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Directive 2012/18/EU of the European Parliament and of the CouncilShow full title

Directive 2012/18/EU of the European Parliament and of the Council of 4 July 2012 on the control of major-accident hazards involving dangerous substances, amending and subsequently repealing Council Directive 96/82/EC (Text with EEA relevance)

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PART 2 Named dangerous substances

a

The CAS number is shown only for indication.

b

Provided that the mixture in the absence of sodium hypochlorite would not be classified as Aquatic Acute Category 1 [H400].

Column 1CAS numberaColumn 2Column 3
Qualifying quantity (tonnes) for the application of
Dangerous substances
Lower-tier requirementsUpper-tier requirements

1.Ammonium nitrate (see note 13)

5 00010 000

2.Ammonium nitrate (see note 14)

1 2505 000

3.Ammonium nitrate (see note 15)

3502 500

4.Ammonium nitrate (see note 16)

1050

5.Potassium nitrate (see note 17)

5 00010 000

6.Potassium nitrate (see note 18)

1 2505 000

7.Arsenic pentoxide, arsenic (V) acid and/or salts

1303-28-212

8.Arsenic trioxide, arsenious (III) acid and/or salts

1327-53-30,1

9.Bromine

7726-95-620100

10.Chlorine

7782-50-51025

11.Nickel compounds in inhalable powder form: nickel monoxide, nickel dioxide, nickel sulphide, trinickel disulphide, dinickel trioxide

1

12.Ethyleneimine

151-56-41020

13.Fluorine

7782-41-41020

14.Formaldehyde (concentration ≥ 90 %)

50-00-0550

15.Hydrogen

1333-74-0550

16.Hydrogen chloride (liquefied gas)

7647-01-025250

17.Lead alkyls

550

18.Liquefied flammable gases, Category 1 or 2 (including LPG) and natural gas (see note 19)

50200

19.Acetylene

74-86-2550

20.Ethylene oxide

75-21-8550

21.Propylene oxide

75-56-9550

22.Methanol

67-56-15005 000

23.4, 4′-Methylene bis (2-chloraniline) and/or salts, in powder form

101-14-40,01

24.Methylisocyanate

624-83-90,15

25.Oxygen

7782-44-72002 000

26.2,4 -Toluene diisocyanate

584-84-910100
2,6 -Toluene diisocyanate91-08-7

27.Carbonyl dichloride (phosgene)

75-44-50,30,75

28.Arsine (arsenic trihydride)

7784-42-10,21

29.Phosphine (phosphorus trihydride)

7803-51-20,21

30.Sulphur dichloride

10545-99-01

31.Sulphur trioxide

7446-11-91575

32.Polychlorodibenzofurans and polychlorodibenzodioxins (including TCDD), calculated in TCDD equivalent (see note 20)

0,001

33.The following CARCINOGENS or the mixtures containing the following carcinogens at concentrations above 5 % by weight:

4-Aminobiphenyl and/or its salts, Benzotrichloride, Benzidine and/or salts, Bis (chloromethyl) ether, Chloromethyl methyl ether, 1,2-Dibromoethane, Diethyl sulphate, Dimethyl sulphate, Dimethylcarbamoyl chloride, 1,2-Dibromo-3-chloropropane, 1,2-Dimethylhydrazine, Dimethylnitrosamine, Hexamethylphosphoric triamide, Hydrazine, 2- Naphthylamine and/or salts, 4-Nitrodiphenyl, and 1,3 Propanesultone

0,52

34.Petroleum products and alternative fuels

(a)

gasolines and naphthas,

(b)

kerosenes (including jet fuels),

(c)

gas oils (including diesel fuels, home heating oils and gas oil blending streams)

(d)

heavy fuel oils

(e)

alternative fuels serving the same purposes and with similar properties as regards flammability and environmental hazards as the products referred to in points (a) to (d)

2 50025 000

35.Anhydrous Ammonia

7664-41-750200

36.Boron trifluoride

7637-07-2520

37.Hydrogen sulphide

7783-06-4520

38.Piperidine

110-89-450200

39.Bis(2-dimethylaminoethyl) (methyl)amin

3030-47-550200

40.3-(2-Ethylhexyloxy)propylamin

5397-31-950200

41.Mixturesb of sodium hypochlorite classified as Aquatic Acute Category 1 [H400] containing less than 5 % active chlorine and not classified under any of the other hazard categories in Part 1 of Annex I.

200500

42.Propylamine (see note 21)

107-10-85002 000

43.Tert-butyl acrylate (see note 21)

1663-39-4200500

44.2-Methyl-3-butenenitrile (see note 21)

16529-56-95002 000

45.Tetrahydro-3,5-dimethyl-1,3,5,-thiadiazine-2-thione (Dazomet) (see note 21)

533-74-4100200

46.Methyl acrylate (see note 21)

96-33-35002 000

47.3-Methylpyridine (see note 21)

108-99-65002 000

48.1-Bromo-3-chloropropane (see note 21)

109-70-65002 000

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