The Chemicals (Hazard Information and Packaging for Supply) (Amendment) Regulations 1996

Regulation 3(9)

SCHEDULE 1 MODIFICATIONS TO PART II OF SCHEDULE 3 TO THE PRINCIPAL REGULATIONS

1.  Part II of Schedule 3 to the principal Regulations shall be modified in accordance with the following paragraphs of this Schedule.

2.  In Table III, in the first entry in the column headed “Classification of the substance” , for the symbol “T+” substitute the symbol “T” .

3.  In Table IIIA, in the first entry in the column headed “Classification of the substance (gas)” , for the symbol “T+” substitute the symbol “T” .

4.  Table IVA shall be modified as follows—

(a) under the column headed “Xi with R41” delete the last entry, that is, the words “concentration >5% R41 obligatory” ;

(b) in the notes below the table, in paragraph (a)—

(i) for each occurrence of the figure “10%” substitute the figure “5%” , and

(ii) for the figure “5%” substitute the figure “0.2%” ; and

(c) in the notes below the table, in paragraph (b)—

(i) for the figure “20%” substitute the figure “5%” ,

(ii) for each occurrence of the figure “5%” substitute the figure “0.5%” , and

(iii) for the figure “1%” substitute the figure “0.02%” .

Regulation 3(10)

SCHEDULE 2 MODIFICATIONS TO SCHEDULE 6 OF THE PRINCIPAL REGULATIONS After Part II of Schedule 6 to the principal Regulations insert the following Part—

PART III SUBSTANCES REQUIRING ADDITIONAL LABELLING PHRASE

A Category 1 and 2 Carcinogenic, Mutagenic and Toxic for Reproduction substances requiring additional labelling phrase

