a minimum diameter of 47 mm (37 mm stain diameter). Larger diameter filters are acceptable (section 1.5.1.5).
1.5.1.3. Primary and back-up filters U.K.
The diluted exhaust shall be sampled by a pair of filters placed in series (one primary and one back-up filter) during the test sequence. The back-up filter shall be located no more than 100 mm downstream of, and shall not be in contact with, the primary filter. The filters may be weighed separately or as a pair with the filters placed stain side to stain side.
1.5.1.4. Filter face velocity U.K.
A gas face velocity through the filter of 35 to 100 cm/s shall be achieved. The pressure drop increase between the beginning and the end of the test shall be no more than 25 kPa.
1.5.1.5. Filter loading U.K.
The recommended minimum filter loadings for the most common filter sizes are shown in the following table. For larger filter sizes, the minimum filter loading shall be 0,065 mg/ 1 000 mm 2 filter area.
Filter diameter (mm) | Recommended stain diameter (mm) | Recommended minimum loading (mg) |
---|
47 | 37 | 0,11 |
70 | 60 | 0,25 |
90 | 80 | 0,41 |
110 | 100 | 0,62 |
For the multiple filter method, the recommended minimum filter loading for the sum of all filters shall be the product of the appropriate value above and the square root of the total number of modes.
1.5.2. Weighing chamber and analytical balance specifications U.K.
1.5.2.1. Weighing chamber conditions U.K.
The temperature of the chamber (or room) in which the particulate filters are conditioned and weighed shall be maintained to within 295 K (22 °C) ± 3 K during all filter conditioning and weighing. The humidity shall be maintained to a dew point of 282,5 (9,5 °C) ± 3 K and a relative humidity of 45 ± 8 %.
1.5.2.2. Reference filter weighing U.K.
The chamber (or room) environment shall be free of any ambient contaminants (such as dust) that would settle on the particulate filters during their stabilisation. Disturbances to weighing room specifications as outlined in section 1.5.2.1 will be allowed if the duration of the disturbances does not exceed 30 minutes. The weighing room should meet the required specifications prior to personnel entrance into the weighing room. At least two unused reference filters or reference filter pairs shall be weighed within four hours of, but preferably at the same time as the sample filter (pair) weighing. They shall be the same size and material as the sample filters.
If the average weight of the reference filters (reference filter pairs) changes between sample filter weighing by more than 10μg, then all sample filters shall be discarded and the emissions test repeated.
If the weighing room stability criteria outlined in section 1.5.2.1 is not met, but the reference filter (pair) weighing meet the above criteria, the engine manufacturer has the option of accepting the sample filter weights or voiding the tests, fixing the weighing room control system and re-running the test.
1.5.2.3. Analytical balance U.K.
The analytical balance used to determine the weights of all filters shall have a precision (standard deviation) of 2 μg and a resolution of 1 μg (1 digit = 1 μg) specified by the balance manufacturer.
1.5.2.4. Elimination of static electricity effects U.K.
To eliminate the effects of static electricity, the filters shall be neutralised prior to weighing, for example, by a Polonium neutraliser or a device of similar effect.
1.5.3. Additional specifications for particulate measurement U.K.
All parts of the dilution system and the sampling system from the exhaust pipe up to the filter holder, which are in contact with raw and diluted exhaust gas, must be designed to minimise deposition or alteration of the particulates. All parts must be made of electrically conductive materials that do not react with exhaust gas components, and must be electrically grounded to prevent electrostatic effects.
2. MEASUREMENT AND SAMPLING PROCEDURES (NRTC TEST) U.K.
2.1. Introduction U.K.
Gaseous and particulate components emitted by the engine submitted for testing shall be measured by the methods of Annex VI. The methods of Annex VI describe the recommended analytical systems for the gaseous emissions (Section 1.1) and the recommended particulate dilution and sampling systems (Section 1.2).
2.2. Dynamometer and test cell equipment U.K.
The following equipment shall be used for emission tests of engines on engine dynamometers:
2.2.1. Engine dynamometer U.K.
An engine dynamometer shall be used with adequate characteristics to perform the test cycle described in Appendix 4 to this Annex. The instrumentation for torque and speed measurement shall allow the measurement of the power within the given limits. Additional calculations may be necessary. The accuracy of the measuring equipment must be such that the maximum tolerances of the figures given in Table 3 are not exceeded.
2.2.2. Other instruments U.K.
Measuring instruments for fuel consumption, air consumption, temperature of coolant and lubricant, exhaust gas pressure and intake manifold depression, exhaust gas temperature, air intake temperature, atmospheric pressure, humidity and fuel temperature shall be used, as required. These instruments shall satisfy the requirements given in Table 3:
Table 3 — Accuracy of measuring instruments U.K.
No. | Measuring instrument | accuracy |
---|
1 | Engine speed | ± 2 % of reading or ± 1 % of engine's max. value, whichever is larger |
2 | Torque | ± 2 % of reading or ± 1 % of engine's max. value, whichever is larger |
3 | Fuel consumption | ± 2 % of engine's max. value |
4 | Air consumption | ± 2 % of reading or ± 1 % of engine's max. value, whichever is larger |
5 | Exhaust gas flow | ± 2,5 % of reading or ± 1,5 % of engine's max. value, whichever is larger |
6 | Temperatures ≤ 600 K | ± 2 K absolute |
7 | Temperatures > 600 K | ± 1 % of reading |
8 | Exhaust gas pressure | ± 0,2 kPa absolute |
9 | Intake air depression | ± 0,05 kPa absolute |
10 | Atmospheric pressure | ± 0,1 kPa absolute |
11 | Other pressures | ± 0,1 kPa absolute |
12 | Absolute humidity | ± 5 % of reading |
13 | Dilution air flow | ± 2 % of reading |
14 | Diluted exhaust gas flow | ± 2 % of reading |
2.2.3. Raw exhaust gas flow U.K.
For calculating the emissions in the raw exhaust gas and for controlling a partial flow dilution system, it is necessary to know the exhaust gas mass flow rate. For determining the exhaust mass flow rate, either of the methods described below may be used.
For the purpose of emissions calculation, the response time of either method described below shall be equal to or less than the requirement for the analyser response time, as defined in Appendix 2, Section 1.11.1.
For the purpose of controlling a partial flow dilution system, a faster response is required. For partial flow dilution systems with online control, a response time of ≤ 0,3 s is required. For partial flow dilution systems with look ahead control based on a pre-recorded test run, a response time of the exhaust flow measurement system of ≤ 5 s with a rise time of ≤ 1 s is required. The system response time shall be specified by the instrument manufacturer. The combined response time requirements for exhaust gas flow and partial flow dilution system are indicated in Section 2.4.
Direct measurement method U.K.
Direct measurement of the instantaneous exhaust flow may be done by systems, such as:
Precautions shall be taken to avoid measurement errors, which will impact emission value errors. Such precautions include the careful installation of the device in the engine exhaust system according to the instrument manufacturers' recommendations and to good engineering practice. Especially, engine performance and emissions must not be affected by the installation of the device.
The flowmeters shall meet the accuracy specifications of Table 3.
Air and fuel measurement method U.K.
This involves measurement of the airflow and the fuel flow with suitable flowmeters. The calculation of the instantaneous exhaust gas flow is as follows:
G EXHW = G AIRW + G FUEL (for wet exhaust mass)
The flowmeters shall meet the accuracy specifications of Table 3, but shall also be accurate enough to also meet the accuracy specifications for the exhaust gas flow.
Tracer measurement method U.K.
This involves measurement of the concentration of a tracer gas in the exhaust.
A known amount of an inert gas (e.g. pure helium) shall be injected into the exhaust gas flow as a tracer. The gas is mixed and diluted by the exhaust gas, but must not react in the exhaust pipe. The concentration of the gas shall then be measured in the exhaust gas sample.
In order to ensure complete mixing of the tracer gas, the exhaust gas sampling probe shall be located at least 1 m or 30 times the diameter of the exhaust pipe, whichever is larger, downstream of the tracer gas injection point. The sampling probe may be located closer to the injection point if complete mixing is verified by comparing the tracer gas concentration with the reference concentration when the tracer gas is injected upstream of the engine.
The tracer gas flow rate shall be set so that the tracer gas concentration at engine idle speed after mixing becomes lower than the full scale of the trace gas analyser.
The calculation of the exhaust gas flow is as follows:
where
G EXHW
=
instantaneous exhaust mass flow (kg/s)
G T
=
tracer gas flow (cm 3 /min)
conc mix
=
instantaneous concentration of the tracer gas after mixing (ppm)
ρ EXH
=
density of the exhaust gas (kg/m 3 )
conc a
=
background concentration of the tracer gas in the intake air (ppm)
The background concentration of the tracer gas ( conc a ) may be determined by averaging the background concentration measured immediately before the test run and after the test run.
When the background concentration is less than 1 % of the concentration of the tracer gas after mixing ( conc mix. ) at maximum exhaust flow, the background concentration may be neglected.
The total system shall meet the accuracy specifications for the exhaust gas flow, and shall be calibrated according to Appendix 2, paragraph 1.11.2.
Air flow and air to fuel ratio measurement method U.K.
This involves exhaust mass calculation from the airflow and the air to fuel ratio. The calculation of the instantaneous exhaust gas mass flow is as follows:
where
A/Fst
=
stoichiometric air/fuel ratio (kg/kg)
λ
=
relative air/fuel ratio
conc CO2
=
dry CO 2 concentration ( %)
conc CO
=
dry CO concentration (ppm)
conc HC
=
HC concentration (ppm)
Note: The calculation refers to a diesel fuel with a H/C ratio equal to 1,8. U.K.
The air flowmeter shall meet the accuracy specifications in Table 3, the CO 2 analyser used shall meet the specifications of section 2.3.1, and the total system shall meet the accuracy specifications for the exhaust gas flow.
Optionally, air to fuel ratio measurement equipment, such as a zirconia type sensor, may be used for the measurement of the excess air ratio in accordance with the specifications of section 2.3.4.
2.2.4. Diluted exhaust gas flow U.K.
For calculation of the emissions in the diluted exhaust gas, it is necessary to know the diluted exhaust gas mass flow rate. The total diluted exhaust gas flow over the cycle (kg/test) shall be calculated from the measurement values over the cycle and the corresponding calibration data of the flow measurement device ( V 0 for PDP, K V for CFV, C d for SSV): the corresponding methods described in Appendix 3, section 2.2.1 shall be used. If the total sample mass of particulates and gaseous pollutants exceeds 0,5 % of the total CVS flow, the CVS flow shall be corrected or the particulate sample flow shall be returned to the CVS prior to the flow measuring device.
2.3. Determination of the gaseous components U.K.
2.3.1. General analyser specifications U.K.
The analysers shall have a measuring range appropriate for the accuracy required to measure the concentrations of the exhaust gas components (section 1.4.1.1). It is recommended that the analysers be operated in such a way that the measured concentration falls between 15 and 100 % of full scale.
If the full scale value is 155 ppm (or ppm C) or less, or if read-out systems (computers, data loggers) that provide sufficient accuracy and resolution below 15 % of full scale are used, concentrations below 15 % of full scale are also acceptable. In this case, additional calibrations are to be made to ensure the accuracy of the calibration curves – Annex III, Appendix 2, section 1.5.5.2.
The electromagnetic compatibility (EMC) of the equipment shall be of a level such as to minimise additional errors.
2.3.1.1. Measurement error U.K.
The analyser shall not deviate from the nominal calibration point by more than ± 2 % of the reading or ± 0,3 % of full scale, whichever is larger.
Note: For the purpose of this standard, accuracy is defined as the deviation of the analyser reading from the nominal calibration values using a calibration gas (≡ true value). U.K.
2.3.1.2. Repeatability U.K.
The repeatability, defined as 2,5 times the standard deviation of 10 repetitive responses to a given calibration or span gas, must be no greater than ± 1 % of full scale concentration for each range used above 155 ppm (or ppm C) or ± 2 % for each range used below 155 ppm (or ppm C).
2.3.1.3. Noise U.K.
The analyser peak-to-peak response to zero and calibration or span gases over any 10-second period shall not exceed 2 % of full scale on all ranges used.
2.3.1.4. Zero drift U.K.
The zero drift during a one-hour period shall be less than 2 % of full scale on the lowest range used. The zero response is defined as the mean response, including noise, to a zero gas during a 30-second time interval.
2.3.1.5. Span drift U.K.
The span drift during a one-hour period shall be less than 2 % of full scale on the lowest range used. Span is defined as the difference between the span response and the zero response. The span response is defined as the mean response, including noise, to a span gas during a 30-second time interval.
2.3.1.6. Rise time U.K.
For raw exhaust gas analysis, the rise time of the analyser installed in the measurement system shall not exceed 2,5 s.
NOTE: Only evaluating the response time of the analyser alone will not clearly define the suitability of the total system for transient testing. Volumes, and especially dead volumes, through out the system will not only affect the transportation time from the probe to the analyser, but also affect the rise time. Also transport times inside of an analyser would be defined as analyser response time, like the converter or water traps inside of a NO x analysers. The determination of the total system response time is described in Appendix 2, Section 1.11.1. U.K.
2.3.2. Gas drying U.K.
Same specifications as for NRSC test cycle apply (Section 1.4.2) as described here below.
The optional gas drying device must have a minimal effect on the concentration of the measured gases. Chemical dryers are not an acceptable method of removing water from the sample.
2.3.3. Analysers U.K.
Same specifications as for NRSC test cycle apply (Section 1.4.3) as described here below.
The gases to be measured shall be analysed with the following instruments. For non-linear analysers, the use of linearising circuits is permitted.
2.3.3.1. Carbon monoxide (CO) analysis U.K.
The carbon monoxide analyser shall be of the non-dispersive infra-red (NDIR) absorption type.
2.3.3.2. Carbon dioxide (CO 2 ) analysis U.K.
The carbon dioxide analyser shall be of the non-dispersive infra-red (NDIR) absorption type.
2.3.3.3. Hydrocarbon (HC) analysis U.K.
The hydrocarbon analyser shall be of the heated flame ionization detector (HFID) type with detector, valves, pipework, etc, heated so as to maintain a gas temperature of 463K (190 °C) ± 10 K.
2.3.3.4. Oxides of nitrogen (NO x ) analysis U.K.
The oxides of nitrogen analyser shall be of the chemiluminescent detector (CLD) or heated chemiluminescent detector (HCLD) type with a NO 2 /NO converter, if measured on a dry basis. If measured on a wet basis, a HCLD with converter maintained above 328 K (55 °C shall be used, provided the water quench check (Annex III, Appendix 2, section 1.9.2.2) is satisfied.
For both CLD and HCLD, the sampling path shall be maintained at a wall temperature of 328K to 473 K (55 to 200 °C) up to the converter for dry measurement, and up to the analyser for wet measurement.
2.3.4. Air to fuel measurement U.K.
The air to fuel measurement equipment used to determine the exhaust gas flow as specified in section 2.2.3 shall be a wide range air to fuel ratio sensor or lambda sensor of Zirconia type.
The sensor shall be mounted directly on the exhaust pipe where the exhaust gas temperature is high enough to eliminate water condensation.
The accuracy of the sensor with incorporated electronics shall be within:
To fulfil the accuracy specified above, the sensor shall be calibrated as specified by the instrument manufacturer.
2.3.5. Sampling of gaseous emissions U.K.
2.3.5.1. Raw exhaust gas flow U.K.
For calculation of the emissions in the raw exhaust gas the same specifications as for NRSC test cycle apply (Section 1.4.4), as described here below.
