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ANNEXU.K. BAT CONCLUSIONS FOR THE NON-FERROUS METALS INDUSTRIES

1.3.BAT CONCLUSIONS FOR ALUMINIUM PRODUCTION INCLUDING ALUMINA AND ANODE PRODUCTIONU.K.

1.3.2. Anode production U.K.

1.3.2.1. Air emissions U.K.
1.3.2.1.1. Dust, PAH and fluoride emissions from the paste plant U.K.
BAT 58.In order to reduce dust emissions to air from a paste plant (removing coke dust from operations such as coke storage and grinding), BAT is to use a bag filter.U.K.

BAT-associated emission levels: See Table 7.

BAT 59.In order to reduce dust and PAH emissions to air from a paste plant (hot pitch storage, paste mixing, cooling and forming), BAT is to use one or a combination of the techniques given below.U.K.
a

Descriptions of the techniques are given in Section 1.10.

Techniquea
aDry scrubber using coke as the adsorbent agent, with or without precooling, followed by a bag filter
bRegenerative thermal oxidiser
cCatalytic thermal oxidiser

BAT-associated emission levels: See Table 7.

Table 7

BAT-associated emission levels for dust and BaP (as an indicator of PAH) emissions to air from a paste plant

a

As a daily average or as an average over the sampling period.

b

As an average over the sampling period.

ParameterProcessBAT-AEL (mg/Nm3)
Dust
  • Hot pitch storage, paste mixing, cooling and forming

  • Removing coke dust from operations such as coke storage and grinding

2-5a
BaPHot pitch storage, paste mixing, cooling and forming0,001-0,01b

The associated monitoring is in BAT 10.

1.3.2.1.2. Dust, sulphur dioxide, PAH and fluoride emissions from the baking plant U.K.
BAT 60.In order to reduce dust, sulphur dioxide, PAH and fluoride emissions to air from a baking plant in an anode production plant integrated with a primary aluminium smelter, BAT is to use one or a combination of the techniques given below.U.K.
a

Descriptions of the techniques are given in Section 1.10.

TechniqueaApplicability
aUse of raw materials and fuels containing a low amount of sulphurGenerally applicable for reducing SO2 emissions
bDry scrubber using alumina as the adsorbent agent followed by a bag filterGenerally applicable for reducing dust, PAH and fluoride emissions
cWet scrubber

Applicability for reducing dust, SO2, PAH and fluoride emissions may be limited in the following cases:

  • very high off-gas flow rates (due to the significant amounts of waste and waste water generated)

  • in arid areas (due to the large volume of water necessary and the need for waste water treatment)

dRegenerative thermal oxidiser in combination with a dust abatement systemGenerally applicable for reducing dust and PAH emissions.

BAT-associated emission levels: See Table 8.

Table 8

BAT-associated emission levels for dust, BaP (as an indicator of PAH) and fluoride emissions to air from a baking plant in an anode production plant integrated with a primary aluminium smelter

a

As a daily average or as an average over the sampling period.

b

As an average over the sampling period.

ParameterBAT-AEL (mg/Nm3)
Dust2-5a
BaP0,001-0,01b
HF0,3-0,5a
Total fluorides≤ 0,8b

The associated monitoring is in BAT 10.

BAT 61.In order to reduce dust, PAH and fluoride emissions to air from a baking plant in a stand-alone anode production plant, BAT is to use a pre-filtration unit and a regenerative thermal oxidiser followed by a dry scrubber (e.g. lime bed).U.K.

BAT-associated emission levels: See Table 9.

Table 9

BAT-associated emission levels for dust, BaP (as an indicator of PAH) and fluoride emissions to air from a baking plant in a stand-alone anode production plant

a

As a daily average.

b

As an average over the sampling period.

ParameterBAT-AEL (mg/Nm3)
Dust2-5a
BaP0,001-0,01b
HF≤ 3a

The associated monitoring is in BAT 10.

1.3.2.2. Waste water generation U.K.
BAT 62.In order to prevent the generation of waste water from anode baking, BAT is to use a closed water cycle.U.K.
Applicability U.K.

Generally applicable to new plants and major upgrades. The applicability may be limited due to water quality and/or product quality requirements.

1.3.2.3. Waste U.K.
BAT 63.In order to reduce the quantities of waste sent for disposal, BAT is to recycle carbon dust from the coke filter as a scrubbing medium.U.K.
Applicability U.K.

There may be restrictions on applicability depending on the ash content of the carbon dust.