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[F1ANNEX I U.K. LIST OF POLLUTANTS, STATISTICAL PARAMETERS AND UNITS OF MEASUREMENT

1. Pollutants listed in Annex I to Directive 96/62/EC on air quality U.K.

. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

2. Pollutants not listed in Annex I to Directive 96/62/EC on air quality U.K.

Pollutants to be reported under Directives other than Directive 96/62/EC are listed in Section 3 under Nos 14 and 15. Pollutants only to be reported if available are listed under Nos 16 to 63.

3. Pollutants, units of measurement, averaging times: U.K.

a

ISO 7168-2: 1999.

b

Use at least two figures for each value reported, e.g. 1,4 mg/m 3 or 21 μg/m 3 .

c

Some measurement techniques involve sampling times from a few minutes up to several weeks. In such a case values with different averaging times differing from those listed in this column can be reported indicating the actual averaging period.

d

Directives in force when the revised Annexes to the exchange of information Decision enter into force.

e

Amending Directive 80/779/EEC.

f

No reference method available for PM 2,5 (particulate matter) when the revised Annexes to the exchange of information Decision enter into force.

g

For heavy metals and PAH, community legislation is currently under preparation that is expected to result, in particular, in a list of specific PAH substances and proposals for amendments to this Decision as necessary.

h

If available.

i

Not available.

No ISO-code  a Formula Name of pollutant Units of measurement  b Average over  c Expressed as Relevant Directives  d
Pollutants listed in Annex I of the Directive 96/62/EC on air quality
1 01 SO 2 sulphur dioxide μg/m 3 1 h

1999/30/EC

80/779/EEC

89/427/EEC  e

2 03 NO 2 nitrogen dioxide μg/m 3 1 h

1999/30/EC

85/203/EEC

3 24 PM 10 suspended particulates (<10 μm) μg/m 3 24 h

1999/30/EC

96/62/EC

4 39 PM 2,5   f suspended particulates (<2,5 μm) μg/m 3 24 h

1999/30/EC

96/62/EC

5 22 SPM suspended particulates (total) μg/m 3 24 h

80/779/EEC

89/427/EEC

6 19 Pb lead μg/m 3 24 h

1999/30/EC

82/884/EC

7 08 O 3 ozone μg/m 3 1 h 92/72/EEC
8 V4 C 6 H 6 benzene μg/m 3 24 h

96/62/EC

2000/69/EC

9 04 CO carbon monoxide [X1mg/m 3] 1 h

96/62/EC

2000/69/EC

10 82 Cd  g cadmium ng/m 3 24 h 96/62/EC
11 80 As arsenic ng/m 3 24 h 96/62/EC
12 87 Ni nickel ng/m 3 24 h 96/62/EC
13 85 Hg mercury ng/m 3 24 h 96/62/EC
Pollutants to be reported under other EU Directives
14 11 BS black smoke μg/m 3 24 h

80/779/EEC

89/427/EEC

15 35 NO x nitrogen oxides μg/m 3 1 h NO 2 equivalent 1999/30/EC
Other pollutants  h
16 V8 C2H 6 ethane μg/m 3 24 h
17 V9 H 2 C=CH 2 ethene (ethylene) μg/m 3 24 h
18 V3 HC=CH ethine (acetylene) μg/m 3 24 h
19 VN H 3 C-CH 2 -CH 3 propane μg/m 3 24 h
20 VP CH 2 =CH-CH 3 propene μg/m 3 24 h
21 V6 H 3 C-CH 2 -CH 2 -CH 3 n-butane μg/m 3 24 h
22 V5 H 3 C-CH(CH 3 ) 2 iso-butane μg/m 3 24 h
23 V1 H 2 C=CH-CH 2 -CH 3 l-butene μg/m 3 24 h
24 V2 H 3 C-CH=CH-CH 3 trans-2-butene μg/m 3 24 h
25 V7 H 3 C-CH=CH-CH 3 cis-2-butene μg/m 3 24 h
26 V0 CH 2 =CH-CH=CH 2 butadiene 1,3 μg/m 3 24 h
27 VK H 3 C-(CH 2 ) 3 -CH 3 n-pentane μg/m 3 24 h
28 V1 H 3 C-CH 2 -CH(CH 3 ) 2 iso-pentane μg/m 3 24 h
29 VL H 2 C=CH-CH 2 -CH 2 -CH 3 1-pentene μg/m 3 24 h
30 VM H 3 C-HC=CH-CH 2 -CH 3 2-pentene μg/m 3 24 h
31 VF H 2 C=CH-C(CH 3 )=CH 2 isoprene μg/m 3 24 h
32 VD C 36 H 14 n-hexane μg/m 3 24 h
33 n.a.  i (CH 3 ) 2 -CH-CH 2 -CH 2 -CH 3 i-hexane μg/m 3 24 h
34 VC C 7 H 16 n-heptane μg/m 3 24 h
35 VH C 8 H 18 n-octane μg/m 3 24 h
36 VG (CH 3 ) 3 -C-CH 2 -CH-(CH 3 ) 2 iso-octane μg/m 3 24 h
37 VQ C 6 H 5 -CH 3 toluene μg/m 3 24 h
38 VA C 6 H 5 -C 2 H 5 ethyl benzene μg/m 3 24 h
39 VU m,p-C 6 H 4 (CH 3 ) 2 m,p-xylene μg/m 3 24 h
40 VV o-C 6 H 4 -(CH 3 ) 2 o-xylene μg/m 3 24 h
41 VS C 6 H 3 -(CH 3 ) 3 1,2,4-trimethylbenzene μg/m 3 24 h
42 VR C 6 H 3 (CH 3 ) 3 1,2,3-trimethylbenzene μg/m 3 24 h
43 VT C 6 H 3 (CH 3 ) 3 1,3,5-trimethylbenzene μg/m 3 24 h
44 VB HCHO formaldehyde μg/m 3 1 h
45 20 THC (NM) total non-methane hydrocarbons μg/m 3 24 h C equivalent
46 10 SA strong acidity μg/m 3 24 h SO 2 equivalent