The gaseous emissions sampling probes must be fitted at least 0,5 m or three times the diameter of the exhaust pipe — whichever is the larger — upstream of the exit of the exhaust gas system as far as applicable and sufficiently close to the engine as to ensure an exhaust gas temperature of at least 343 K (70 °C) at the probe.
In the case of a multicylinder engine with a branched exhaust manifold, the inlet of the probe shall be located sufficiently far downstream so as to ensure that the sample is representative of the average exhaust emissions from all cylinders. In multicylinder engines having distinct groups of manifolds, such as in a ‘ V ’ -engine configuration, it is permissible to acquire a sample from each group individually and calculate an average exhaust emission. Other methods which have been shown to correlate with the above methods may be used. For exhaust emissions calculation the total exhaust mass flow of the engine must be used.
If the composition of the exhaust gas is influenced by any exhaust after-treatment system, the exhaust sample must be taken upstream of this device in the tests of stage I and downstream of this device in the tests of stage II.
2.3.5.2. Diluted exhaust gas flow U.K.
If a full flow dilution system is used, the following specifications apply.
The exhaust pipe between the engine and the full flow dilution system shall conform to the requirements of Annex VI.
The gaseous emissions sample probe(s) shall be installed in the dilution tunnel at a point where the dilution air and exhaust gas are well mixed, and in close proximity to the particulates sampling probe.
Sampling can generally be done in two ways:
the pollutants are sampled into a sampling bag over the cycle and measured after completion of the test,
the pollutants are sampled continuously and integrated over the cycle; this method is mandatory for HC and NO x .
The background concentrations shall be sampled upstream of the dilution tunnel into a sampling bag, and shall be subtracted from the emissions concentration according to Appendix 3, Section 2.2.3.
2.4. Determination of the particulates U.K.
Determination of the particulates requires a dilution system. Dilution may be accomplished by a partial flow dilution system or a full flow dilution system. The flow capacity of the dilution system shall be large enough to completely eliminate water condensation in the dilution and sampling systems, and maintain the temperature of the diluted exhaust gas between 315 K (42 °C) and 325 K (52 °C) immediately upstream of the filter holders. De-humidifying the dilution air before entering the dilution system is permitted, if the air humidity is high. Dilution air pre-heating above the temperature limit of 303 K (30 °C) is recommended if the ambient temperature is below 293 K (20 °C). However, the diluted air temperature must not exceed 325 K (52 °C) prior to the introduction of the exhaust in the dilution tunnel.
The particulate sampling probe shall be installed in close proximity to the gaseous emissions sampling probe, and the installation shall comply with the provisions of Section 2.3.5.
To determine the mass of the particulates, a particulate sampling system, particulate sampling filters, microgram balance, and a temperature and humidity controlled weighing chamber, are required.
Partial flow dilution system specifications
The partial flow dilution system has to be designed to split the exhaust stream into two fractions, the smaller one being diluted with air and subsequently used for particulate measurement. For this it is essential that the dilution ratio be determined very accurately. Different splitting methods can be applied, whereby the type of splitting used dictates to a significant degree the sampling hardware and procedures to be used (Annex VI, section 1.2.1.1).
For the control of a partial flow dilution system, a fast system response is required. The transformation time for the system shall be determined by the procedure described in Appendix 2, Section 1.11.1.
If the combined transformation time of the exhaust flow measurement (see previous section) and the partial flow system is less than 0,3 s, online control may be used. If the transformation time exceeds 0,3 s, look ahead control based on a pre-recorded test run must be used. In this case, the rise time shall be ≤ 1 s and the delay time of the combination ≤ 10 s.
The total system response shall be designed as to ensure a representative sample of the particulates, G SE , proportional to the exhaust mass flow. To determine the proportionality, a regression analysis of G SE versus G EXHW shall be conducted on a minimum 5 Hz data acquisition rate, and the following criteria shall be met:
the correlation coefficient r of the linear regression between G SE and G EXHW shall be not less than 0,95,
the standard error of estimate of G SE on G EXHW shall not exceed 5 % of G SE maximum.
G SE intercept of the regression line shall not exceed ± 2 % of G SE maximum .
Optionally, a pre-test may be run, and the exhaust mass flow signal of the pre-test be used for controlling the sample flow into the particulate system (look-ahead control). Such a procedure is required if the transformation time of the particulate system, t 50,P or/and the transformation time of the exhaust mass flow signal, t 50,F are > 0,3 s. Acorrect control of the partial dilution system is obtained, if the time trace of G EXHW ,pre of the pre-test, which controls G SE , is shifted by a ‘look-ahead’ time of t 50,P + t 50,F .
For establishing the correlation between G SE and G EXHW the data taken during the actual test shall be used, with G EXHW time aligned by t 50,F relative to G SE (no contribution from t 50,P to the time alignment). That is, the time shift between G EXHW and G SE is the difference in their transformation times that were determined in Appendix 2, Section 2.6.
For partial flow dilution systems, the accuracy of the sample flow G SE is of special concern, if not measured directly, but determined by differential flow measurement:
G SE = G TOTW — G DILW
In this case an accuracy of ± 2 % for G TOTW and G DILW is not sufficient to guarantee acceptable accuracies of G SE. If the gas flow is determined by differential flow measurement, the maximum error of the difference shall be such that the accuracy of G SE is within ± 5 % when the dilution ratio is less than 15. It can be calculated by taking root-mean-square of the errors of each instrument.
Acceptable accuracies of G SE can be obtained by either of the following methods:
(a)
The absolute accuracies of G TOTW and G DILW are ± 0,2 % which guarantees an accuracy of G SE of ≤ 5 % at a dilution ratio of 15. However, greater errors will occur at higher dilution ratios.
(b)
Calibration of G DILW relative to G TOTW is carried out such that the same accuracies for G SE as in (a) are obtained. For the details of such a calibration see Appendix 2, Section 2.6.
(c)
The accuracy of G SE is determined indirectly from the accuracy of the dilution ratio as determined by a tracer gas, e.g. CO 2 . Again, accuracies equivalent to method (a) for G SE are required.
(d)
The absolute accuracy of G TOTW and G DILW is within ± 2 % of full scale, the maximum error of the difference between G TOTW and G DILW is within 0,2 %, and the linearity error is within ± 0,2 % of the highest G TOTW observed during the test.
2.4.1. Particulate sampling filters U.K.
2.4.1.1. Filter specification U.K.
Fluorocarbon coated glass fibre filters or fluorocarbon based membrane filters are required for certification tests. For special applications different filter materials may be used. All filter types shall have a 0,3 μm DOP (di-octylphthalate) collection efficiency of at least 99 % at a gas face velocity between 35 and 100 cm/s. When performing correlation tests between laboratories or between a manufacturer and an approval authority, filters of identical quality must be used.
2.4.1.2. Filter size U.K.
Particulate filters must have a minimum diameter of 47 mm (37 mm stain diameter). Larger diameter filters are acceptable (section 2.4.1.5).
2.4.1.3. Primary and back-up filters U.K.
The diluted exhaust shall be sampled by a pair of filters placed in series (one primary and one back-up filter) during the test sequence. The back-up filter shall be located no more than 100mm downstream of, and shall not be in contact with, the primary filter. The filters may be weighed separately or as a pair with the filters placed stain side to stain side.
2.4.1.4. Filter face velocity U.K.
A gas face velocity through the filter of 35 to 100 cm/s shall be achieved. The pressure drop increase between the beginning and the end of the test shall be no more than 25 kPa.
2.4.1.5. Filter loading U.K.
The recommended minimum filter loadings for the most common filter sizes are shown in the following table. For larger filter sizes, the minimum filter loading shall be 0,065 mg/ 1 000 mm 2 filter area.
Filter diameter (mm) | Recommended stain diameter (mm) | Recommended minimum loading (mg) |
---|
47 | 37 | 0,11 |
70 | 60 | 0,25 |
90 | 80 | 0,41 |
110 | 100 | 0,62 |
2.4.2. Weighing chamber and analytical balance specifications U.K.
2.4.2.1. Weighing chamber conditions U.K.
The temperature of the chamber (or room) in which the particulate filters are conditioned and weighed shall be maintained to within 295 K (22 °C) ± 3 K during all filter conditioning and weighing. The humidity shall be maintained to a dewpoint of 282,5 (9,5 °C) ± 3 K and a relative humidity of 45 ± 8 %.
2.4.2.2. Reference filter weighing U.K.
The chamber (or room) environment shall be free of any ambient contaminants (such as dust) that would settle on the particulate filters during their stabilisation. Disturbances to weighing room specifications as outlined in section 2.4.2.1 will be allowed if the duration of the disturbances does not exceed 30 minutes. The weighing room should meet the required specifications prior to personnel entrance into the weighing room. At least two unused reference filters or reference filter pairs shall be weighed within four hours of, but preferably at the same time as the sample filter (pair) weighing. They shall be the same size and material as the sample filters.
If the average weight of the reference filters (reference filter pairs) changes between sample filter weighing by more than 10 μg, then all sample filters shall be discarded and the emissions test repeated.
If the weighing room stability criteria outlined in section 2.4.2.1 are not met, but the reference filter (pair) weighing meet the above criteria, the engine manufacturer has the option of accepting the sample filter weights or voiding the tests, fixing the weighing room control system and re-running the test.
2.4.2.3. Analytical balance U.K.
The analytical balance used to determine the weights of all filters shall have a precision (standard deviation) of 2 μg and a resolution of 1 μg (1 digit = 1 μg) specified by the balance manufacturer.
2.4.2.4. Elimination of static electricity effects U.K.
To eliminate the effects of static electricity, the filters shall be neutralised prior to weighing, for example, by a Polonium neutraliser or a device having similar effect.
2.4.3. Additional specifications for particulate measurement U.K.
All parts of the dilution system and the sampling system from the exhaust pipe up to the filter holder, which are in contact with raw and diluted exhaust gas, must be designed to minimise deposition or alteration of the particulates. All parts must be made of electrically conductive materials that do not react with exhaust gas components, and must be electrically grounded to prevent electrostatic effects.]
[Appendix 2
CALIBRATION PROCEDURE (NRSC, NRTC () )]
1.CALIBRATION OF THE ANALYTICAL INSTRUMENTSU.K.
1.1.IntroductionU.K.
Each analyzer shall be calibrated as often as necessary to fulfil the accuracy requirements of this standard. The calibration method that shall be used is described in this paragraph for the analysers indicated in Appendix 1, section 1.4.3.
1.2.Calibration gasesU.K.
The shelf life of all calibration gases must be respected.
The expiry date of the calibration gases stated by the manufacturer shall be recorded.
1.2.1.Pure gasesU.K.
The required purity of the gases is defined by the contamination limits given below. The following gases must be available for operation:
purified nitrogen
(contamination ≤ 1 ppm C, ≤ 1 ppm CO, ≤ 400 ppm CO2, ≤ 0,1 ppm NO)
purified oxygen
(purity > 99,5 % vol O2)
hydrogen-helium mixture
(40 ± 2 % hydrogen, balance helium)
(contamination ≤ 1 ppm C, ≤ 400 ppm [CO 2] )
purified synthetic air
(contamination ≤ 1 ppm C, ≤ 1 ppm CO, ≤ 400 ppm CO2, ≤ 0,1 ppm NO)
(oxygen content between 18 – 21 % vol)
1.2.2.Calibration and span gasesU.K.
Mixture of gases having the following chemical compositions shall be available:
C3H8 and purified synthetic air (see section 1.2.1)
CO and purified nitrogen
NO and purified nitrogen (the amount of NO2 contained in this calibration gas must not exceed 5 % of the NO content)
O2 and purified nitrogen
CO2 and purified nitrogen
CH4 and purified synthetic air
C2H6 and purified synthetic air
Note: other gas combinations are allowed provided the gases do not react with one another.U.K.
The true concentration of a calibration and span gas must be within ± 2 % of the nominal value. All concentrations of calibration gas shall be given on a volume basis (volume percent or volume ppm).
The gases used for calibration and span may also be obtained by means of a gas divider, diluting with purified N2 or with purified synthetic air. The accuracy of the mixing device must be such that the concentration of the diluted calibration gases may be determined to within ± 2 %.
[This accuracy implies that primary gases used for blending shall be known to have an accuracy of at least ± 1 %, traceable to national or international gas standards. The verification shall be performed at between 15 and 50 % of full scale for each calibration incorporating a blending device. An additional verification may be performed using another calibration gas, if the first verification has failed.
Optionally, the blending device may be checked with an instrument which by nature is linear, e.g. using NO gas with a CLD. The span value of the instrument shall be adjusted with the span gas directly connected to the instrument. The blending device shall be checked at the used settings and the nominal value shall be compared to the measured concentration of the instrument. This difference shall in each point be within ± 1 % of the nominal value.
Other methods may be used based on good engineering practice and with the prior agreement of the parties involved.
Note: A precision gas divider of accuracy is within ± 1 %, is recommended for establishing the accurate analyser calibration curve. The gas divider shall be calibrated by the instrument manufacturer.] U.K.
1.3.Operating procedure for analysers and sampling systemU.K.
The operating procedure for analysers shall follow the start-up and operating instructions of the instrument manufacturer. The minimum requirements given in sections 1.4 to 1.9 shall be included.
1.4.Leakage testU.K.
A system leakage test shall be performed. The probe shall be disconnected from the exhaust system and the end plugged. The analyser pump shall be switched on. After an initial stabilization period all flow meters should read zero. If not, the sampling lines shall be checked and the fault corrected. The maximum allowable leakage rate on the vacuum side shall be 0,5 % of the in-use flow rate for the portion of the system being checked. The analyser flows and bypass flows may be used to estimate the in-use flow rates.
Another method is the introduction of a concentration step change at the beginning of the sampling line by switching from zero to span gas.
If after an adequate period of time the reading shows a lower concentration compared to the introduced concentration, this points to calibration or leakage problems.
1.5.Calibration procedureU.K.
1.5.1.Instrument assemblyU.K.
The instrument assembly shall be calibrated and calibration curves checked against standard gases. The same gas flow rates shall be used as when sampling exhaust.
1.5.2.Warming-up timeU.K.
The warming-up time should be according to the recommendations of the manufacturer. If not specified, a minimum of two Hours is recommended for warming-up the analysers.
1.5.3.NDIR and HFID analyserU.K.
The NDIR analyser shall be tuned, as necessary, and the combustion flame of the HFID analyser shall be optimized (section 1.8.1).
1.5.4.CalibrationU.K.
Each normally used operating range shall be calibrated.
Using purified synthetic air (or nitrogen), the CO, CO2, Nox, HC and O2 analysers shall be set at zero.
The appropriate calibration gases shall be introduced to the analysers, the values recorded, and the calibration curve established according to section 1.5.6.
The zero setting shall be re-checked and the calibration procedure repeated, if necessary.
1.5.5.Establishment of the calibration curveU.K.
1.5.5.1.General guidelinesU.K.
[The analyser calibration curve is established by at least six calibration points (excluding zero) spaced as uniformly as possible.] The highest nominal concentration must be equal to or higher than 90 % of full scale.
The calibration curve is calculated by the method of least squares. If the resulting polynomial degree is greater than three, the number of calibration points (zero included) must be at least equal to this polynomial degree plus two.
[The calibration curve must not differ by more than ± 2 % from the nominal value of each calibration point and by more than ± 0,3 % of full scale at zero.]
From the calibration curve and the calibration points, it is possible to verify that the calibration has been carried out correctly. The different characteristic parameters of the analyser must be indicated, particularly:
1.5.5.2.Calibration below 15 % of full scaleU.K.
