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ANNEXU.K. BAT CONCLUSIONS FOR THE NON-FERROUS METALS INDUSTRIES

1.2.BAT CONCLUSIONS FOR COPPER PRODUCTIONU.K.

1.2.3. Air emissions U.K.

1.2.3.1. Diffuse emissions U.K.
BAT 25.In order to prevent or reduce diffuse emissions from pretreatment (such as blending, drying, mixing, homogenisation, screening and pelletisation) of primary and secondary materials, BAT is to use one or a combination of the techniques given below.U.K.
TechniqueApplicability
aUse enclosed conveyers or pneumatic transfer systems for dusty materialsGenerally applicable
bCarry out activities with dusty materials such as mixing in an enclosed buildingFor existing plants, application may be difficult due to the space requirements
cUse dust suppression systems such as water cannons or water sprinklersNot applicable for mixing operations carried out indoors. Not applicable for processes that require dry materials. The application is also limited in regions with water shortages or with very low temperatures
dUse enclosed equipment for operations with dusty material (such as drying, mixing, milling, air separation and pelletisation) with an air extraction system connected to an abatement systemGenerally applicable
eUse an extraction system for dusty and gaseous emissions, such as a hood in combination with a dust and gas abatement systemGenerally applicable
BAT 26.In order to prevent or reduce diffuse emissions from charging, smelting and tapping operations in primary and secondary copper smelters and from holding and melting furnaces, BAT is to use a combination of the techniques given below.U.K.
a

Description of the technique is given in Section 1.10.

TechniqueApplicability
aBriquetting and pelletisation of raw materialsApplicable only when the process and the furnace can use pelletised raw materials
bEnclosed charging system such as single jet burner, door sealinga, closed conveyers or feeders equipped with an air extraction system in combination with a dust and gas abatement systemThe jet burner is applicable only for flash furnaces
cOperate the furnace and gas route under negative pressure and at a sufficient gas extraction rate to prevent pressurisationGenerally applicable
dCapture hood/enclosures at charging and tapping points in combination with an off-gas abatement system (e.g. housing/tunnel for ladle operation during tapping, and which is closed with a movable door/barrier equipped with a ventilation and abatement system)Generally applicable
eEncapsulate the furnace in vented housingGenerally applicable
fMaintain furnace sealingGenerally applicable
gHold the temperature in the furnace at the lowest required levelGenerally applicable
hBoosted suction systemsaGenerally applicable
iEnclosed building in combination with other techniques to collect the diffuse emissionsGenerally applicable
jDouble bell charging system for shaft/blast furnacesGenerally applicable
kSelect and feed the raw materials according to the type of furnace and abatement techniques usedGenerally applicable
lUse of lids on throats of rotary anode furnaceGenerally applicable
BAT 27.In order to reduce diffuse emissions from Peirce-Smith converter (PS) furnace in primary and secondary copper production, BAT is to use a combination of the techniques given below.U.K.
a

Description of the technique is given in Section 1.10.

Technique
aOperate the furnace and gas route under negative pressure and at a sufficient gas extraction rate to prevent pressurisation
bOxygen enrichment
cPrimary hood over the converter opening to collect and transfer the primary emissions to an abatement system
dAddition of materials (e.g. scrap and flux) through the hood
eSystem of secondary hoods in addition to the main one to capture emissions during charging and tapping operations
fFurnace located in enclosed building
gApply motor-driven secondary hoods, to move them according to the process stage, to increase the efficiency of the collection of secondary emissions
hBoosted suction systemsa and automatic control to prevent blowing when the converter is ‘rolled out’ or ‘rolled in’
BAT 28.In order to reduce diffuse emissions from a Hoboken converter furnace in primary copper production, BAT is to use a combination of the techniques given below.U.K.
a

Description of the technique is given in Section 1.10.

Technique
aOperate furnace and gas route under negative pressure during charging, skimming and tapping operations
bOxygen enrichment
cMouth with closed lids during operation
dBoosted suction systemsa
BAT 29.In order to reduce diffuse emissions from the matte conversion process, BAT is to use a flash converting furnace.U.K.
Applicability U.K.

Applicable only to new plants or major upgrades of existing plants.

BAT 30.In order to reduce diffuse emissions from a top-blown rotary converter (TBRC) furnace in secondary copper production, BAT is to use a combination of the techniques given below.U.K.
a

Description of the technique is given in Section 1.10.

TechniqueApplicability
aOperate the furnace and gas route under negative pressure and at a sufficient gas extraction rate to prevent pressurisationGenerally applicable
bOxygen enrichmentGenerally applicable
cFurnace located in enclosed building in combination with techniques to collect and transfer diffuse emissions from charging and tapping to an abatement systemGenerally applicable
dPrimary hood over the converter opening to collect and transfer the primary emissions to an abatement systemGenerally applicable
eHoods or crane integrated hood to collect and transfer the emissions from charging and tapping operations to an abatement systemFor existing plants, a crane integrated hood is only applicable to major upgrades of the furnace hall
fAddition of materials (e.g. scrap and flux) through the hoodGenerally applicable
gBoosted suction systemaGenerally applicable
BAT 31.In order to reduce diffuse emissions from copper recovery with a slag concentrator, BAT is to use the techniques given below.U.K.
Technique
aDust suppression techniques such as a water spray for handling, storage and crushing of slag
bGrinding and flotation performed with water
cDelivery of the slag to the final storage area via hydro transport in a closed pipeline
dMaintain a water layer in the pond or use a dust suppressant such as lime milk in dry areas
BAT 32.In order to reduce diffuse emissions from copper-rich slag furnace treatment, BAT is to use a combination of the techniques given below.U.K.
Technique
aDust suppression techniques such as a water spray for handling, storage and crushing of the final slag
bOperation of the furnace under negative pressure
cEnclosed furnace
dHousing, enclosure and hood to collect and transfer the emissions to an abatement system
eCovered launder
BAT 33.In order to reduce diffuse emissions from anode casting in primary and secondary copper production, BAT is to use one or a combination of the techniques given below.U.K.
Technique
aUse an enclosed tundish
bUse a closed intermediate ladle
cUse a hood, equipped with an air extraction system, over the casting ladle and over the casting wheel
BAT 34.In order to reduce diffuse emissions from electrolysis cells, BAT is to use one or a combination of the techniques given below.U.K.
TechniqueApplicability
aAddition of surfactants to the electrowinning cellsGenerally applicable
bUse covers or a hood to collect and transfer the emissions to an abatement systemOnly applicable for electrowinning cells or refining cells for low-purity anodes. Not applicable when the cell needs to remain uncovered to maintain the cell temperature at workable levels (approximately 65 °C)
cClosed and fixed pipelines for transferring the electrolyte solutionsGenerally applicable
dGas extraction from the washing chambers of the cathode stripping machine and anode scrap washing machineGenerally applicable
BAT 35.In order to reduce diffuse emissions from the casting of copper alloys, BAT is to use one or a combination of the techniques given below.U.K.
a

Description of the technique is given in Section 1.10.

Technique
aUse enclosures or hoods to collect and transfer the emissions to an abatement system
bUse covering for the melts in holding and casting furnaces
cBoosted suction systema
BAT 36.In order to reduce diffuse emissions from non-acid and acid pickling, BAT is to use one of the techniques given below.U.K.
TechniqueApplicability
aEncapsulate the pickling line with a solution of isopropanol operating in a closed circuitOnly applicable for pickling of copper wire rod in continuous operations
bEncapsulate the pickling line to collect and transfer the emissions to an abatement systemOnly applicable for acid pickling in continuous operations