82/459/EEC

(alternative to SO 2 )

47 n.a. PM 1 suspended particulates (<1 μm) μg/m 3 24 h 96/62/EC
48 16 CH 4 methane μg/m 3 24 h
49 83 Cr chromium ng/m 3 24 h
50 90 MN manganese ng/m 3 24 h
51 05 H 2 S hydrogen sulphide μg/m 3 24 h
52 n.a. CS 2 carbon disulphide μg/m 3 1 h
53 n.a. C 6 H 5 -CH=CH 2 styrene μg/m 3 24 h
54 n.a. CH 2 =CH-CN acrylonitrile μg/m 3 24 h
55 H3 C1CHCC1 2 trichloroethylene μg/m 3 24 h
56 H4 C 2 C1 4 tetrachloroethylene μg/m 3 24 h
57 n.a. CH 2 C1 2 dichloromethane μg/m 3 24 h
58 P6 BaP benzo(a)pyrene ng/m 3 24 h
59 n.a. VC vinyl chloride μg/m 3 24 h
60 09 PAN peroxyacetyl nitrate μg/m 3 1 h
61 21 NH 3 ammonia μg/m 3 24 h
62 n.a. N-dep. wet nitrogen deposition mg/(m 2 * month) 1 month N equivalent
63 n.a. S-dep. wet sulphur deposition mg/(m 2 * month) 1 month S equivalent

4. Data, calculated over the calendar year, to be transmitted to the Commission U.K.

Member States shall send raw data or shall send raw data and statistics.

For those Member States who transfer raw data and statistics the following statistics are required.

The y th percentile should be selected from the values actually measured. All the values should be listed in increasing order:

The y th percentile is the concentration X k , where the value of k is calculated as follows: with q being equal to y/100 and N the number of values actually measured.

The value of (q × N) should be rounded off to the nearest whole number.

All the results should be expressed at the following conditions of temperature and pressure: 293 K and 101,3 kPa, except for pollutants 62 and 63. For particle bound components, data from the year 2001 and onwards should be reported at ambient conditions.

5. Data transmission to the Commission: U.K.

Data shall be transmitted by one of the following data formats: ISO 7168 version 2 extended format, NASA-AMES 1001/1010 or DEM (1) compatible format; or in DEM database:

The Commission will confirm receipt of data and the number of stations and pollutants.

ANNEX II U.K. INFORMATION CONCERNING NETWORKS, STATIONS AND MEASUREMENT TECHNIQUES

Member States shall report on the following points: I.1, I.4.1 to I.4.4, I.5, II.1.1, II.1.4, II.1.8, II.1.10, II.1.11 and II.2.1. To the extent possible, as much information as feasible should be supplied on the other points:

ANNEX III U.K. DATA VALIDATION PROCEDURE AND QUALITY ASSURANCE

All transmitted data are deemed to be valid.

It is the responsibility of the Member States to ensure that a quality assurance procedure is in place, which meets in general the objectives of this Decision and in paricular the objectives of the relevant Directives.

ANNEX IV U.K. CRITERIA FOR THE AGGREGATION OF DATA AND THE CALCULATION OF STATISTICAL PARAMETERS

These criteria mainly concern the data capture U.K.

If criteria for the aggregation of data and the calculation of statistical parameters have not been laid down in EU directives the following applies:

(a)

Aggregation of data

The criteria for the calculaltion of one-hour and 24-hour values from data with a smaller averaging time are

— for one-hour values: Minimum data capture 75 %,
— for 24-hour values: At least 13 one-hour values available, not more than six successive one-hour values missing.
(b)

Calculation of statistical parameters

— for the mean and the median: minimum data capture 50 %,
— for the percentiles 98, 99,9 and the maximum: minimum data capture 75 %.

The ratio between the number of valid data for the two seasons of the year considered cannot be greater than 2, the two seasons being winter (from January to March inclusive and from October to December inclusive) and summer (from April to September inclusive).]

(1)

[F1Data exchange module provided on behalf of the European Commission.

(2)

If the station is measuring ozone additional information on the status of rural background is to be provided (II.2.3.5).

(3)

Located such that their pollution level is not mainly influenced by any single source or street but rather by the integrated contribution from all sources upwind of the station (e.g. by all traffic, combustion sources, etc. upwind of a station in a city or by all upwind source areas (cities, industrial areas) in a rural area).]