The analyser calibration curve is established by at least ten calibration points (excluding zero) spaced so that 50 % of the calibration points is below 10 % of full scale.
The calibration curve is calculated by the method of least squares.
[The calibration curve must not differ by more than ± 4 % from the nominal value of each calibration point and by more than ± 0,3 % of full scale at zero.]
1.5.5.3.Alternative methodsU.K.
If it can be shown that alternative technology (e.g. computer, electronically controlled range switch, etc.) can give equivalent accuracy, then these alternatives may be used.
1.6.Verification of the calibrationU.K.
Each normally used operating range shall be checked prior to each analysis in accordance with the following procedure.
The calibration is checked by using a zero gas and a span gas whose nominal value is more than 80 % of full scale of the measuring range.
If, for the two points considered, the value found does not differ by more than ± 4 % of full scale from the declared reference value, the adjustment parameters may be modified. Should this not be the case, a new calibration curve shall be established in accordance with section 1.5.4.
1.7.Efficiency test of the NOx converterU.K.
The efficiency of the converter used for the conversion of NO2 into NO is tested as given in sections 1.7.1 to 1.7.8 (Figure 1).
1.7.1.Test set-upU.K.
Using the test set-up as shown in Figure 1 (see also Appendix 1, section 1.4.3.5) and the procedure below, the efficiency of converters can be tested by means of an ozonator.
1.7.2.CalibrationU.K.
The CLD and the HCLD shall be calibrated in the most common operating range following the manufacturer's specifications using zero and span gas (the NO content of which must amount to about 80 % of the operating range and the NO2 concentration of the gas mixture to less than 5 % of the NO concentration). The NOx analyser must be in the NO mode so that the span gas does not pass through the converter. The indicated concentration has to be recorded.
1.7.3.CalculationU.K.
The efficiency of the NOx converter is calculated as follows:
(a)
NOx concentration according to section 1.7.6;
(b)
NOx concentration according to section 1.7.7;
(c)
NO concentration according to section 1.7.4;
(d)
NO concentration according to section 1.7.5.
1.7.4.Adding of oxygenU.K.
Via a T-fitting, oxygen or zero air is added continuously to the gas flow until the concentration indicated is about 20 % less than the indicated calibration concentration given in section 1.7.2 (The analyser is in the NO mode.)
The indicated concentration (c) shall be recorded. The ozonator is kept de-activated throughout the process.
1.7.5.Activation of the ozonatorU.K.
The ozonator is now activated to generate enough ozone to bring the NO concentration down to about 20 % (minimum 10 %) of the calibration concentration given in section 1.7.2. The indicated concentration (d) shall be recorded. (The analyser is in the NO mode.)
1.7.6.NOx modeU.K.
The NO analyser is then switched to the NOx mode so that the gas mixture (consisting of NO, NO2, O2 and N2) now passes through the converter. The indicated concentration (a) shall be recorded. (The analyser is in the NOx mode.)
1.7.7.De-activation of the ozonatorU.K.
The ozonator is now de-activated. The mixture of gases described in section 1.7.6 passes through the converter into the detector. The indicated concentration (b) shall be recorded. (The analyser is in the NOx mode.)
1.7.8.NO modeU.K.
Switched to NO mode with the ozonator de-activated, the flow of oxygen or synthetic air is also shut off. The NOx reading of the analyser shall not deviate by more than ± 5 % from the value measured according to section 1.7.2 (The analyser is in the NO mode.)
1.7.9.Test intervalU.K.
The efficiency of the converter must be tested prior to each calibration of the NOx analyser.
1.7.10.Efficiency requirementU.K.
The efficiency of the converter shall not be less than 90 %, but a higher efficiency of 95 % is strongly recommended.
Note: If, with the analyser in the most common range, the ozonator cannot give a reduction from 80 % to 20 % according to section 1.7.5, then the highest range which will give the reduction shall be used.U.K.
1.8.Adjustment of the FIDU.K.
1.8.1.Optimization of the detector responseU.K.
The HFID must be adjusted as specified by the instrument manufacturer. A propane in air span gas should be used to optimize the response on the most common operating range.
With the fuel and air flow rates set at the manufacturer's recommendations, a 350 ± 75 ppm C span gas shall be introduced to the analyser. The response at a given fuel flow shall be determined from the difference between the span gas response and the zero gas response. The fuel flow shall be incrementally adjusted above and below the manufacturer's specification. The span and zero response at these fuel flows shall be recorded. The difference between the span and zero response shall be plotted and the fuel flow adjusted to the rich side of the curve.
1.8.2.Hydrocarbon response factorsU.K.
The analyser shall be calibrated using propane in air and purified synthetic air, according to section 1.5.
Response factors shall be determined when introducing an analyser into service and after major service intervals. The response factor (Rf) for a particular hydrocarbon species is the ratio of the FID C1 reading to the gas concentration in the cylinder expressed by ppm C1.
The concentration of the test gas must be at a level to give a response of approximately 80 % of full scale. The concentration must be known to an accuracy of ± 2 % in reference to a gravimetric standard expressed in volume. In addition, the gas cylinder must be pre-conditioned for 24 hours at a temperature of 298 K (25 oC) ± 5 K.
The test gases to be used and the recommended relative response factor ranges are as follows:
— methane and purified synthetic air: | 1,0 ≤ Rf ≤ 1,15 |
— propylene and purified synthetic air: | 0,9 ≤ Rf ≤ 1,1 |
— toluene and purified synthetic air: | 0,9 ≤ Rf ≤ 1,1 |
These values are relative to the response factor (Rf) of 1,00 for propane and purified synthetic air.
1.8.3.Oxygen interference checkU.K.
[The oxygen interference check shall be determined when introducing an analyser into service and after major service intervals.
A range shall be chosen where the oxygen interference check gases will fall within the upper 50 %. The test shall be conducted with the oven temperature set as required.
1.8.3.1. Oxygen interference gases U.K.
Oxygen interference check gases shall contain propane with 350 ppmC ÷ 75 ppmC hydrocarbon. The concentration value shall be determined to calibration gas tolerances by chromatographic analysis of total hydrocarbons plus impurities or by dynamic blending. Nitrogen shall be the predominant diluent with the balance oxygen. Blends required for Diesel engine testing are:
O 2 concentration | Balance |
---|
21 (20 to 22) | Nitrogen |
10 (9 to 11 | Nitrogen |
5 (4 to 6) | Nitrogen |
1.8.3.2. Procedure U.K.
(a)
The analyser shall be zeroed.
(b)
The analyser shall be spanned with the 21 % oxygen blend.
(c)
The zero response shall be rechecked. If it has changed more than 0,5 % of full scale clauses (a) and (b) shall be repeated.
(d)
The 5 % and 10 % oxygen interference check gases shall be introduced.
(e)
The zero response shall be rechecked. If it has changed more than ± 1 % of full scale, the test shall be repeated.
(f)
The oxygen interference (%O 2 I) shall be calculated for each mixture in (d) as follows:
A
=
hydrocarbon concentration (ppmC) of the span gas used in (b)
B
=
hydrocarbon concentration (ppmC) of the oxygen interference check gases used in (d)
D
=
percent of full scale analyser response due to A.
(g)
The % of oxygen interference (%O 2 I) shall be less than ± 3,0 % for all required oxygen interference check gases prior to testing.
(h)
If the oxygen interference is greater than ± 3,0 %, the air flow above and below the manufacturer's specifications shall be incrementally adjusted, repeating clause 1.8.1 for each flow.
(i)
If the oxygen interference is greater than ± 3,0 % after adjusting the air flow, the fuel flow and thereafter the sample flow shall be varied, repeating clause 1.8.1 for each new setting.
(j)
If the oxygen interference is still greater than ± 3,0 %, the analyser, FID fuel, or burner air shall be repaired or replaced prior to testing. This clause shall then be repeated with the repaired or replaced equipment or gases.]
1.9.Interference effects with NDIR and CLD analysersU.K.
Gases present in the exhaust other than the one being analysed can interfere with the reading in several ways. Positive interference occurs in NDIR instruments where the interfering gas gives the same effect as the gas being measured, but to a lesser degree. Negative interference occurs in NDIR instruments by the interfering gas broadening the absorption band of the measured gas, and in CLD instruments by the interfering gas quenching the radiation. The interference checks in sections 1.9.1 and 1.9.2 shall be performed prior to an analyser's initial use and after major service intervals.
1.9.1.CO analyser interference checkU.K.
Water and CO2 can interfere with the CO analyser performance. Therefore a CO2 span gas having a concentration of 80 to 100 % of full scale of the maximum operating range used during testing shall be bubbled through water at room temperature and the analyser response recorded. The analyser response must not be more than 1 % of full scale for ranges equal to or above 300 ppm or more than 3 ppm for ranges below 300 ppm.
1.9.2.NOx analyser quench checksU.K.
The two gases of concern for CLD (and HCLD) analysers are CO2 and water vapour. Quench responses of these gases are proportional to their concentrations, and therefore require test techniques to determine the quench at the highest expected concentrations experienced during testing.
1.9.2.1.CO2 quench checkU.K.
A CO2 span gas having a concentration of 80 to 100 % of full scale of the maximum operating range shall be passed through the NDIR analyser and the CO2 value recorded as A. It shall then be diluted approximately 50 % with NO span gas and passed through the NDIR and (H)CLD with the CO2 and NO values recorded as B and C, respectively. The CO2 shall be shut off and only the NO span gas be passed through the (H)CLD and the NO value recorded as D.
The quench shall be calculated as follows:
and must not be greater than 3 % of full scale.
where:
A
:
undiluted CO2 concentration measured with NDIR %
B
:
diluted CO2 concentration measured with NDIR %
C
:
diluted NO concentration measured with CLD ppm
D
:
undiluted NO concentration measured with CLD ppm
[1.9.2.2. Water quench check U.K.
[This check applies to wet gas concentration measurements only. Calculation of water quench must consider dilution of the NO span gas with water vapour and scaling of water vapour concentration of the mixture to that expected during testing. A NO span gas having a concentration of 80 to 100 % of full scale to the normal operating range shall be passed through the (H)CLD and the NO value recorded as D. The NO gas shall be bubbled through water at room temperature and passed through the (H)CLD and NO value recorded as C. The water temperature shall be determined and recorded as F. The mixture's saturation vapour pressure that corresponds to the bubbler water temperature (F) shall be determined and recorded as G. The water vapour concentration (in %) of the mixture shall be calculated as follows:]
and recorded as H. The expected diluted NO span gas (in water vapour) concentration shall be calculated as follows:
[and recorded as De. For diesel exhaust, the maximum exhaust water vapour concentration (in %) expected during testing shall be estimated, under the assumption of a fuel atom H/C ratio of 1,8 to 1, from the maximum CO 2 concentration in the exhaust gas or from the undiluted CO 2 span gas concentration (A, as measured in section 1.9.2.1) as follows:]
and recorded as Hm.
The water quench shall be calculated as follows:
and must not be greater than 3 % of full scale.
De
:
expected diluted NO concentration (ppm)
C
:
diluted NO concentration (ppm)
Hm
:
maximum water vapour concentration (%)
H
:
actual water vapour concentration (%)
NB: It is important that the NO span gas contains minimal NO 2 concentration for this check, since obsorption of NO 2 in water has not been accounted for in the quench calculations.] U.K.
1.10.Calibration intervalsU.K.
The analysers shall be calibrated according to section 1.5 at least every three months or whenever a system repair or change is made that could influence calibration.
[1.11. Additional calibration requirements for raw exhaust measurements over NRTC test U.K.
1.11.1. Response time check of the analytical system U.K.
The system settings for the response time evaluation shall be exactly the same as during measurement of the test run (i.e. pressure, flow rates, filter settings on the analysers and all other response time influences). The response time determination shall be done with gas switching directly at the inlet of the sample probe. The gas switching shall be done in less than 0,1 second. The gases used for the test shall cause a concentration change of at least 60 % FS.
The concentration trace of each single gas component shall be recorded. The response time is defined as the difference in time between the gas switching and the appropriate change of the recorded concentration. The system response time (t 90 ) consists of the delay time to the measuring detector and the rise time of the detector. The delay time is defined as the time from the change (t 0 ) until the response is 10 % of the final reading (t 10 ). The rise time is defined as the time between 10 and 90 % response of the final reading (t 90 — t 10 ).
For time alignment of the analyser and exhaust flow signals in the case of raw measurement, the transformation time is defined as the time from the change (t 0 ) until the response is 50 % of the final reading (t 50 ).
The system response time shall be ≤ 10 seconds with a rise time ≤ 2,5 seconds for all limited components (CO, NO x , HC) and all ranges used.
1.11.2. Calibration of tracer gas analyser for exhaust flow measurement U.K.
The analyser for measurement of the tracer gas concentration, if used, shall be calibrated using the standard gas.
The calibration curve shall be established by at least 10 calibration points (excluding zero) spaced so that a half of the calibration points are placed between 4 to 20 % of analyser's full scale and the rest are in between 20 to 100 % of the full scale. The calibration curve is calculated by the method of least squares.
The calibration curve shall not differ by more than ± 1 % of the full scale from the nominal value of each calibration point, in the range from 20 to 100 % of the full scale. It shall also not differ by more than ± 2 % from the nominal value in the range from 4 to 20 % of the full scale.
The analyser shall be set at zero and spanned prior to the test run using a zero gas and a span gas whose nominal value is more than 80 % of the analyser full scale.]
2.CALIBRATION OF THE PARTICULATE MEASURING SYSTEMU.K.
2.1.IntroductionU.K.
Each component shall be calibrated as often as necessary to fulfil the accuracy requirements of this standard. The calibration method to be used is described in this section for the components indicated in Annex III, Appendix 1, section 1.5 and Annex V.
2.2.Flow measurementU.K.
[The calibration of gas flow-meters or flow measurement instrumentation shall be traceable to national and/or international standards.
The maximum error of the measured value shall be within ± 2 % of reading.
For partial flow dilution systems, the accuracy of the sample flow G SE is of special concern, if not measured directly, but determined by differential flow measurement:
G SE = G TOTW — G DILW
In this case an accuracy of ± 2 % for G TOTW and G DILW is not sufficient to guarantee acceptable accuracies of G SE. If the gas flow is determined by differential flow measurement, the maximum error of the difference shall be such that the accuracy of G SE is within ± 5 % when the dilution ratio is less than 15. It can be calculated by taking root-mean-square of the errors of each instrument.]
2.3.Checking the dilution ratioU.K.
When using particulate sampling systems without EGA (Annex V, section 1.2.1.1), the dilution ratio shall be checked for each new engine installation with the engine running and the use of either the CO2 or NOx concentration measurements in the raw and dilute exhaust.
The measured dilution ratio shall be within ± 10 % of the calculated dilution ratio from CO2 or NOx concentration measurement.
2.4.Checking the partial flow conditionsU.K.
The range of the exhaust gas velocity and the pressure oscillations shall be checked and adjusted according to the requirements of Annex V, section 1.2.1.1, EP, if applicable.
2.5.Calibration intervalsU.K.
The flow measurement instrumentation shall be calibrated at least every three months, or whenever a system change is made that could influence calibration.
[2.6. Additional calibration requirements for partial flow dilution systems U.K.