The substances referred to in regulation 9(3A) are specified in the table below—

Substance	CAS Number
Carcinogenic substances of Category 1
2-naphthylamine; β-naphthylamine	91-59-8
biphenyl-4-ylamine; xenylamine; 4-aminobiphenyl	92-67-1
benzidine; 4,4'-diaminobiphenyl; biphenyl-4,4'-ylenediamine	92-87-5
chromium trioxide	1333-82-0
arsenic acid and its salts	—
arsenic pentoxide; arsenic oxide	1303-28-2
diarsenic trioxide; arsenic trioxide	1327-52-3
asbestos	132207-33-1
	132207-32-0
	12172-73-5
	77536-66-4
	77536-68-6
	77536-67-5
benzene	71-43-2
bis (chloromethyl) ether	542-88-1
chloromethyl methyl ether, chlorodimethyl ether	107-30-2
dinickel trioxide	1314-06-3
erionite	12510-42-8
nickel dioxide	12035-36-8
nickel monoxide	1313-99-1
nickel subsulphide	12035-72-2
nickel sulphide	16812-54-7
salts of 2-naphthylamine	—
salts of biphenyl-4-ylamine; salts of xenylamine; salts of 4-aminobiphenyl	—
salts of benzidine	—
vinyl chloride; chloroethylene	75-01-4
zinc chromates including zinc potassium chromate	—
Carcinogenic substances of Category 2
1-methyl-3-nitro-1-nitrosoguanidine	70-25-7
1,2-dibromo-3-chloropropane	96-12-8
1,2-dimethylhydrazin	540-73-8
1,3-butadiene, buta-1,3-diene	106-99-0
1,3-dichloro-2-propanol	96-23-1
1,3-propanesultone	1120-71-4
3-propanolide; 1,3-propiolactone	57-57-8
1,4-dichlorobut-2-ene	764-41-0
2-nitronaphthalene	581-89-5
2-nitropropane	79-46-9
2,2'-dichloro-4,4'-methylenedianiline; 4,4'-methylene bis(2-chloroaniline)	101-14-4
2-2'-(nitrosoimino)bisethanol	1116-54-7
3,3'-dichlorobenzidine; 3,3'-dichlorobiphenyl-4,4'-ylenediamine	91-94-1
3,3'-dimethoxybenzidine; o-dianisidine	119-90-4
3,3'-dimethylbenzidine; o-toluidine	119-93-7
4-aminoazobenzene	60-09-3
4-amino-3-fluorophenol	399-95-1
4-methyl-m-phenylenediamine	95-80-7
4-nitrobiphenyl	92-93-3
4,4'-methylenedi-o-toluidine	838-88-0
4,4'-diaminodiphenylmethane; 4,4'-methylenedianiline	101-77-9
5-nitroacenaphthene	602-87-9
4-o-tolylazo-o-toluidine; 4-amino-2',3-dimethylazobenzene; fast garnet GBC base, AAT; o-aminoazotoluene	97-56-3
disodium-{5[4'-((2,6-hydroxy-3-((2-hydroxy-5-sulphophenyl)a zo)phenyl) azo)(1,1'-biphenyl)-4-yl)azo]salicylato(4-)}cuprate(2-); C1 Direct Brown 95	16071-86-6
cadmium oxide	1306-19-0
Extracts (petroleum), heavy naphthenic distillate solvent	64742-11-6
Extracts (petroleum), heavy paraffinic distillate solvent	64742-04-7
Extracts (petroleum), light naphthenic distillate solvent	64742-03-6
Extracts (petroleum), light paraffinic distillate solvent	64742-05-8
Extracts (petroleum), light vacuum gas oil solvent	91995-78-7
Hydrocarbons, C26-55, arom. rich	97722-04-8
N,N-dimethylhydrazine	57-14-7
acrylamide	79-06-1
acrylonitrile	107-13-1
α,α,α-trichlorotoluene; benzotrichloride	98-07-7
benzo[a]anthracene	56-55-3
benzo[a]pyrene; benzo[d,e,f]chrysene	50-32-8
benzo[b]fluoranthene; benzo[e]acephenanthrylene	205-99-2
benzo[j]fluoranthene	205-82-3
benzo[k]fluoranthene	207-08-9
beryllium	7440-41-7
beryllium compounds with the exception of aluminium beryllium silicates	—
cadmium chloride	10108-64-2
cadmium sulphate	10124-36-4
calcium chromate	13765-19-0
captafol (ISO); 1,2,3,6-tetrahydro-N-(1,1,2,2-tetrachloroethylthio)phthalimide	2425-06-1
carbadox (INN); methyl-3-(quinoxalin-2-ylmethylene)carbazate 1,4-dioxide; 2-(methoxycarbonylhydrazonomethyl)quinoxaline 1,4-dioxide	6804-07-5
chromium III chromate; chromic chromate	24613-89-6
diazomethane	334-88-3
dibenz[a,h]anthracene	53-70-3
diethyl sulphate	64-67-5
dimethyl sulphate	77-78-1
dimethyl carbamoyl chloride	79-44-7
N-nitrosodimethylamine; dimethylnitrosamine	62-75-9
dimethylsulfamochloride	13360-57-1
1-chloro-2,3-epoxypropane; epichlorohydrin	106-89-8
