The Fertilisers (Sampling and Analysis) Regulations 1996

Buffer solution, pH 4.00 at 20° C

3.2  Dissolve 10.21+0.01 grams of potassium hydrogen phthalate (KHC8O4H4) in water, transfer without loss into a 1 litre standard flask, make up to the mark and mix.

Keep this solution in an airtight vessel.