2.6.1 Periodical calibration U.K.
If the sample gas flow is determined by differential flow measurement the flow meter or the flow measurement instrumentation shall be calibrated by one of the following procedures, such that the probe flow G SE into the tunnel fulfils the accuracy requirements of Appendix I section 2.4:
The flow meter for G DILW is connected in series to the flow meter for G TOTW , the difference between the two flow meters is calibrated for at least five set points with flow values equally spaced between the lowest G DILW value used during the test and the value of G TOTW used during the test The dilution tunnel may be bypassed.
A calibrated mass flow device is connected in series to the flowmeter for G TOTW and the accuracy is checked for the value used for the test. Then the calibrated mass flow device is connected in series to the flow meter for G DILW , and the accuracy is checked for at least five settings corresponding to the dilution ratio between 3 and 50, relative to G TOTW used during the test.
The transfer tube TT is disconnected from the exhaust, and a calibrated flow measuring device with a suitable range to measure G SE is connected to the transfer tube. Then G TOTW is set to the value used during the test, and G DILW is sequentially set to at least five values corresponding to dilution ratios q between 3 and 50. Alternatively, a special calibration flow path may be provided, in which the tunnel is bypassed, but the total and dilution air flow through the corresponding meters are maintained as in the actual test.
A tracer gas is fed into the transfer tube TT. This tracer gas may be a component of the exhaust gas, like CO 2 or NO x . After dilution in the tunnel the tracer gas component is measured. This shall be carried out for five dilution ratios between 3 and 50. The accuracy of the sample flow is determined from the dilution ration q :
G SE = G TOTW / q
The accuracies of the gas analysers shall be taken into account to guarantee the accuracy of G SE .
2.6.2. Carbon flow check U.K.
A carbon flow check using actual exhaust is strongly recommended for detecting measurement and control problems and verifying the proper operation of the partial flow dilution system. The carbon flow check should be run at least each time a new engine is installed, or something significant is changed in the test cell configuration.
The engine shall be operated at peak torque load and speed or any other steady-state mode that produces 5 % or more of CO 2 . The partial flow sampling system shall be operated with a dilution factor of about 15 to 1.
2.6.3. Pre-test check U.K.
A pre-test check shall be performed within two hours before the test run in the following way:
The accuracy of the flow meters shall be checked by the same method as used for calibration for at least two points, including flow values of G DILW that correspond to dilution ratios between five and 15 for the G TOTW value used during the test.
If it can be demonstrated by records of the calibration procedure described above that the flow meter calibration is stable over a longer period of time, the pre-test check may be omitted.
2.6.4. Determination of the transformation time U.K.
The system settings for the transformation time evaluation shall be exactly the same as during measurement of the test run. The transformation time shall be determined by the following method:
An independent reference flowmeter with a measurement range appropriate for the probe flow shall be put in series with and closely coupled to the probe. This flow meter shall have a transformation time of less than 100 ms for the flow step size used in the response time measurement, with flow restriction sufficiently low not to affect the dynamic performance of the partial flow dilution system, and consistent with good engineering practice.
A step change shall be introduced to the exhaust flow (or air flow if exhaust flow is calculated) input of the partial flow dilution system, from a low flow to at least 90 % of full scale. The trigger for the step change should be the same one as that used to start the look-ahead control in actual testing. The exhaust flow step stimulus and the flowmeter response shall be recorded at a sample rate of at least 10 Hz.
From this data, the transformation time shall be determined for the partial flow dilution system, which is the time from the initiation of the step stimulus to the 50 % point of the flowmeter response. In a similar manner, the transformation times of the G SE signal of the partial flow dilution system and of the G EXHW signal of the exhaust flow meter shall be determined. These signals are used in the regression checks performed after each test (Appendix I section 2.4).
The calculation shall be repeated for at least five rise-and-fall stimuli, and the results shall be averaged. The internal transformation time (< 100 ms) of the reference flowmeter shall be subtracted from this value. This is the ‘ look-ahead ’ value of the partial flow dilution system, which shall be applied in accordance with Appendix I section 2.4.]
[3. CALIBRATION OF THE CVS SYSTEM U.K.
3.1. General U.K.
The CVS system shall be calibrated by using an accurate flowmeter and means to change operating conditions.
The flow through the system shall be measured at different flow operating settings, and the control parameters of the system shall be measured and related to the flow.
Various type of flowmeters may be used, e.g. calibrated venturi, calibrated laminar flowmeter, calibrated turbine meter.
3.2. Calibration of the positive displacement pump (PDP) U.K.
All the parameters related to the pump shall be simultaneously measured along with the parameters related to a calibration venturi which is connected in series with the pump. The calculated flow rate (in m 3 /min at pump inlet, absolute pressure and temperature) shall be plotted against a correlation function which is the value of a specific combination of pump parameters. The linear equation which relates the pump flow and the correlation function shall be determined. If a CVS has a multiple speed drive, the calibration shall be performed for each range used.
Temperature stability shall be maintained during calibration.
Leaks in all the connections and ducting between the calibration venturi and the CVS pump shall be maintained lower than 0,3 % of the lowest flow point (highest restriction and lowest PDP speed point).
3.2.1. Data analysis U.K.
The air flowrate (Q s ) at each restriction setting (minimum 6 settings) shall be calculated in standard m 3 /min from the flowmeter data using the manufacturer's prescribed method. The air flow rate shall then be converted to pump flow (V 0 ) in m 3 /rev at absolute pump inlet temperature and pressure as follows
where,
Q s
=
air flow rate at standard conditions (101,3 kPa, 273 K) (m 3 /s)
T
=
temperature at pump inlet (K)
p A
=
absolute pressure at pump inlet (p B - p 1 ) (kPa)
To account for the interaction of pressure variations at the pump and the pump slip rate, the correlation function (X 0 ) between pump speed, pressure differential from pump inlet to pump outlet and absolute pump outlet pressure shall be calculated as follows:
where,
p A
=
absolute outlet pressure at pump outlet (kPa)
A linear least-square fit shall be performed to generate the calibration equation as follows:
D 0 and m are the intercept and slope constants, respectively, describing the regression lines.
For a CVS system with multiple speeds, the calibration curves generated for the different pump flow ranges shall be approximately parallel, and the intercept values (D 0 ) shall increase as the pump flow range decreases.
The values calculated by the equation shall be within ± 0,5 % of the measured value of V 0 . Values of m will vary from one pump to another. Particulate influx over time will cause the pump slip to decrease, as reflected by lower values for m. Therefore, calibration shall be performed at pump start-up, after major maintenance, and if the total system verification (section 3.5) indicates a change in the slip rate.
3.3. Calibration of the critical flow venturi (CFV) U.K.
Calibration of the CFV is based upon the flow equation for a critical venturi. Gas flow is a function of inlet pressure and temperature, as shown below:
where,
K v
=
calibration coefficient
p A
=
absolute pressure at venturi inlet (kPa)
T
=
temperature at venturi inlet (K)
3.3.1. Data analysis U.K.
The air flow rate (Q s ) at each restriction setting (minimum 8 settings) shall be calculated in standard m 3 /min from the flowmeter data using the manufacturer's prescribed method. The calibration coefficient shall be calculated from the calibration data for each setting as follows:
where,
Q s
=
air flow rate at standard conditions (101,3 kPa, 273 K) (m 3 /s)
T
=
temperature at the venturi inlet (K)
p A
=
absolute pressure at venturi inlet (kPa)
To determine the range of critical flow, K v shall be plotted as a function of venturi inlet pressure. For critical (choked) flow, K v will have a relatively constant value. As pressure decreases (vacuum increases), the venturi becomes unchoked and K v decreases, which indicates that the CFV is operated outside the permissible range.
For a minimum of eight points in the region of critical flow, the average K V and the standard deviation shall be calculated. The standard deviation shall not exceed ± 0,3 % of the average K V
3.4. Calibration of the subsonic venturi (SSV) U.K.
Calibration of the SSV is based upon the flow equation for a subsonic venturi. Gas flow is a function of inlet pressure and temperature, pressure drop between the SSV inlet and throat, as shown below:
where,
A 0
=
collection of constants and units conversions
d
=
diameter of the SSV throat (m)
C d
=
discharge coefficient of the SSV
P A
=
absolute pressure at venturi inlet (kPa)
T
=
temperature at the venturi inlet (K)
3.4.1. Data analysis U.K.
The air flow rate (Q SSV ) at each flow setting (minimum 16 settings) shall be calculated in standard m 3 /min from the flowmeter data using the manufacturer's prescribed method. The discharge coefficient shall be calculated from the calibration data for each setting as follows:
where,
Q SSV
=
air flow rate at standard conditions (101,3 kPa, 273 K), m 3 /s
T
=
temperature at the venturi inlet, K
d
=
diameter of the SSV throat, m
To determine the range of subsonic flow, C d shall be plotted as a function of Reynolds number, at the SSV throat. The Re at the SSV throat is calculated with the following formula:
where,
A 1
=
a collection of constants and units conversions
Q SSV
=
air flow rate at standard conditions (101,3 kPa, 273 K) (m 3 /s)
d
=
diameter of the SSV throat (m)
μ
=
absolute or dynamic viscosity of the gas, calculated with the following formula:
where:
Because Q SSV is an input to the Re formula, the calculations must be started with an initial guess for Q SSV or C d of the calibration venturi, and repeated until Q SSV converges. The convergence method must be accurate to 0,1 % or better.
For a minimum of sixteen points in the subsonic flow region, the calculated values of C d from the resulting calibration curve fit equation must be within ± 0,5 % of the measured C d for each calibration point.
3.5. Total system verification U.K.
The total accuracy of the CVS sampling system and analytical system shall be determined by introducing a known mass of a pollutant gas into the system while it is being operated in the normal manner. The pollutant is analysed, and the mass calculated according to Annex III, Appendix 3, section 2.4.1 except in the case of propane where a factor of 0,000472 is used in place of 0,000479 for HC. Either of the following two techniques shall be used.
3.5.1. Metering with a critical flow orifice U.K.
A known quantity of pure gas (propane) shall be fed into the CVS system through a calibrated critical orifice. If the inlet pressure is high enough, the flow rate, which is adjusted by means of the critical flow orifice, is independent of the orifice outlet pressure (critical flow). The CVS system shall be operated as in a normal exhaust emission test for about five to 10 minutes. A gas sample shall be analysed with the usual equipment (sampling bag or integrating method), and the mass of the gas calculated. The mass so determined shall be within ± 3 % of the known mass of the gas injected.
3.5.2. Metering by means of a gravimetric technique U.K.
The weight of a small cylinder filled with propane shall be determined with a precision of ± 0,01 g. For about five to 10 minutes, the CVS system shall be operated as in a normal exhaust emission test, while carbon monoxide or propane is injected into the system. The quantity of pure gas discharged shall be determined by means of differential weighing. A gas sample shall be analysed with the usual equipment (sampling bag or integrating method), and the mass of the gas calculated. The mass so determined shall be within ± 3 % of the known mass of the gas injected.]
Appendix 3
[DATA EVALUATION AND CALCULATIONS]
1. [DATA EVALUATION AND CALCULATIONS — NRSC TEST] U.K.
1.1.Gaseous emissions data evaluationU.K.
For the evaluation of the gaseous emissions, the chart reading of the last 60 seconds of each mode shall be averaged, and the average concentrations (conc) of HC, CO, NOx and CO2 if the carbon balance method is used, during each mode shall be determined from the average chart readings and the corresponding calibration data. A different type of recording can be used if it ensures an equivalent data acquisition.
The average background concentrations (concd) may be determined from the bag readings of the dilution air or from the continous (non-bag) background reading and the corresponding calibration data.
[1.2. Particulate emissions U.K.
For the evaluation of the particulates, the total sample masses (MSAM, i) through the filters shall be recorded for each mode. The filters shall be returned to the weighing chamber and conditioned for at least one hour, but not more than 80 hours, and then weighed. The gross weight of the filters shall be recorded and the tare weight (see section 3.1, Annex III) subtracted. The particulate mass (Mf for single filter method; Mf, i for the multiple filter method) is the sum of the particulate masses collected on the primary and back-up filters. If background correction is to be applied, the dilution air mass (MDIL) through the filters and the particulate mass (Md) shall be recorded. If more than one measurement was made, the quotient Md/MDIL must be calculated for each single measurement and the values averaged.]
1.3.Calculation of the gaseous emissionsU.K.
The finally reported test results shall be derived through the following steps:
[1.3.1. Determination of the exhaust gas flow U.K.
The exhaust gas flow rate (G EXHW ,) shall be determined for each mode according to Annex III, Appendix 1, sections 1.2.1. to 1.2.3.
When using a full flow dilution system, the total dilute exhaust gas flow rate (G TOTW ,) shall be determined for each mode according to Annex III, Appendix 1, section 1.2.4.]
[1.3.2. Dry/wet correction U.K.
Dry/wet correction (G EXHW ,) shall be determined for each mode according to Annex III, Appendix 1, sections 1.2.1. to 1.2.3.
When applying G EXHW the measured concentration shall be converted to a wet basis according to the following formulae, if not already measured on a wet basis:
conc (wet) = k w × conc (dry)
For the raw exhaust gas:
For the diluted gas:
or:
For the dilution air:
For the intake air (if different from the dilution air):
where:
H a
:
absolute humidity of the intake air (g water per kg dry air)
H d
:
absolute humidity of the dilution air (g water per kg dry air)
R d
:
relative humidity of the dilution air ( %)
R a
:
relative humidity of the intake air ( %)
p d
:
saturation vapour pressure of the dilution air (kPa)
p a
:
saturation vapour pressure of the intake air (kPa)
p B
:
total barometric pressure (kPa).
Note: H a and H d may be derived from relative humidity measurement, as described above, or from dewpoint measurement, vapour pressure measurement or dry/wet bulb measurement using the generally accepted formulae. U.K.
1.3.3. Humidity correction for NO x U.K.
As the NO x emission depends on ambient air conditions, the NO x concentration shall be corrected for ambient air temperature and humidity by the factors K H given in the following formula:
where:
T a
:
temperatures of the air in (K)
Ha
:
humidity of the intake air (g water per kg dry air):
where:
R a
:
relative humidity of the intake air ( %)
p a
:
saturation vapour pressure of the intake air (kPa)
p B
:
total barometric pressure (kPa).
Note: H a may be derived from relative humidity measurement, as described above, or from dewpoint measurement, vapour pressure measurement or dry/wet bulb measurement using the generally accepted formulae. U.K.
1.3.4. Calculation of emission mass flow rates U.K.
The emission mass flow rates for each mode shall be calculated as follows:
(a)
For the raw exhaust gas () :
Gas mass = u × conc × G EXHW
(b)
For the dilute exhaust gas () :
Gas mass = u × conc c × G TOTW
where:
conc c is the background corrected concentration
or:
DF=13,4/conc CO2
The coefficients u - wet shall be used according to Table 4:
Table 4: Values of the coefficients u - wet for various exhaust components U.K.
Gas | u | conc |
---|
NO x | 0,001587 | ppm |
CO | 0,000966 | ppm |
HC | 0,000479 | ppm |
CO 2 | 15,19 | percent |
The density of HC is based upon an average carbon to hydrogen ratio of 1:1,85.
1.3.5. Calculation of the specific emissions U.K.
The specific emission (g/kWh) shall be calculated for all individual components in the following way:
where P i = P m, i + P AE, i .
The weighting factors and the number of modes (n) used in the above calculation are according to Annex III, section 3.7.1.