1,2-dichloroethane; ethylene dichloride	107-06-2
ethylene oxide; oxirane	75-21-8
ethyleneimine; aziridine	151-56-4
hexachlorobenzene	118-74-1
hexamethylphosphoric triamide; hexamethylphosphoramide	680-31-9
hydrazine	302-01-2
hydrazobenzene; 1,2-diphenylhydrazine	122-66-7
methyl acrylamidomethoxyacetate (containing >0.1% acrylamide)	77402-03-0
methyl-ONN-azoxymethyl acetate; methyl azoxy methyl acetate	592-62-1
nitrofen (ISO); 2,4-dichlorophenyl 4-nitrophenyl ether	1836-75-5
nitrosodipropylamine	621-64-7
2-methoxyaniline; o-anisidine	90-04-0
potassium bromate	7758-01-2
propylene oxide; 1,2-epoxypropane; methyloxirane	75-56-9
o-toluidine	95-53-4
2-methylaziridine; propyleneimine	75-55-8
salts of 2,2'-dichloro-4,4'-methylenedianiline; salts of 4,4'-methylenebis (2-chloroaniline)	—
salts of 3,3'-dichlorobenzidine; salts of 3,3'-dichlorobiphenyl-4,4'-ylenediamine	—
salts of 3,3'-dimethoxybenzidine; salts of o-dianisidine	—
salts of 3,3'-dimethylbenzidine; salts of o-toluidine	—
strontium chromate	7789-06-2
styrene oxide; (epoxyethyl)benzene; phenyloxirane	96-09-3
sulfallate (ISO); 2-chlorallyl diethyldithiocarbamate	95-06-7
thioacetamide	62-55-5
urethane (INN); ethyl carbamate	51-79-6
Mutagenic substances of Category 1
There are no substances classified in this category,
Mutagenic substances of Category 2
1,2-dibromo-3-chloropropane	96-12-8
acrylamide	79-06-1
benzo[a]pyrene; benzo[d,e,f]chrysene	50-32-8
diethyl sulphate	64-67-5
ethylene oxide; oxirane	75-21-8
ethyleneimine, aziridine	151-56-4
hexamethylphosphoric triamide; hexamethylphosphoramide	680-31-9
methyl acrylamidomethoxyacetate (containing >0.1% acrylamide)	77402-03-0
Toxic for reproduction substances of Category 1,
lead hexafluorosilicate	25808-74-6
lead acetate	1335-32-6
lead alkyls	—
lead azide	13424-46-9
lead chromate	7758-97-6
lead compounds, with the exception of those specified elsewhere in this Part of this Schedule	—
lead di(acetate)	301-04-2
lead 2,4,6-trinitroresorcinoxide; lead styphnate	15245-44-0
lead (II) methanesulfonate	17570-76-2
trilead bis(orthophosphate)	7446-27-7
warfarin; 4-hydroxy-3-(3-oxo-1-phenylbutyl)coumarin	81-81-2
Toxic for reproduction substances of Category 2
2-ethoxyethanol; ethylene glycol monoethyl ether	110-80-5
2-ethylhexyl 3,5-bis(1,1-dimethylethyl)-4-hydroxyphenyl methyl thio acetate	80387-97-9
2-methoxyethanol, ethylene glycol monoethyl ether	109-86-4
benzo[a]pyrene; benzo[d,e,f]chrysene	50-32-8
binapacryl (ISO); 2-sec butyl-4,6-dinitrophenyl-3-methylcrotonate	485-31-4
N,N-dimethylformamide; dimethyl formamide	68-12-2
dinoseb; 6-sec butyl-2,4-dinitrophenol	88-85-7
dinoterb; 2-tert-butyl-4,6-dinitrophenol	1420-07-1
ethylene thiourea; imidazolidine-2-thione; 2-imidazoline-2-thiol	96-45-7
2-ethoxyethyl acetate; ethylglycol acetate	111-15-9
methyl-ONN-azoxymethyl acetate; methyl azoxy methyl acetate	592-62-1
2-methoxyethyl acetate; methylglycol acetate	110-49-6
nickel tetracarbonyl	13463-39-3
nitrofen (ISO); 2,4-dichlorophenyl 4-nitrophenyl ether	1836-75-5
salts and esters of dinoseb, with the exception of those specified elsewhere in this Part of this Schedule	—
salts and esters of dinoterb	—

B Chlorinated solvents requiring additional labelling phrase

The substances referred to in regulation 9(3B) are specified in the table below—

Substance	CAS Number
Note The CAS Number is the number assigned to the substance by the Chemicals Abstract Service.
chloroform	67-66-3
carbon tetrachloride	56-23-5
1,1,2-trichloroethane	79-00-5
1,1,2,2-tetrachloroethane	79-34-5
1,1,1,2-tetrachloroethane	630-20-6
pentachloroethane	76-01-7
1,1-dichloroethylene	75-35-4
1,1,1-trichlororethane	71-55-6