1.4. Calculation of the particulate emission U.K.
The particulate emission shall be calculated in the following way:
1.4.1. Humidity correction factor for particulates U.K.
As the particulate emission of diesel engines depends on ambient air conditions, the particulate mass flow rate shall be corrected for ambient air humidity with the factor K p given in the following formula:
where:
H a
:
humidity of the intake air, gram of water per kg dry air
where:
R a
:
relative humidity of the intake air (%)
p a
:
saturation vapour pressure of the intake air (kPa)
p B
:
total barometric pressure (kPa)
Note: H a may be derived from relative humidity measurement, as described above, or from dewpoint measurement, vapour pressure measurement or dry/wet bulb measurement using the generally accepted formulae U.K.
1.4.2. Partial flow dilution system U.K.
The final reported test results of the particulate emission shall be derived through the following steps. Since various types of dilution rate control may be used, different calculation methods for equivalent diluted exhaust gas mass flow rate G EDF apply. All calculations shall be based upon the average values of the individual modes (i) during the sampling period.
1.4.2.1. Isokinetic systems U.K.
G EDFW, i = G EXHW, i × q i
where r corresponds to the ratio of the cross sectional areas of the isokinetic probe A p and exhaust pipe A T :
1.4.2.2. Systems with measurement of CO 2 or NO x concentration U.K.
G EDFW, i = G EXHW, i × q i
where:
Conc E
=
wet concentration of the tracer gas in raw exhaust
Conc D
=
wet concentration of the tracer gas in the diluted exhaust
Conc A
=
wet concentration of the tracer gas in the dilution air
Concentrations measured on a dry basis shall be converted to a wet basis according to section 1.3.2.
1.4.2.3. Systems with CO2 measurement and carbon balance method U.K.
where:
CO 2D
=
CO 2 concentration of the diluted exhaust
CO 2A
=
CO 2 concentration of the dilution air
(concentrations in volume % on wet basis)
This equation is based upon the carbon balance assumption (carbon atoms supplied to the engine are emitted as CO 2 ) and derived through the following steps:
G EDFW, i = G EXHW, i × q i
and:
1.4.2.4. Systems with flow measurement U.K.
G EDFW, i = G EXHW, i × q i
1.4.3. Full flow dilution system U.K.
The final reported test results of the particulate emission shall be derived through the following steps.
All calculations shall be based upon the average values of the individual modes (i) during the sampling period.
G EDFW, i = G TOTW, i
1.4.4. Calculation of the particulate mass flow rate U.K.
The particulate mass flow rate shall be calculated as follows:
For the single filter method:
where:
(G EDFW ) aver over the test cycle shall be determined by summation of the average values of the individual modes during the sampling period:
where i = 1, . . . n
For the multiple filter method:
where i = 1, . . . n
The particulate mass flow rate may be background corrected as follows:
For single filter method:
If more than one measurement is made, (M d /M DIL ) shall be replaced with (M d /M DIL ) aver
or:
DF=13,4/concCO 2
For multiple filter method:
If more than one measurement is made, (M d /M DIL ) shall be replaced with (M d /M DIL ) aver
or:
DF= 13,4/concCO 2
1.4.5. Calculation of the specific emissions U.K.
The specific emission of particulates PT (g/kWh) shall be calculated in the following way () :
For the single filter method:
For the multiple filter method:
1.4.6. Effective weighting factor U.K.
For the single filter method, the effective weighting factor WF E, i for each mode shall be calculated in the following way:
where i = l, . . . n.
The value of the effective weighting factors shall be within ± 0,005 (absolute value) of the weighting factors listed in Annex III, section 3.7.1.]
[2. DATA EVALUATION AND CALCULATIONS (NRTC TEST) U.K.
The two following measurement principles that can be used for the evaluation of pollutant emissions over the NRTC cycle are described in this section:
the gaseous components are measured in the raw exhaust gas on a real-time basis, and the particulates are determined using a partial flow dilution system,
the gaseous components and the particulates are determined using a full flow dilution system (CVS system).
2.1. Calculation of gaseous emissions in the raw exhaust gas and of the particulate emissions with a partial flow dilution system U.K.
2.1.1. Introduction U.K.
The instantaneous concentration signals of the gaseous components are used for the calculation of the mass emissions by multiplication with the instantaneous exhaust mass flow rate. The exhaust mass flow rate may be measured directly, or calculated using the methods described in Annex III, Appendix 1, section 2.2.3 (intake air and fuel flow measurement, tracer method, intake air and air/fuel ratio measurement). Special attention shall be paid to the response times of the different instruments. These differences shall be accounted for by time aligning the signals.
For particulates, the exhaust mass flow rate signals are used for controlling the partial flow dilution system to take a sample proportional to the exhaust mass flow rate. The quality of proportionality is checked by applying a regression analysis between sample and exhaust flow as described in Annex III, Appendix 1, section 2.4.
2.1.2. Determination of the gaseous components U.K.
2.1.2.1. Calculation of mass emission U.K.
The mass of the pollutants M gas (g/test) shall be determined by calculating the instantaneous mass emissions from the raw concentrations of the pollutants, the u values from Table 4 (see also Section 1.3.4) and the exhaust mass flow, aligned for the transformation time and integrating the instantaneous values over the cycle. Preferably, the concentrations should be measured on a wet basis. If measured on a dry basis, the dry/wet correction as described here below shall be applied to the instantaneous concentration values before any further calculation is done.
Table 4: Values of the coefficients u — wet for various exhaust components U.K.
Gas | u | conc |
---|
NO x | 0,001587 | ppm |
CO | 0,000966 | ppm |
HC | 0,000479 | ppm |
CO 2 | 15,19 | percent |
The density of HC is based upon an average carbon to hydrogen ratio of 1:1,85.
The following formula shall be applied:
where
u
=
ratio between density of exhaust component and density of exhaust gas
conc i
=
instantaneous concentration of the respective component in the raw exhaust gas (ppm)
G EXHW, i
=
instantaneous exhaust mass flow (kg/s)
f
=
data sampling rate (Hz)
n
=
number of measurements
For the calculation of NO x , the humidity correction factor k H , as described here below, shall be used.
The instantaneously measured concentration shall be converted to a wet basis as described here below, if not already measured on a wet basis
2.1.2.2. Dry/wet correction U.K.
If the instantaneously measured concentration is measured on a dry basis, it shall be converted to a wet basis according to the following formulae:
conc wet = k W x conc dry
where
with
where
conc CO2
=
dry CO 2 concentration (%)
conc CO
=
dry CO concentration (%)
H a
=
intake air humidity, (g water per kg dry air)
R a
:
relative humidity of the intake air (%)
p a
:
saturation vapour pressure of the intake air (kPa)
p B
:
total barometric pressure (kPa)
Note: H a may be derived from relative humidity measurement, as described above, or from dewpoint measurement, vapour pressure measurement or dry/wet bulb measurement using the generally accepted formulae. U.K.
2.1.2.3. NO x correction for humidity and temperature U.K.
As the NO x emission depends on ambient air conditions, the NO x concentration shall be corrected for humidity and ambient air temperature with the factors given in the following formula:
with:
T a
=
temperature of the intake air, K
H a
=
humidity of the intake air, g water per kg dry air
where:
R a
:
relative humidity of the intake air ( %)
p a
:
saturation vapour pressure of the intake air (kPa)
p B
:
total barometric pressure (kPa)
Note: H a may be derived from relative humidity measurement, as described above, or from dewpoint measurement, vapour pressure measurement or dry/wet bulb measurement using the generally accepted formulae. U.K.
2.1.2.4. Calculation of the specific emissions U.K.
The specific emissions (g/kWh) shall be calculated for each individual component in the following way:
Individual gas = M gas / W act
where:
W act
=
actual cycle work as determined in Annex III Section 4.6.2 (kWh)
2.1.3. Particulate determination U.K.
2.1.3.1. Calculation of mass emission U.K.
The mass of particulates M PT (g/test) shall be calculated by either of the following methods:
(a)
where
M f
=
particulate mass sampled over the cycle (mg)
M SAM
=
mass of diluted exhaust gas passing the particulate collection filters (kg)
M EDFW
=
mass of equivalent diluted exhaust gas over the cycle (kg)
The total mass of equivalent diluted exhaust gas mass over the cycle shall be determined as follows:
where
G EDFW ,i
=
instantaneous equivalent diluted exhaust mass flow rate (kg/s)
G EXHW ,i
=
instantaneous exhaust mass flow rate (kg/s)
q i
=
instantaneous dilution ratio
G TOTW ,I
=
instantaneous diluted exhaust mass flow rate through dilution tunnel (kg/s)
G DILW ,i
=
instantaneous dilution air mass flow rate (kg/s)
f
=
data sampling rate (Hz)
n
=
number of measurements
(b)
where
M f
=
particulate mass sampled over the cycle (mg)
r s
=
average sample ratio over the test cycle
where
M SE
=
sampled exhaust mass over the cycle (kg)
M EXHW
=
total exhaust mass flow over the cycle (kg)
M SAM
=
mass of diluted exhaust gas passing the particulate collection filters (kg)
M TOTW
=
mass of diluted exhaust gas passing the dilution tunnel (kg)
Note: In case of the total sampling type system, M SAM and M TOTW are identical . U.K.
2.1.3.2. Particulate correction factor for humidity U.K.
As the particulate emission of diesel engines depends on ambient air conditions, the particulate concentration shall be corrected for ambient air humidity with the factor Kp given in the following formula.
where
H a
=
humidity of the intake air in g water per kg dry air
R a
:
relative humidity of the intake air (%)
p a
:
saturation vapour pressure of the intake air (kPa)
p B
:
total barometric pressure (kPa)
Note: H a may be derived from relative humidity measurement, as described above, or from dewpoint measurement, vapour pressure measurement or dry/wet bulb measurement using the generally accepted formulae. U.K.
2.1.3.3. Calculation of the specific emissions U.K.
The particulate emission (g/kWh) shall be calculated in the following way:
where
W act
=
actual cycle work as determined in Annex III Section 4.6.2(kWh)
2.2. Determination of gaseous and particulate components with a full flow dilution system U.K.
For calculation of the emissions in the diluted exhaust gas, it is necessary to know the diluted exhaust gas mass flow rate. The total diluted exhaust gas flow over the cycle M TOTW (kg/test) shall be calculated from the measurement values over the cycle and the corresponding calibration data of the flow measurement device ( V 0 for PDP, K V for CFV, C d for SSV): the corresponding methods described in section 2.2.1 may be used. If the total sample mass of particulates ( M SAM ) and gaseous pollutants exceeds 0,5 % of the total CVS flow ( M TOTW ), the CVS flow shall be corrected for M SAM or the particulate sample flow shall be returned to the CVS prior to the flow measuring device.
2.2.1. Determination of the diluted exhaust gas flow U.K.
PDP-CVS system U.K.
The calculation of the mass flow over the cycle, if the temperature of the diluted exhaust is kept within ± 6 K over the cycle by using a heat exchanger, is as follows:
M TOTW = 1,293 x V 0 x N P x (p B - p 1 ) x273/(101,3 x T)
where
M TOTW
=
mass of the diluted exhaust gas on wet basis over the cycle
V 0
=
volume of gas pumped per revolution under test conditions (m 3 /rev)
N P
=
total revolutions of pump per test
p B
=
atmospheric pressure in the test cell (kPa)
p 1
=
pressure drop below atmospheric at the pump inlet (kPa)
T
=
average temperature of the diluted exhaust gas at pump inlet over thecycle (K)
If a system with flow compensation is used (i.e. without heat exchanger), the instantaneous mass emissions shall be calculated and integrated over the cycle. In this case, the instantaneous mass of the diluted exhaust gas shall be calculated as follows:
M TOTW ,i = 1,293 × V 0 × N P, i x (p B – p 1 ) × 273 /( 101,3 x T)
where
N P, i
=
total revolutions of pump per time interval
CFV-CVS system U.K.
The calculation of the mass flow over the cycle, if the temperature of the diluted exhaust gas is kept within ± 11 K over the cycle by using a heat exchanger, is as follows:
M TOTW = 1,293 × t × K v × p A /T 0,5
where
M TOTW
=
mass of the diluted exhaust gas on wet basis over the cycle
K V
=
calibration coefficient of the critical flow venturi for standard conditions,
p A
=
absolute pressure at venturi inlet (kPa)
T
=
absolute temperature at venturi inlet (K)
If a system with flow compensation is used (i.e. without heat exchanger), the instantaneous mass emissions shall be calculated and integrated over the cycle. In this case, the instantaneous mass of the diluted exhaust gas shall be calculated as follows:
M TOTW ,i = 1,293 × Δt i × K V × p A /T 0,5
where
SSV-CVS system U.K.
The calculation of the mass flow over the cycle is as follows if the temperature of the diluted exhaust is kept within ± 11 K over the cycle by using a heat exchanger:
where
A 0
=
collection of constants and units conversions = 0,006111 in SI units of
d
=
diameter of the SSV throat (m)
C d
=
discharge coefficient of the SSV
P A
=
absolute pressure at venturi inlet (kPa)
T
=
temperature at the venturi inlet (K)
If a system with flow compensation is used (i.e. without heat exchanger), the instantaneous mass emissions shall be calculated and integrated over the cycle. In this case, the instantaneous mass of the diluted exhaust gas shall be calculated as follows:
where
The real time calculation shall be initialised with either a reasonable value for C d , such as 0.98, or a reasonable value of Q ssv . If the calculation is initialised with Q ssv , the initial value of Q ssv shall be used to evaluate Re.
During all emissions tests, the Reynolds number at the SSV throat must be in the range of Reynolds numbers used to derive the calibration curve developed in Appendix 2 section 3.2.
2.2.2. NO x correction for humidity U.K.
As the NO x emission depends on ambient air conditions, the NO x concentration shall be corrected for ambient air humidity with the factors given in the following formulae.
where
T a
=
temperature of the air (K)
H a
=
humidity of the intake air (g water per kg dry air)
in which,
R a
=
relative humidity of the intake air (%)
p a
=
saturation vapour pressure of the intake air (kPa)
p B
=
total barometric pressure (kPa)
Note: H a may be derived from relative humidity measurement, as described above, or from dewpoint measurement, vapour pressure measurement or dry/wet bulb measurement using the generally accepted formulae. U.K.
2.2.3. Calculation of the emission mass flow U.K.
2.2.3.1. Systems with constant mass flow U.K.
For systems with heat exchanger, the mass of the pollutants M GAS (g/test) shall be determined from the following equation:
M gaz = u × conc × M TOTW
where
u
=
ratio between density of the exhaust component and density of diluted exhaust gas, as reported in Table 4, point 2.1.2.1
conc
=
average background corrected concentrations over the cycle from integration (mandatory for NO x and HC) or bag measurement (ppm)
M TOTW
=
total mass of diluted exhaust gas over the cycle as determined in section 2.2.1 (kg)
As the NO x emission depends on ambient air conditions, the NO x concentration shall be corrected for ambient air humidity with the factor k H , as described in section 2.2.2.
Concentrations measured on a dry basis shall be converted to a wet basis in accordance with section 1.3.2.
2.2.3.1.1. Determination of the background corrected concentrations U.K.
The average background concentration of the gaseous pollutants in the dilution air shall be subtracted from measured concentrations to get the net concentrations of the pollutants. The average values of the background concentrations can be determined by the sample bag method or by continuous measurement with integration. The following formula shall be used.
conc = conc e – conc d × ( 1 – ( 1 /DF))
where,
conc
=
concentration of the respective pollutant in the diluted exhaust gas, corrected by the amount of the respective pollutant contained in the dilution air (ppm)
conc e
=
concentration of the respective pollutant measured in the diluted exhaust gas (ppm)
conc d
=
concentration of the respective pollutant measured in the dilution air (ppm)
The dilution factor shall be calculated as follows:
2.2.3.2. Systems with flow compensation U.K.
For systems without heat exchanger, the mass of the pollutants M GAS (g/test) shall be determined by calculating the instantaneous mass emissions and integrating the instantaneous values over the cycle. Also, the background correction shall be applied directly to the instantaneous concentration value. The following formulae shall be applied:
where
conc e, i
=
instantaneous concentration of the respective pollutant measured in the diluted exhaust gas (ppm)
conc d
=
concentration of the respective pollutant measured in the dilution air (ppm)
u
=
ratio between density of the exhaust component and density of diluted exhaust gas, as reported in Table 4, point 2.1.2.1
M TOTW, i
=
instantaneous mass of the diluted exhaust gas (section 2.2.1) (kg)
M TOTW
=
total mass of diluted exhaust gas over the cycle (section 2.2.1) (kg)
DF
=
dilution factor as determined in point 2.2.3.1.1.
As the NO x emission depends on ambient air conditions, the NO x concentration shall be corrected for ambient air humidity with the factor k H , as described in section 2.2.2.
2.2.4. Calculation of the specific emissions U.K.
The specific emissions (g/kWh) shall be calculated for each individual component in the following way:
Individual gas = M gas / W act
where
W act
=
actual cycle work as determined in Annex III Section 4.6.2 (kWh)
2.2.5. Calculation of the particulate emission U.K.
2.2.5.1. Calculation of the mass flow U.K.
The particulate mass M PT (g/test) shall be calculated as follows:
M f
=
particulate mass sampled over the cycle (mg)
M TOTW
=
total mass of diluted exhaust gas over the cycle as determined in section 2.2.1 (kg)
M SAM
=
mass of diluted exhaust gas taken from the dilution tunnel for collecting particulates (kg)
and,
M f
=
M f, p + M f, b , if weighed separately (mg)
M f, p
=
particulate mass collected on the primary filter (mg)
M f, b
=
particulate mass collected on the back-up filter (mg)
If a double dilution system is used, the mass of the secondary dilution air shall be subtracted from the total mass of the double diluted exhaust gas sampled through the particulate filters.
M SAM = M TOT – M SEC
where
M TOT
=
mass of double diluted exhaust gas through particulate filter (kg)
M SEC
=
mass of secondary dilution air (kg)
If the particulate background level of the dilution air is determined in accordance with Annex III, section 4.4.4, the particulate mass may be background corrected. In this case, the particulate mass (g/test) shall be calculated as follows:
where
M f , M SAM , M TOTW
=
see above
M DIL
=
mass of primary dilution air sampled by background particulate sampler (kg)
M d
=
mass of the collected background particulates of the primary dilution air (mg)
DF
=
dilution factor as determined in section 2.2.3.1.1
2.2.5.2. Particulate correction factor for humidity U.K.
As the particulate emission of diesel engines depends on ambient air conditions, the particulate concentration shall be corrected for ambient air humidity with the factor Kp given in the following formula.
where
H a
=
humidity of the intake air in g water per kg dry air
where:
R a
:
relative humidity of the intake air ( %)
p a
:
saturation vapour pressure of the intake air (kPa)
p B
:
total barometric pressure (kPa)
Note: H a may be derived from relative humidity measurement, as described above, or from dewpoint measurement, vapour pressure measurement or dry/wet bulb measurement using the generally accepted formulae. U.K.
2.2.5.3. Calculation of the specific emission U.K.
The particulate emission (g/kWh) shall be calculated in the following way:
where
W act
=
actual cycle work, as determined in Annex III Section 4.6.2 (kWh)]
[Appendix 4
NRTC ENGINE DYNAMOMETER SCHEDULE U.K.
Time (s) | Norm. Speed (%) | Norm. Torque (%) |
---|
1 | 0 | 0 |
2 | 0 | 0 |
3 | 0 | 0 |
4 | 0 | 0 |
5 | 0 | 0 |
6 | 0 | 0 |
7 | 0 | 0 |
8 | 0 | 0 |
9 | 0 | 0 |
10 | 0 | 0 |
11 | 0 | 0 |
12 | 0 | 0 |
13 | 0 | 0 |
14 | 0 | 0 |
15 | 0 | 0 |
16 | 0 | 0 |
17 | 0 | 0 |
18 | 0 | 0 |
19 | 0 | 0 |
20 | 0 | 0 |
21 | 0 | 0 |
22 | 0 | 0 |
23 | 0 | 0 |
24 | 1 | 3 |
25 | 1 | 3 |
26 | 1 | 3 |
27 | 1 | 3 |
28 | 1 | 3 |
29 | 1 | 3 |
30 | 1 | 6 |
31 | 1 | 6 |
32 | 2 | 1 |
33 | 4 | 13 |
34 | 7 | 18 |
35 | 9 | 21 |
36 | 17 | 20 |
37 | 33 | 42 |
38 | 57 | 46 |
39 | 44 | 33 |
40 | 31 | 0 |
41 | 22 | 27 |
42 | 33 | 43 |
43 | 80 | 49 |
44 | 105 | 47 |
45 | 98 | 70 |
46 | 104 | 36 |
47 | 104 | 65 |
48 | 96 | 71 |
49 | 101 | 62 |
50 | 102 | 51 |
51 | 102 | 50 |
52 | 102 | 46 |
53 | 102 | 41 |
54 | 102 | 31 |
55 | 89 | 2 |
56 | 82 | 0 |
57 | 47 | 1 |
58 | 23 | 1 |
59 | 1 | 3 |
60 | 1 | 8 |
61 | 1 | 3 |
62 | 1 | 5 |
63 | 1 | 6 |
64 | 1 | 4 |
65 | 1 | 4 |
66 | 0 | 6 |
67 | 1 | 4 |
68 | 9 | 21 |
69 | 25 | 56 |
70 | 64 | 26 |
71 | 60 | 31 |
72 | 63 | 20 |
73 | 62 | 24 |
74 | 64 | 8 |
75 | 58 | 44 |
76 | 65 | 10 |
77 | 65 | 12 |
78 | 68 | 23 |
79 | 69 | 30 |
80 | 71 | 30 |
81 | 74 | 15 |
82 | 71 | 23 |
83 | 73 | 20 |
84 | 73 | 21 |
85 | 73 | 19 |
86 | 70 | 33 |
87 | 70 | 34 |
88 | 65 | 47 |
89 | 66 | 47 |
90 | 64 | 53 |
91 | 65 | 45 |
92 | 66 | 38 |
93 | 67 | 49 |
94 | 69 | 39 |
95 | 69 | 39 |
96 | 66 | 42 |
97 | 71 | 29 |
98 | 75 | 29 |
99 | 72 | 23 |
100 | 74 | 22 |
101 | 75 | 24 |
102 | 73 | 30 |
103 | 74 | 24 |
104 | 77 | 6 |
105 | 76 | 12 |
106 | 74 | 39 |
107 | 72 | 30 |
108 | 75 | 22 |
109 | 78 | 64 |
110 | 102 | 34 |
111 | 103 | 28 |
112 | 103 | 28 |
113 | 103 | 19 |
114 | 103 | 32 |
115 | 104 | 25 |
116 | 103 | 38 |
117 | 103 | 39 |
118 | 103 | 34 |
119 | 102 | 44 |
120 | 103 | 38 |
121 | 102 | 43 |
122 | 103 | 34 |
123 | 102 | 41 |
124 | 103 | 44 |
125 | 103 | 37 |
126 | 103 | 27 |
127 | 104 | 13 |
128 | 104 | 30 |
129 | 104 | 19 |
130 | 103 | 28 |
131 | 104 | 40 |
132 | 104 | 32 |
133 | 101 | 63 |
134 | 102 | 54 |
135 | 102 | 52 |
136 | 102 | 51 |
137 | 103 | 40 |
138 | 104 | 34 |
139 | 102 | 36 |
140 | 104 | 44 |
141 | 103 | 44 |
142 | 104 | 33 |
143 | 102 | 27 |
144 | 103 | 26 |
145 | 79 | 53 |
146 | 51 | 37 |
147 | 24 | 23 |
148 | 13 | 33 |
149 | 19 | 55 |
150 | 45 | 30 |
151 | 34 | 7 |
152 | 14 | 4 |
153 | 8 | 16 |
154 | 15 | 6 |
155 | 39 | 47 |
156 | 39 | 4 |
157 | 35 | 26 |
158 | 27 | 38 |
159 | 43 | 40 |
160 | 14 | 23 |
161 | 10 | 10 |
162 | 15 | 33 |
163 | 35 | 72 |
164 | 60 | 39 |
165 | 55 | 31 |
166 | 47 | 30 |
167 | 16 | 7 |
168 | 0 | 6 |
169 | 0 | 8 |
170 | 0 | 8 |
171 | 0 | 2 |
172 | 2 | 17 |
173 | 10 | 28 |
174 | 28 | 31 |
175 | 33 | 30 |
176 | 36 | 0 |
177 | 19 | 10 |
178 | 1 | 18 |
179 | 0 | 16 |
180 | 1 | 3 |
181 | 1 | 4 |
182 | 1 | 5 |
183 | 1 | 6 |
184 | 1 | 5 |
185 | 1 | 3 |
186 | 1 | 4 |
187 | 1 | 4 |
188 | 1 | 6 |
189 | 8 | 18 |
190 | 20 | 51 |
191 | 49 | 19 |
192 | 41 | 13 |
193 | 31 | 16 |
194 | 28 | 21 |
195 | 21 | 17 |
196 | 31 | 21 |
197 | 21 | 8 |
198 | 0 | 14 |
199 | 0 | 12 |
200 | 3 | 8 |
201 | 3 | 22 |
202 | 12 | 20 |
203 | 14 | 20 |
204 | 16 | 17 |
205 | 20 | 18 |
206 | 27 | 34 |
207 | 32 | 33 |
208 | 41 | 31 |
209 | 43 | 31 |
210 | 37 | 33 |
211 | 26 | 18 |
212 | 18 | 29 |
213 | 14 | 51 |
214 | 13 | 11 |
215 | 12 | 9 |
216 | 15 | 33 |
217 | 20 | 25 |
218 | 25 | 17 |
219 | 31 | 29 |
220 | 36 | 66 |
221 | 66 | 40 |
222 | 50 | 13 |
223 | 16 | 24 |
224 | 26 | 50 |
225 | 64 | 23 |
226 | 81 | 20 |
227 | 83 | 11 |
228 | 79 | 23 |
229 | 76 | 31 |
230 | 68 | 24 |
231 | 59 | 33 |
232 | 59 | 3 |
233 | 25 | 7 |
234 | 21 | 10 |
235 | 20 | 19 |
236 | 4 | 10 |
237 | 5 | 7 |
238 | 4 | 5 |
239 | 4 | 6 |
240 | 4 | 6 |
241 | 4 | 5 |
242 | 7 | 5 |
243 | 16 | 28 |
244 | 28 | 25 |
245 | 52 | 53 |
246 | 50 | 8 |
247 | 26 | 40 |
248 | 48 | 29 |
249 | 54 | 39 |
250 | 60 | 42 |
251 | 48 | 18 |
252 | 54 | 51 |
253 | 88 | 90 |
254 | 103 | 84 |
255 | 103 | 85 |
256 | 102 | 84 |
257 | 58 | 66 |
258 | 64 | 97 |
259 | 56 | 80 |
260 | 51 | 67 |
261 | 52 | 96 |
262 | 63 | 62 |
263 | 71 | 6 |
264 | 33 | 16 |
265 | 47 | 45 |
266 | 43 | 56 |
267 | 42 | 27 |
268 | 42 | 64 |
269 | 75 | 74 |
270 | 68 | 96 |
271 | 86 | 61 |
272 | 66 | 0 |
273 | 37 | 0 |
274 | 45 | 37 |
275 | 68 | 96 |
276 | 80 | 97 |
277 | 92 | 96 |
278 | 90 | 97 |
279 | 82 | 96 |
280 | 94 | 81 |
281 | 90 | 85 |
282 | 96 | 65 |
283 | 70 | 96 |
284 | 55 | 95 |
285 | 70 | 96 |
286 | 79 | 96 |
287 | 81 | 71 |
288 | 71 | 60 |
289 | 92 | 65 |
290 | 82 | 63 |
291 | 61 | 47 |
292 | 52 | 37 |
293 | 24 | 0 |
294 | 20 | 7 |
295 | 39 | 48 |
296 | 39 | 54 |
297 | 63 | 58 |
298 | 53 | 31 |
299 | 51 | 24 |
300 | 48 | 40 |
301 | 39 | 0 |
302 | 35 | 18 |
303 | 36 | 16 |
304 | 29 | 17 |
305 | 28 | 21 |
306 | 31 | 15 |
307 | 31 | 10 |
308 | 43 | 19 |
309 | 49 | 63 |
310 | 78 | 61 |
311 | 78 | 46 |
312 | 66 | 65 |
313 | 78 | 97 |
314 | 84 | 63 |
315 | 57 | 26 |
316 | 36 | 22 |
317 | 20 | 34 |
318 | 19 | 8 |
319 | 9 | 10 |
320 | 5 | 5 |
321 | 7 | 11 |
322 | 15 | 15 |
323 | 12 | 9 |
324 | 13 | 27 |
325 | 15 | 28 |
326 | 16 | 28 |
327 | 16 | 31 |
328 | 15 | 20 |
329 | 17 | 0 |
330 | 20 | 34 |
331 | 21 | 25 |
332 | 20 | 0 |
333 | 23 | 25 |
334 | 30 | 58 |
335 | 63 | 96 |
336 | 83 | 60 |
337 | 61 | 0 |
338 | 26 | 0 |
339 | 29 | 44 |
340 | 68 | 97 |
341 | 80 | 97 |
342 | 88 | 97 |
343 | 99 | 88 |
344 | 102 | 86 |
345 | 100 | 82 |
346 | 74 | 79 |
347 | 57 | 79 |
348 | 76 | 97 |
349 | 84 | 97 |
350 | 86 | 97 |
351 | 81 | 98 |
352 | 83 | 83 |
353 | 65 | 96 |
354 | 93 | 72 |
355 | 63 | 60 |
356 | 72 | 49 |
357 | 56 | 27 |
358 | 29 | 0 |
359 | 18 | 13 |
360 | 25 | 11 |
361 | 28 | 24 |
362 | 34 | 53 |
363 | 65 | 83 |
364 | 80 | 44 |
365 | 77 | 46 |
366 | 76 | 50 |
367 | 45 | 52 |
368 | 61 | 98 |
369 | 61 | 69 |
370 | 63 | 49 |
371 | 32 | 0 |
372 | 10 | 8 |
373 | 17 | 7 |
374 | 16 | 13 |
375 | 11 | 6 |
376 | 9 | 5 |
377 | 9 | 12 |
378 | 12 | 46 |
379 | 15 | 30 |
380 | 26 | 28 |
381 | 13 | 9 |
382 | 16 | 21 |
383 | 24 | 4 |
384 | 36 | 43 |
385 | 65 | 85 |
386 | 78 | 66 |
387 | 63 | 39 |
388 | 32 | 34 |
389 | 46 | 55 |
390 | 47 | 42 |
391 | 42 | 39 |
392 | 27 | 0 |
393 | 14 | 5 |
394 | 14 | 14 |
395 | 24 | 54 |
396 | 60 | 90 |
397 | 53 | 66 |
398 | 70 | 48 |
399 | 77 | 93 |
400 | 79 | 67 |
401 | 46 | 65 |
402 | 69 | 98 |
403 | 80 | 97 |
404 | 74 | 97 |
405 | 75 | 98 |
406 | 56 | 61 |
407 | 42 | 0 |
408 | 36 | 32 |
409 | 34 | 43 |
410 | 68 | 83 |
411 | 102 | 48 |
412 | 62 | 0 |
413 | 41 | 39 |
414 | 71 | 86 |
415 | 91 | 52 |
416 | 89 | 55 |
417 | 89 | 56 |
418 | 88 | 58 |
419 | 78 | 69 |
420 | 98 | 39 |
421 | 64 | 61 |
422 | 90 | 34 |
423 | 88 | 38 |
424 | 97 | 62 |
425 | 100 | 53 |
426 | 81 | 58 |
427 | 74 | 51 |
428 | 76 | 57 |
429 | 76 | 72 |
430 | 85 | 72 |
431 | 84 | 60 |
432 | 83 | 72 |
433 | 83 | 72 |
434 | 86 | 72 |
435 | 89 | 72 |
436 | 86 | 72 |
437 | 87 | 72 |
438 | 88 | 72 |
439 | 88 | 71 |
440 | 87 | 72 |
441 | 85 | 71 |
442 | 88 | 72 |
443 | 88 | 72 |
444 | 84 | 72 |
445 | 83 | 73 |
446 | 77 | 73 |
447 | 74 | 73 |
448 | 76 | 72 |
449 | 46 | 77 |
450 | 78 | 62 |
451 | 79 | 35 |
452 | 82 | 38 |
453 | 81 | 41 |
454 | 79 | 37 |
455 | 78 | 35 |
456 | 78 | 38 |
457 | 78 | 46 |
458 | 75 | 49 |
459 | 73 | 50 |
460 | 79 | 58 |
461 | 79 | 71 |
462 | 83 | 44 |
463 | 53 | 48 |
464 | 40 | 48 |
465 | 51 | 75 |
466 | 75 | 72 |
467 | 89 | 67 |
468 | 93 | 60 |
469 | 89 | 73 |
470 | 86 | 73 |
471 | 81 | 73 |
472 | 78 | 73 |
473 | 78 | 73 |
474 | 76 | 73 |
475 | 79 | 73 |
476 | 82 | 73 |
477 | 86 | 73 |
478 | 88 | 72 |
479 | 92 | 71 |
480 | 97 | 54 |
481 | 73 | 43 |
482 | 36 | 64 |
483 | 63 | 31 |
484 | 78 | 1 |
485 | 69 | 27 |
486 | 67 | 28 |
487 | 72 | 9 |
488 | 71 | 9 |
489 | 78 | 36 |
490 | 81 | 56 |
491 | 75 | 53 |
492 | 60 | 45 |
493 | 50 | 37 |
494 | 66 | 41 |
495 | 51 | 61 |
496 | 68 | 47 |
497 | 29 | 42 |
498 | 24 | 73 |
499 | 64 | 71 |
500 | 90 | 71 |
501 | 100 | 61 |
502 | 94 | 73 |
503 | 84 | 73 |
504 | 79 | 73 |
505 | 75 | 72 |
506 | 78 | 73 |
507 | 80 | 73 |
508 | 81 | 73 |
509 | 81 | 73 |
510 | 83 | 73 |
511 | 85 | 73 |
512 | 84 | 73 |
513 | 85 | 73 |
514 | 86 | 73 |
515 | 85 | 73 |
516 | 85 | 73 |
517 | 85 | 72 |
518 | 85 | 73 |
519 | 83 | 73 |
520 | 79 | 73 |
521 | 78 | 73 |
522 | 81 | 73 |
523 | 82 | 72 |
524 | 94 | 56 |
525 | 66 | 48 |
526 | 35 | 71 |
527 | 51 | 44 |
528 | 60 | 23 |
529 | 64 | 10 |
530 | 63 | 14 |
531 | 70 | 37 |
532 | 76 | 45 |
533 | 78 | 18 |
534 | 76 | 51 |
535 | 75 | 33 |
536 | 81 | 17 |
537 | 76 | 45 |
538 | 76 | 30 |
539 | 80 | 14 |
540 | 71 | 18 |
541 | 71 | 14 |
542 | 71 | 11 |
543 | 65 | 2 |
544 | 31 | 26 |
545 | 24 | 72 |
546 | 64 | 70 |
547 | 77 | 62 |
548 | 80 | 68 |
549 | 83 | 53 |
550 | 83 | 50 |
551 | 83 | 50 |
552 | 85 | 43 |
553 | 86 | 45 |
554 | 89 | 35 |
555 | 82 | 61 |
556 | 87 | 50 |
557 | 85 | 55 |
558 | 89 | 49 |
559 | 87 | 70 |
560 | 91 | 39 |
561 | 72 | 3 |
562 | 43 | 25 |
563 | 30 | 60 |
564 | 40 | 45 |
565 | 37 | 32 |
566 | 37 | 32 |
567 | 43 | 70 |
568 | 70 | 54 |
569 | 77 | 47 |
570 | 79 | 66 |
571 | 85 | 53 |
572 | 83 | 57 |
573 | 86 | 52 |
574 | 85 | 51 |
575 | 70 | 39 |
576 | 50 | 5 |
577 | 38 | 36 |
578 | 30 | 71 |
579 | 75 | 53 |
580 | 84 | 40 |
581 | 85 | 42 |
582 | 86 | 49 |
583 | 86 | 57 |
584 | 89 | 68 |
585 | 99 | 61 |
586 | 77 | 29 |
587 | 81 | 72 |
588 | 89 | 69 |
589 | 49 | 56 |
590 | 79 | 70 |
591 | 104 | 59 |
592 | 103 | 54 |
593 | 102 | 56 |
594 | 102 | 56 |
595 | 103 | 61 |
596 | 102 | 64 |
597 | 103 | 60 |
598 | 93 | 72 |
599 | 86 | 73 |
600 | 76 | 73 |
601 | 59 | 49 |
602 | 46 | 22 |
603 | 40 | 65 |
604 | 72 | 31 |
605 | 72 | 27 |
606 | 67 | 44 |
607 | 68 | 37 |
608 | 67 | 42 |
609 | 68 | 50 |
610 | 77 | 43 |
611 | 58 | 4 |
612 | 22 | 37 |
613 | 57 | 69 |
614 | 68 | 38 |
615 | 73 | 2 |
616 | 40 | 14 |
617 | 42 | 38 |
618 | 64 | 69 |
619 | 64 | 74 |
620 | 67 | 73 |
621 | 65 | 73 |
622 | 68 | 73 |
623 | 65 | 49 |
624 | 81 | 0 |
625 | 37 | 25 |
626 | 24 | 69 |
627 | 68 | 71 |
628 | 70 | 71 |
629 | 76 | 70 |
630 | 71 | 72 |
631 | 73 | 69 |
632 | 76 | 70 |
633 | 77 | 72 |
634 | 77 | 72 |
635 | 77 | 72 |
636 | 77 | 70 |
637 | 76 | 71 |
638 | 76 | 71 |
639 | 77 | 71 |
640 | 77 | 71 |
641 | 78 | 70 |
642 | 77 | 70 |
643 | 77 | 71 |
644 | 79 | 72 |
645 | 78 | 70 |
646 | 80 | 70 |
647 | 82 | 71 |
648 | 84 | 71 |
649 | 83 | 71 |
650 | 83 | 73 |
651 | 81 | 70 |
652 | 80 | 71 |
653 | 78 | 71 |
654 | 76 | 70 |
655 | 76 | 70 |
656 | 76 | 71 |
657 | 79 | 71 |
658 | 78 | 71 |
659 | 81 | 70 |
660 | 83 | 72 |
661 | 84 | 71 |
662 | 86 | 71 |
663 | 87 | 71 |
664 | 92 | 72 |
665 | 91 | 72 |
666 | 90 | 71 |
667 | 90 | 71 |
668 | 91 | 71 |
669 | 90 | 70 |
670 | 90 | 72 |
671 | 91 | 71 |
672 | 90 | 71 |
673 | 90 | 71 |
674 | 92 | 72 |
675 | 93 | 69 |
676 | 90 | 70 |
677 | 93 | 72 |
678 | 91 | 70 |
679 | 89 | 71 |
680 | 91 | 71 |
681 | 90 | 71 |
682 | 90 | 71 |
683 | 92 | 71 |
684 | 91 | 71 |
685 | 93 | 71 |
686 | 93 | 68 |
687 | 98 | 68 |
688 | 98 | 67 |
689 | 100 | 69 |
690 | 99 | 68 |
691 | 100 | 71 |
692 | 99 | 68 |
693 | 100 | 69 |
694 | 102 | 72 |
695 | 101 | 69 |
696 | 100 | 69 |
697 | 102 | 71 |
698 | 102 | 71 |
699 | 102 | 69 |
700 | 102 | 71 |
701 | 102 | 68 |
702 | 100 | 69 |
703 | 102 | 70 |
704 | 102 | 68 |
705 | 102 | 70 |
706 | 102 | 72 |
707 | 102 | 68 |
708 | 102 | 69 |
709 | 100 | 68 |
710 | 102 | 71 |
711 | 101 | 64 |
712 | 102 | 69 |
713 | 102 | 69 |
714 | 101 | 69 |
715 | 102 | 64 |
716 | 102 | 69 |
717 | 102 | 68 |
718 | 102 | 70 |
719 | 102 | 69 |
720 | 102 | 70 |
721 | 102 | 70 |
722 | 102 | 62 |
723 | 104 | 38 |
724 | 104 | 15 |
725 | 102 | 24 |
726 | 102 | 45 |
727 | 102 | 47 |
728 | 104 | 40 |
729 | 101 | 52 |
730 | 103 | 32 |
731 | 102 | 50 |
732 | 103 | 30 |
733 | 103 | 44 |
734 | 102 | 40 |
735 | 103 | 43 |
736 | 103 | 41 |
737 | 102 | 46 |
738 | 103 | 39 |
739 | 102 | 41 |
740 | 103 | 41 |
741 | 102 | 38 |
742 | 103 | 39 |
743 | 102 | 46 |
744 | 104 | 46 |
745 | 103 | 49 |
746 | 102 | 45 |
747 | 103 | 42 |
748 | 103 | 46 |
749 | 103 | 38 |
750 | 102 | 48 |
751 | 103 | 35 |
752 | 102 | 48 |
753 | 103 | 49 |
754 | 102 | 48 |
755 | 102 | 46 |
756 | 103 | 47 |
757 | 102 | 49 |
758 | 102 | 42 |
759 | 102 | 52 |
760 | 102 | 57 |
761 | 102 | 55 |
762 | 102 | 61 |
763 | 102 | 61 |
764 | 102 | 58 |
765 | 103 | 58 |
766 | 102 | 59 |
767 | 102 | 54 |
768 | 102 | 63 |
769 | 102 | 61 |
770 | 103 | 55 |
771 | 102 | 60 |
772 | 102 | 72 |
773 | 103 | 56 |
774 | 102 | 55 |
775 | 102 | 67 |
776 | 103 | 56 |
777 | 84 | 42 |
778 | 48 | 7 |
779 | 48 | 6 |
780 | 48 | 6 |
781 | 48 | 7 |
782 | 48 | 6 |
783 | 48 | 7 |
784 | 67 | 21 |
785 | 105 | 59 |
786 | 105 | 96 |
787 | 105 | 74 |
788 | 105 | 66 |
789 | 105 | 62 |
790 | 105 | 66 |
791 | 89 | 41 |
792 | 52 | 5 |
793 | 48 | 5 |
794 | 48 | 7 |
795 | 48 | 5 |
796 | 48 | 6 |
797 | 48 | 4 |
798 | 52 | 6 |
799 | 51 | 5 |
800 | 51 | 6 |
801 | 51 | 6 |
802 | 52 | 5 |
803 | 52 | 5 |
804 | 57 | 44 |
805 | 98 | 90 |
806 | 105 | 94 |
807 | 105 | 100 |
808 | 105 | 98 |
809 | 105 | 95 |
810 | 105 | 96 |
811 | 105 | 92 |
812 | 104 | 97 |
813 | 100 | 85 |
814 | 94 | 74 |
815 | 87 | 62 |
816 | 81 | 50 |
817 | 81 | 46 |
818 | 80 | 39 |
819 | 80 | 32 |
820 | 81 | 28 |
821 | 80 | 26 |
822 | 80 | 23 |
823 | 80 | 23 |
824 | 80 | 20 |
825 | 81 | 19 |
826 | 80 | 18 |
827 | 81 | 17 |
828 | 80 | 20 |
829 | 81 | 24 |
830 | 81 | 21 |
831 | 80 | 26 |
832 | 80 | 24 |
833 | 80 | 23 |
834 | 80 | 22 |
835 | 81 | 21 |
836 | 81 | 24 |
837 | 81 | 24 |
838 | 81 | 22 |
839 | 81 | 22 |
840 | 81 | 21 |
841 | 81 | 31 |
842 | 81 | 27 |
843 | 80 | 26 |
844 | 80 | 26 |
845 | 81 | 25 |
846 | 80 | 21 |
847 | 81 | 20 |
848 | 83 | 21 |
849 | 83 | 15 |
850 | 83 | 12 |
851 | 83 | 9 |
852 | 83 | 8 |
853 | 83 | 7 |
854 | 83 | 6 |
855 | 83 | 6 |
856 | 83 | 6 |
857 | 83 | 6 |
858 | 83 | 6 |
859 | 76 | 5 |
860 | 49 | 8 |
861 | 51 | 7 |
862 | 51 | 20 |
863 | 78 | 52 |
864 | 80 | 38 |
865 | 81 | 33 |
866 | 83 | 29 |
867 | 83 | 22 |
868 | 83 | 16 |
869 | 83 | 12 |
870 | 83 | 9 |
871 | 83 | 8 |
872 | 83 | 7 |
873 | 83 | 6 |
874 | 83 | 6 |
875 | 83 | 6 |
876 | 83 | 6 |
877 | 83 | 6 |
878 | 59 | 4 |
879 | 50 | 5 |
880 | 51 | 5 |
881 | 51 | 5 |
882 | 51 | 5 |
883 | 50 | 5 |
884 | 50 | 5 |
885 | 50 | 5 |
886 | 50 | 5 |
887 | 50 | 5 |
888 | 51 | 5 |
889 | 51 | 5 |
890 | 51 | 5 |
891 | 63 | 50 |
892 | 81 | 34 |
893 | 81 | 25 |
894 | 81 | 29 |
895 | 81 | 23 |
896 | 80 | 24 |
897 | 81 | 24 |
898 | 81 | 28 |
899 | 81 | 27 |
900 | 81 | 22 |
901 | 81 | 19 |
902 | 81 | 17 |
903 | 81 | 17 |
904 | 81 | 17 |
905 | 81 | 15 |
906 | 80 | 15 |
907 | 80 | 28 |
908 | 81 | 22 |
909 | 81 | 24 |
910 | 81 | 19 |
911 | 81 | 21 |
912 | 81 | 20 |
913 | 83 | 26 |
914 | 80 | 63 |
915 | 80 | 59 |
916 | 83 | 100 |
917 | 81 | 73 |
918 | 83 | 53 |
919 | 80 | 76 |
920 | 81 | 61 |
921 | 80 | 50 |
922 | 81 | 37 |
923 | 82 | 49 |
924 | 83 | 37 |
925 | 83 | 25 |
926 | 83 | 17 |
927 | 83 | 13 |
928 | 83 | 10 |
929 | 83 | 8 |
930 | 83 | 7 |
931 | 83 | 7 |
932 | 83 | 6 |
933 | 83 | 6 |
934 | 83 | 6 |
935 | 71 | 5 |
936 | 49 | 24 |
937 | 69 | 64 |
938 | 81 | 50 |
939 | 81 | 43 |
940 | 81 | 42 |
941 | 81 | 31 |
942 | 81 | 30 |
943 | 81 | 35 |
944 | 81 | 28 |
945 | 81 | 27 |
946 | 80 | 27 |
947 | 81 | 31 |
948 | 81 | 41 |
949 | 81 | 41 |
950 | 81 | 37 |
951 | 81 | 43 |
952 | 81 | 34 |
953 | 81 | 31 |
954 | 81 | 26 |
955 | 81 | 23 |
956 | 81 | 27 |
957 | 81 | 38 |
958 | 81 | 40 |
959 | 81 | 39 |
960 | 81 | 27 |
961 | 81 | 33 |
962 | 80 | 28 |
963 | 81 | 34 |
964 | 83 | 72 |
965 | 81 | 49 |
966 | 81 | 51 |
967 | 80 | 55 |
968 | 81 | 48 |
969 | 81 | 36 |
970 | 81 | 39 |
971 | 81 | 38 |
972 | 80 | 41 |
973 | 81 | 30 |
974 | 81 | 23 |
975 | 81 | 19 |
976 | 81 | 25 |
977 | 81 | 29 |
978 | 83 | 47 |
979 | 81 | 90 |
980 | 81 | 75 |
981 | 80 | 60 |
982 | 81 | 48 |
983 | 81 | 41 |
984 | 81 | 30 |
985 | 80 | 24 |
986 | 81 | 20 |
987 | 81 | 21 |
988 | 81 | 29 |
989 | 81 | 29 |
990 | 81 | 27 |
991 | 81 | 23 |
992 | 81 | 25 |
993 | 81 | 26 |
994 | 81 | 22 |
995 | 81 | 20 |
996 | 81 | 17 |
997 | 81 | 23 |
998 | 83 | 65 |
999 | 81 | 54 |
1 000 | 81 | 50 |
1 001 | 81 | 41 |
1 002 | 81 | 35 |
1 003 | 81 | 37 |
1 004 | 81 | 29 |
1 005 | 81 | 28 |
1 006 | 81 | 24 |
1 007 | 81 | 19 |
1 008 | 81 | 16 |
1 009 | 80 | 16 |
1 010 | 83 | 23 |
1 011 | 83 | 17 |
1 012 | 83 | 13 |
1 013 | 83 | 27 |
1 014 | 81 | 58 |
1 015 | 81 | 60 |
1 016 | 81 | 46 |
1 017 | 80 | 41 |
1 018 | 80 | 36 |
1 019 | 81 | 26 |
1 020 | 86 | 18 |
1 021 | 82 | 35 |
1 022 | 79 | 53 |
1 023 | 82 | 30 |
1 024 | 83 | 29 |
1 025 | 83 | 32 |
1 026 | 83 | 28 |
1 027 | 76 | 60 |
1 028 | 79 | 51 |
1 029 | 86 | 26 |
1 030 | 82 | 34 |
1 031 | 84 | 25 |
1 032 | 86 | 23 |
1 033 | 85 | 22 |
1 034 | 83 | 26 |
1 035 | 83 | 25 |
1 036 | 83 | 37 |
1 037 | 84 | 14 |
1 038 | 83 | 39 |
1 039 | 76 | 70 |
1 040 | 78 | 81 |
1 041 | 75 | 71 |
1 042 | 86 | 47 |
1 043 | 83 | 35 |
1 044 | 81 | 43 |
1 045 | 81 | 41 |
1 046 | 79 | 46 |
1 047 | 80 | 44 |
1 048 | 84 | 20 |
1 049 | 79 | 31 |
1 050 | 87 | 29 |
1 051 | 82 | 49 |
1 052 | 84 | 21 |
1 053 | 82 | 56 |
1 054 | 81 | 30 |
1 055 | 85 | 21 |
1 056 | 86 | 16 |
1 057 | 79 | 52 |
1 058 | 78 | 60 |
1 059 | 74 | 55 |
1 060 | 78 | 84 |
1 061 | 80 | 54 |
1 062 | 80 | 35 |
1 063 | 82 | 24 |
1 064 | 83 | 43 |
1 065 | 79 | 49 |
1 066 | 83 | 50 |
1 067 | 86 | 12 |
1 068 | 64 | 14 |
1 069 | 24 | 14 |
1 070 | 49 | 21 |
1 071 | 77 | 48 |
1 072 | 103 | 11 |
1 073 | 98 | 48 |
1 074 | 101 | 34 |
1 075 | 99 | 39 |
1 076 | 103 | 11 |
1 077 | 103 | 19 |
1 078 | 103 | 7 |
1 079 | 103 | 13 |
1 080 | 103 | 10 |
1 081 | 102 | 13 |
1 082 | 101 | 29 |
1 083 | 102 | 25 |
1 084 | 102 | 20 |
1 085 | 96 | 60 |
1 086 | 99 | 38 |
1 087 | 102 | 24 |
1 088 | 100 | 31 |
1 089 | 100 | 28 |
1 090 | 98 | 3 |
1 091 | 102 | 26 |
1 092 | 95 | 64 |
1 093 | 102 | 23 |
1 094 | 102 | 25 |
1 095 | 98 | 42 |
1 096 | 93 | 68 |
1 097 | 101 | 25 |
1 098 | 95 | 64 |
1 099 | 101 | 35 |
1 100 | 94 | 59 |
1 101 | 97 | 37 |
1 102 | 97 | 60 |
1 103 | 93 | 98 |
1 104 | 98 | 53 |
1 105 | 103 | 13 |
1 106 | 103 | 11 |
1 107 | 103 | 11 |
1 108 | 103 | 13 |
1 109 | 103 | 10 |
1 110 | 103 | 10 |
1 111 | 103 | 11 |
1 112 | 103 | 10 |
1 113 | 103 | 10 |
1 114 | 102 | 18 |
1 115 | 102 | 31 |
1 116 | 101 | 24 |
1 117 | 102 | 19 |
1 118 | 103 | 10 |
1 119 | 102 | 12 |
1 120 | 99 | 56 |
1 121 | 96 | 59 |
1 122 | 74 | 28 |
1 123 | 66 | 62 |
1 124 | 74 | 29 |
1 125 | 64 | 74 |
1 126 | 69 | 40 |
1 127 | 76 | 2 |
1 128 | 72 | 29 |
1 129 | 66 | 65 |
1 130 | 54 | 69 |
1 131 | 69 | 56 |
1 132 | 69 | 40 |
1 133 | 73 | 54 |
1 134 | 63 | 92 |
1 135 | 61 | 67 |
1 136 | 72 | 42 |
1 137 | 78 | 2 |
1 138 | 76 | 34 |
1 139 | 67 | 80 |
1 140 | 70 | 67 |
1 141 | 53 | 70 |
1 142 | 72 | 65 |
1 143 | 60 | 57 |
1 144 | 74 | 29 |
1 145 | 69 | 31 |
1 146 | 76 | 1 |
1 147 | 74 | 22 |
1 148 | 72 | 52 |
1 149 | 62 | 96 |
1 150 | 54 | 72 |
1 151 | 72 | 28 |
1 152 | 72 | 35 |
1 153 | 64 | 68 |
1 154 | 74 | 27 |
1 155 | 76 | 14 |
1 156 | 69 | 38 |
1 157 | 66 | 59 |
1 158 | 64 | 99 |
1 159 | 51 | 86 |
1 160 | 70 | 53 |
1 161 | 72 | 36 |
1 162 | 71 | 47 |
1 163 | 70 | 42 |
1 164 | 67 | 34 |
1 165 | 74 | 2 |
1 166 | 75 | 21 |
1 167 | 74 | 15 |
1 168 | 75 | 13 |
1 169 | 76 | 10 |
1 170 | 75 | 13 |
1 171 | 75 | 10 |
1 172 | 75 | 7 |
1 173 | 75 | 13 |
1 174 | 76 | 8 |
1 175 | 76 | 7 |
1 176 | 67 | 45 |
1 177 | 75 | 13 |
1 178 | 75 | 12 |
1 179 | 73 | 21 |
1 180 | 68 | 46 |
1 181 | 74 | 8 |
1 182 | 76 | 11 |
1 183 | 76 | 14 |
1 184 | 74 | 11 |
1 185 | 74 | 18 |
1 186 | 73 | 22 |
1 187 | 74 | 20 |
1 188 | 74 | 19 |
1 189 | 70 | 22 |
1 190 | 71 | 23 |
1 191 | 73 | 19 |
1 192 | 73 | 19 |
1 193 | 72 | 20 |
1 194 | 64 | 60 |
1 195 | 70 | 39 |
1 196 | 66 | 56 |
1 197 | 68 | 64 |
1 198 | 30 | 68 |
1 199 | 70 | 38 |
1 200 | 66 | 47 |
1 201 | 76 | 14 |
1 202 | 74 | 18 |
1 203 | 69 | 46 |
1 204 | 68 | 62 |
1 205 | 68 | 62 |
1 206 | 68 | 62 |
1 207 | 68 | 62 |
1 208 | 68 | 62 |
1 209 | 68 | 62 |
1 210 | 54 | 50 |
1 211 | 41 | 37 |
1 212 | 27 | 25 |
1 213 | 14 | 12 |
1 214 | 0 | 0 |
1 215 | 0 | 0 |
1 216 | 0 | 0 |
1 217 | 0 | 0 |
1 218 | 0 | 0 |
1 219 | 0 | 0 |
1 220 | 0 | 0 |
1 221 | 0 | 0 |
1 222 | 0 | 0 |
1 223 | 0 | 0 |
1 224 | 0 | 0 |
1 225 | 0 | 0 |
1 226 | 0 | 0 |
1 227 | 0 | 0 |
1 228 | 0 | 0 |
1 229 | 0 | 0 |
1 230 | 0 | 0 |
1 231 | 0 | 0 |
1 232 | 0 | 0 |
1 233 | 0 | 0 |
1 234 | 0 | 0 |
1 235 | 0 | 0 |
1 236 | 0 | 0 |
1 237 | 0 | 0 |
1 238 | 0 | 0 |
A graphical display of the NRTC dynamometer schedule is shown below
Appendix 5
DURABILITY REQUIREMENTS
1. EMISSION DURABILITY PERIOD AND DETERIORATION FACTORS. U.K.
This appendix shall apply to CI engines Stage IIIA and IIIB and IV only.
1.1. Manufacturers shall determine a Deterioration Factor (DF) value for each regulated pollutant for all Stage IIIA and IIIB engine families. Such DFs shall be used for type approval and production line testing. U.K.
1.1.1. Test to establish DFs shall be conducted as follows: U.K.
1.1.1.1. The manufacturer shall conduct durability tests to accumulate engine operating hours according to a test schedule that is selected on the basis of good engineering judgement to be representative of in-use engine operation in respect to characterising emission performance deterioration. The durability test period should typically represent the equivalent of at least one quarter of the emission durability period (EDP). U.K.
Service accumulation operating hours may be acquired through running engines on a dynamometer test bed or from actual in-field machine operation. Accelerated durability tests can be applied whereby the service accumulation test schedule is performed at a higher load factor than typically experienced in the field. The acceleration factor relating the number of engine durability test hours to the equivalent number of EDP hours shall be determined by the engine manufacturer based on good engineering judgement.
During the period of the durability test, no emission sensitive components can be serviced or replaced other than to the routine service schedule recommended by the manufacturer.
The test engine, subsystems, or components to be used to determine exhaust emission DFs for an engine family, or for engine families of equivalent emission control system technology, shall be selected by the engine manufacturer on the basis of good engineering judgement. The criterion is that the test engine should represent the emission deterioration characteristic of the engine families that will apply the resulting DF values for certification approval. Engines of different bore and stroke, different configuration, different air management systems, different fuel systems can be considered as equivalent in respect to emissions deterioration characteristics if there is a reasonable technical basis for such determination.
DF values from another manufacturer can be applied if there is a reasonable basis for considering technology equivalence with respect to emissions deterioration, and evidence that the tests have been carried according to the specified requirements.
Emissions testing will be performed according to the procedures defined in this Directive for the test engine after initial run-in but before any service accumulation, and at the completion of the durability. Emission tests can also be performed at intervals during the service accumulation test period, and applied in determining the deterioration trend.
1.1.1.2. The service accumulation tests or the emissions tests performed to determine deterioration must not be witnessed by the approval authority. U.K.
1.1.1.3. Determination of DF values from durability tests U.K.
An additive DF is defined as the value obtained by subtraction of the emission value determine at the beginning of the EDP, from the emissions value determined to represent the emission performance at the end of the EDP.
A multiplicative DF is defined as the emission level determined for the end of the EDP divided by the emission value recorded at the beginning of the EDP.
Separate DF values shall be established for each of the pollutants covered by the legislation. In the case of establishing a DF value relative to the NO x +HC standard, for an additive DF, this is determined based on the sum of the pollutants notwithstanding that a negative deterioration for one pollutant may not offset deterioration for the other. For a multiplicative NO x +HC DF, separate HC and NO x DFs shall be determined and applied separately when calculating the deteriorated emission levels from an emissions test result before combining the resultant deteriorated NO x and HC values to establish compliance with the standard.
In cases where the testing is not conducted for the full EDP, the emission values at the end of the EDP is determined by extrapolation of the emission deterioration trend established for the test period, to the full EDP.
When emissions test results have been recorded periodically during the service accumulation durability testing, standard statistical processing techniques based on good practice shall be applied to determine the emission levels at the end of the EDP; statistical significance testing can be applied in the determination of the final emissions values.
If the calculation results in a value of less than 1,00 for a multiplicative DF, or less than 0,00 for an additive DF, then the DF shall be 1,0 or 0,00, respectively.
1.1.1.4. A manufacturer may, with the approval of the type approval authority, use DF values established from results of durability tests conducted to obtain DF values for certification of on-road HD CI engines. This will be allowed if there is technological equivalency between the test on-road engine and the non-road engine families applying the DF values for certification. The DF values derived from on-road engine emission durability test results, must be calculated on the basis of EDP values defined in section 2. U.K.
1.1.1.5. In the case where an engine family uses established technology, an analysis based on good engineering practices may be used in lieu of testing to determine a deterioration factor for that engine family subject to approval of the type approval authority. U.K.
1.2. DF information in approval applications U.K.
1.2.1. Additive DFs shall be specified for each pollutant in an engine family certification application for CI engines not using any after-treatment device. U.K.
1.2.2. Multiplicative DFs shall be specified for each pollutant in an engine family certification application for CI engines using an after-treatment device. U.K.
1.2.3. The manufacture shall furnish the type-approval agency on request with information to support the DF values. This would typically include emission test results, service accumulation test schedule, maintenance procedures together with information to support engineering judgements of technological equivalency, if applicable. U.K.
2. EMISSION DURABILITY PERIODS FOR STAGE IIIA, IIIB AND IV ENGINES. U.K.
2.1. Manufacturers shall use the EDP in Table 1 of this section. U.K.
Table 1: EDP categories for CI Stage IIIA, IIIB and IV Engines (hours) U.K.
Category (power band) | Useful life (hours) (PDE) |
---|
≤ 37 kW
(constant speed engines)
| 3 000 |
≤ 37 kW
(not constant speed engines)
| 5 000 |
> 37 kW | 8 000 |
Engines for the use in inland waterway vessels | 10 000 |
Railcar engines | 10 000] |